Material Safety Data Sheet
Bath Clear
ACC# 89044
Section 1 - Chemical Product and Company Identification |
MSDS Name: Bath Clear
Catalog Numbers:
13-641-337, 13641227X, 1546010, 154602, 1546210, 1546211, 1546215, 1546216,
154622, 1546220, 1546221, 1546228, 1546229, 154622S, 154623, 154623S,
154625, 154626
Synonyms:
None.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
68424-85-1 |
Alkyl (c12-16)dimethylbenzylammonium chloride |
50 | 270-325-2 |
64-17-5 |
Ethyl alcohol |
10 | 200-578-6 |
7732-18-5 |
Water |
Balance | 231-791-2 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: almost colorless liquid. Flash Point: 41.7 deg C.
Danger! Corrosive. Causes eye and skin
burns. Flammable liquid and vapor.
May cause severe respiratory and digestive tract irritation with
possible burns. May cause central nervous system depression. May
cause liver and kidney damage. May cause fetal effects.
Target Organs: Kidneys, central nervous system,
liver.
Potential Health Effects
Eye:
Causes eye burns. Vapors may cause eye irritation. May cause
painful sensitization to light. May cause chemical conjunctivitis
and corneal damage.
Skin:
Causes skin burns. May cause cyanosis of the extremities.
Ingestion:
May cause systemic toxicity with acidosis. May cause severe
gastrointestinal tract irritation with nausea, vomiting and possible
burns. May cause liver and kidney damage. May cause central nervous
system depression, characterized by excitement, followed by headache,
dizziness, drowsiness, and nausea. Advanced stages may cause
collapse, unconsciousness, coma and possible death due to respiratory
failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. May cause severe irritation of the respiratory tract with
sore throat, coughing, shortness of breath and delayed lung edema.
May cause effects similar to those described for ingestion. May
cause burns to the respiratory tract. Aspiration may lead to
pulmonary edema. Vapors may cause dizziness or suffocation. May cause
burning sensation in the chest.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Prolonged
or repeated eye contact may cause conjunctivitis. May cause liver and
kidney damage. May cause fetal effects.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Water may be ineffective. Do NOT use
straight streams of water. Cool containers with flooding quantities
of water until well after fire is out.
Flash Point: 41.7 deg C ( 107.06 deg F)
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 2; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Wash thoroughly after handling.
Remove contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Do not
get in eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep away from
heat, sparks and flame. Do not ingest or inhale. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers
to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Alkyl (c12-16)dimethylbenzylammonium chloride
|
none listed
|
none listed
|
none listed
|
Ethyl alcohol
|
1000 ppm TWA
|
1000 ppm TWA; 1900 mg/m3 TWA 3300 ppm IDLH
|
1000 ppm TWA; 1900 mg/m3 TWA
|
Water
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Alkyl (c12-16)dimethylbenzylammonium chloride:
No OSHA Vacated PELs are listed for this chemical.
Ethyl alcohol:
1000 ppm TWA; 1900 mg/m3 TWA
Water:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: almost colorless
Odor: mild odor
pH: 6.5-8.3 (10% aq)
Vapor Pressure: Not available.
Vapor Density: >1.00
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:58 - 60 deg C
Decomposition Temperature:Not available.
Solubility: Freely Soluble.
Specific Gravity/Density:0.962
Molecular Formula:Not applicable.
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric
acid, muriatic acid, phosphoric acid), acids (mineral, oxidizing,
e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid),
acids (organic, e.g. acetic acid, benzoic acid, formic acid,
methanoic acid, oxalic acid), azo, diazo, and hydrazines (e.g.
dimethyl hydrazine, hydrazine, methyl hydrazine), isocyanates (e.g.
methyl isocyanate), metals (alkali and alkaline, e.g. cesium,
potassium, sodium), nitrides (e.g. potassium nitride, sodium
nitride), peroxides and hydroperoxides (organic, e.g. acetyl
peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone
peroxide), epoxides (e.g. butyl glycidyl ether), oxidizing agents
(strong, e.g. bromine, hydrogen peroxide, nitrogen dioxide,
potassium nitrate), reducing agents (strong, e.g. aluminum carbide,
chlorosilane, hydrogen phosphide, lithium hydride), water reactive
substances (e.g. acetic anyhdride, alkyl aluminum chloride, calcium
carbide, ethyl dichlorosilane).
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 68424-85-1:
UZ2995000
CAS# 64-17-5:
KQ6300000
CAS# 7732-18-5:
ZC0110000
LD50/LC50:
CAS# 68424-85-1:
Draize test,
rabbit, skin: 25 mg Severe;
Oral,
mouse: LD50 = 919 mg/kg;
Oral,
rat: LD50 = 426 mg/kg;
.
CAS# 64-17-5:
Draize test,
rabbit, eye: 500 mg Severe;
Draize
test, rabbit, eye: 500 mg/24H Mild;
Draize test, rabbit, skin: 20 mg/24H
Moderate;
Inhalation, mouse: LC50 =
39 gm/m3/4H;
Inhalation, rat: LC50
= 20000 ppm/10H;
Oral, mouse: LD50
= 3450 mg/kg;
Oral, rabbit: LD50 =
6300 mg/kg;
Oral, rat: LD50 = 7060
mg/kg;
Oral, rat: LD50 = 9000
mg/kg;
.
CAS# 7732-18-5:
Oral, rat:
LD50 = >90 mL/kg;
.
Carcinogenicity:
CAS# 68424-85-1:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 64-17-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Ethanol has been shown to produce fetotoxicity in the
embryo or fetus of laboratory animals.Prenatal exposure to
ethanol is associated with a distinct pattern of
congenital malformations that have collectively been termed
the "fetal alcohol syndrome".
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
CORROSIVE LIQUIDS, FLAMMABLE, N.O.S. |
No information available. |
Hazard Class: |
8 |
|
UN Number: |
UN2920 |
|
Packing Group: |
II |
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 68424-85-1 is listed on the TSCA inventory.
CAS# 64-17-5 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 64-17-5: immediate, delayed, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 68424-85-1 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 64-17-5 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
WARNING: This product contains Ethyl alcohol, a chemical known to the
state of California to cause developmental reproductive toxicity.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 10 Flammable.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 24/25 Avoid contact with skin and eyes.
S 33 Take precautionary measures against static discharges.
S 9 Keep container in a well-ventilated place.
WGK (Water Danger/Protection)
CAS# 68424-85-1: 3
CAS# 64-17-5: 0
CAS# 7732-18-5: No information available.
Canada - DSL/NDSL
CAS# 68424-85-1 is listed on Canada's DSL List.
CAS# 64-17-5 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of E, B3.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 64-17-5 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 4/20/1998
Revision #9 Date: 10/30/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.