CAROLINA BIOLOGICAL SUPPLY CO -- 87-6671, NAPHTHOL ALPHA SOLUTION -- -
===================== Product Identification ===================== Product ID:87-6671, NAPHTHOL ALPHA SOLUTION MSDS Date:09/05/2000 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:CAROLINA BIOLOGICAL SUPPLY CO Address:2700 YORK RD City:BURLINGTON State:NC ZIP:27215-3387 Country:US Info Phone Num:800-227-1150/910-584-0381 Emergency Phone Num:800-424-9300 Chemtrec Ind/Phone:(800)424-9300 CAGE:59896 === Contractor Identification === Company Name:CAROLINA BIOLOGICAL SUPPLY CO Address:2700 YORK RD Box:City:BURLINGTON State:NC ZIP:27215-3387 Country:US Phone:800-227-1150/910-584-0381 Contract Num:MDA414-01-P-1321 CAGE:59896 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ALCOHOL CAS:64-17-5 RTECS #:KQ6300000 = Wt:85.5 OSHA PEL:1900 MG/M3;1000 PPM ACGIH TLV:1880 MG/M3;1000 PPM Ingred Name:METHYL ISOBUTYL KETONE (DENATURANT) CAS:108-10-1 RTECS #:SA9275000 = Wt:3.6 OSHA PEL:410 MG/M3;100 PPM ACGIH TLV:205 MG/M3;50 PPM ACGIH STEL:307 MG/M3;75 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:HEXANE (DENATURANT) CAS:110-54-3 RTECS #:MN9275000 = Wt:.9 OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:.ALPHA.-NAPHTHOL CAS:90-15-3 RTECS #:QL2800000 = Wt:5. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ETHYL ALCOHOL: ORAL,RAT,LD50:7,060 MG/KG Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: MAY CAUSE IRRITATION TO EYES AND SKIN. LOCAL ACTION MAY PRODUCE PEELING OF THE SKIN WHICH MAY BE FOLLOWED BY PERSISTENT PIGMENTATION. CONSULT A PHYSICIAN UPON EXPOSURE. POTENTIAL H EALTH EFFECTS: EYES: MAY CAUSE IRRITATION. SKIN: MAYCAUSE IRRITATION. INGESTION: MAY CAUSE GASTRINTESTINAL DISCOMFORT. INHALATION: MAY CAUSE IRRITATION TO RESPIRATORY TRACT. TARGET ORGANS: KIDNEYS, LI VER, HEART, AND GI TRACT. Explanation of Carcinogenicity:TOXICOLOGICAL PROPERTIES OF THIS MIXTURE HAVE NOT BEEN THOROUGHLY EVALUATED, SEE TOXICITY DATA FOR COMMENTS ON INDIVIDUAL COMPONENTS. Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITAITON. INGESTION: GASTROINTESTINAL DISCOMFORT. INHALTION: IRRITATION TO RESPIRATORY TRACT. Medical Cond Aggravated by Exposure:KIDNEY, LIVER, HEART, AND GASTROINTESTINAL CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES, RAISING EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IF IRRITAITON PERSISTS. SKIN: WASH EXPOSED AREA FOR 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFO RE REUSE. GET MEDICAL ATTENTION. INGESTION: IF CONSCIOUS, GIVE PLENTY OF WATER AND INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. CALL PHYSICIAN OR POISON CONTROL CENTER. NEVER GIVE ANYTHING BY MOU TH TO AN UNCONSCIOUS PERSON. INHALATION: MOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF BREATHING STOPPED. KEEP PERSON WARM, QUIET, GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=13.1C, 55.6F ETHYL ALCOHOL Autoignition Temp:=422.8C, 793.F Autoignition Temp Text:ETHYL Lower Limits:3.3%ETHYL AL Upper Limits:19%ETHYL ALC Extinguishing Media:USE DRY CHEMICAL, CO2, OR APPROPRIATE FOAM. Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE EQUIPMENT AND NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. VAPORS ARE HEAVIER THAN AIR AND CAN TRAVEL DISTANCES TO IGNITION SOURCE AND FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF SPILL. ELIMINATE ALL SOURCES OF IGNITION. REMOVE ALL NON-ESSENTIAL PERSONNEL FROM AREA. CLEAN-UP PERSONNEL SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND CLOTHING. ABSORB MATERIAL WITH SUITABLE ABSORBENT AND CONTAINERIZE FOR DISPOSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:THIS MATERIAL SHOULD BE KEPT IN AN AREA SUITABLE FOR STORAGE OF FLAMMABLE LIQUIDS. BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID. DO NOT BREATHE VAPOR. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHIN G. Other Precautions:DO NOT TAKE INTERNALLY! WASH THOROUGHLY AFTER HANDLING. KEEP OXIDIZING MATERIAL AND STRONG ACIDS AWAY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA CHEMICAL CARTRIDGE RESPIRATOR SHOULD BE WORN IF PEL OR TLV IS EXCEEDED. Ventilation:LOCAL EXHAUST: PREFERRED. MECHANICAL(GENERAL): ACCEPTABLE. Protective Gloves:RUBBER, NEOPRENE, PVC, OR EQUIVALENT. Eye Protection:WEAR SPLASH PROOF CHEMICAL SAFETY GOGGLES AT ALL TIMES. Other Protective Equipment:LAB COAT, EYE WASH AND SAFETY SHOWER. Supplemental Safety and Health MSDS COVERS CAROLINA PRODUCT CODES: 87-6671; 87-6673. SIZE: 120ML; 500ML. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:=25.8C, 78.5F Melt/Freeze Pt:M.P/F.P Text:NO INFO Vapor Pres:NO INFO Vapor Density:1.59(AIR=1 Spec Gravity:<1 (H20=1) Evaporation Rate & Reference:1.70 (H20=1) Solubility in Water:95% (NAPHTHOL IS INSOLUBL Appearance and Odor:DARK REDDISH, BROWN LIQUID; FRUITY ODOR. Percent Volatiles by Volume:95% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, CONCENTRATED NITRIC, AND SULFURIC ACIDS, ALDEHYDES, HALOGENS. Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:TOXICOLOGICAL PROPERTIES OF THIS MIXTURE HAVE NOT BEEN THOROUGHLY EVALUATED. ETHYL ALCOHOL: ORAL, RAT, LD50:7,060 MG/KG; IHL, RAT, LC50: 20,000 PPM/ 10 HR. METHYL ISOBUTYL KETONE: ORAL, RAT, LD50: 5,0 80 MG/KG; IHL, RAT, LC50: 8,000 PPM/4H. HEXANE: ORAL, RAT, LD50: 28,710 MG/M3; INH, HMN TCLO: 5,000 PPM/ 10 M. ALPHA-NAPHTHOL: ORAL, RAT, LD50: 2,400 MG/KG; SKN, RBT, LD50: 880 MG/ KG. EFFECTS OF OVER EXPOSURE: CHRONIC: ETHYL ALCOHOL: MUTATION DAT CITED. REPRODUCTIVE EFFECTS DATA CITED. TUMORIGENIC DATA CITED. NOT LISTED AS CAUSING CANCER BY IARC, NTP, OR OSHA. METHYL ISOBUTYL KETONE: NO CHRONIC EF FECTS (CONTD. SEE "ECOLOGICAL") ===================== Ecological Information ===================== Ecological:EPA WASTE NUMBERS: ETHANOL, 95% D001. (CONTD. FROM "TOXICOLOGICAL") DATA FOUND. NOT LISTED AS CAUSING CANCER BY IARC, NTP, OR OSHA. HEXANE: MUTATION DATA CITED. REPRODUCTIVE EFFECTS DATA CITED. NOT LI STED AS CAUSING CANCER BY IARC, NTP, OR OSHA. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE. =================== MSDS Transport Information =================== Transport Information:DESCRIPTION: FLAMMABLE LIQUIDS, N.O.S. (ETHANOL, METHYL ISOBUTYL KETONE), HAZARD CLASS 3, UN 1993, PKG I I. ===================== Regulatory Information ===================== SARA Title III Information:HAZARD CATEGORY FOR SARA SECTION 311 / 312 REPORTING: ACUTE, FIRE. METHYL ISOBUTYL KETONE IS ON SARA SECTION 313 LIST. Federal Regulatory Information:EPA TSCA STATUS: ON TSCA INVENTORY. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.