DU PONT E I DE NEMOURS & CO INC -- FREON 12 -- 6830-01-443-0387
===================== Product Identification ===================== Product ID:FREON 12 MSDS Date:10/07/1996 FSC:6830 NIIN:01-443-0387 Status Code:A === Responsible Party === Company Name:DU PONT E I DE NEMOURS & CO INC Address:1007 MARKET STREET Box:1635 City:WILMINGTON State:DE ZIP:19898 Country:US Info Phone Num:800-441-9442/MSDS 302-992-3511 Emergency Phone Num:800-441-3637/800-424-9300(CHEMTREC) CAGE:18873 === Contractor Identification === Company Name:DDRV STOCK MAINTENANCE DIV/DDRV-H Address:8000 JEFFERSON-DAVIS HIGHWAY Box:City:RICHMOND State:VA ZIP:23297 Country:US Phone:804-279-3125 CAGE:02LX8 Company Name:E.I. DUPONT DE NEMOURS & CO Address:1007 MARKET STREET Box:City:WILMINGTON State:DE ZIP:19898 Country:US Phone:800-441-7515;800-441-9442 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:DICHLORODIFLUOROMETHANE (SARA 313) (CERCLA) CAS:75-71-8 RTECS #:PA8200000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ozone Depleting Chemical:1 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LC50 (INH, RAT) 800,000 PPM/30 MINUTES Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: CNS, EYE, SKIN, LUNG. ACUTE- HARMFUL IF INHALED. MAY CAUSE HEART IRREGULARITIES, UNCONSCIOUSNESS OR DEATH. INTENTIONAL MISUSE IS FATAL. VAPOR REDUCES OXYGEN & IS HEAVIER THAN AIR. EYE/S KIN CONTACT WITH LIQUID CAN CAUSE FROSTBITE. VAPORS CAN CAUSE EYE IRRITATION. INGESTION IS UNLIKELY. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:TEMPORARY NERVOUS SYSTEM DEPRESSION WITH ANAESTHETIC EFFECTS SUCH AS DIZZINESS, HEADACHE, CONFUSION, INCOORDINATION, LOSS OF CONSCIOUSNESS, IRREGULAR PULSE, PALPITATIONS, INADEQUATE CIRCULATION, FROST BILTE, IRRITATION, BLURRED VISION, TEARING Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING DISEASES OF THE CENTRAL NERVOUS OR CARDIOVASCULAR SYSTEM MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURE. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF NEEDED. EYE/SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER. TREAT FOR FROSTBITE IF NEEDED. INHALED: REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED. ORAL: INGESTION IS NOT CO NSIDERED A POTENTIAL ROUTE OF EXPOSURE.NOTE TO PHYSICIAN: CATECHOLAMINE DRUGS SHOULD BE USED WITH SPECIAL CAUTION ONLY IN SITUATIONS OF EMERGENCY LIFE SUPPORT. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:>1382F Lower Limits:NOT RELEVANT Upper Limits:NOT RELEVANT Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CYLINDERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. MOVE CYLINDERS FROM FIRE AREA IF POSSIBLE WITHOUT INCREASED PERSONAL RISK. Unusual Fire/Explosion Hazard:THIS PRODUCT MAY IGNITE WHEN MIXED WITH AIR AT CONCENTRATIONS OF 65 VOLUME % AIR. CYLINDERS MAY RUPTURE. DECOMPOSITION PRODUCTS ARE TOXIC AND CORROSIVE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA, ESPECIALLY LOW PLACES WHERE VAPORS MIGHT COLLECT. REMOVE OPEN FLAMES. USE SELF-CONTAINED BREATHING APPARATUS FOR LARGE SPILLS OR RELEASES. Neutralizing Agent:NOT RELEVANT ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA, AWAY FROM FLAMES & INCOMPATIBLE MATERIALS. DO NOT HEAT ABOVE 125F/52C. Other Precautions:AVOID BREATHING VAPORS. AVOID EYE OR SKIN CONTACT. WASH WITH SOAP AND WATER BEFORE EATING OR DRINKING. USE WITH ADEQUATE VENTILATION. NEVER USE IN CONFINED OR CLOSED SPACES WITHOUT PROPER PROTECTIVE E QUIPMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE MODE OR SUPPLIED-AIR RESPIRATOR WITH FULL FACEPIECE AND OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE IF A LARGE RELEASE OCCURS. Ventilation:NORMAL VENTILATION IS SUFFICIENT. LOCAL EXHAUST WHEN LARGE AMOUNTS ARE RELEASED, MECHANICAL VENTILATION IN LOW PLACES Protective Gloves:LINED BUTYL GLOVES Eye Protection:CHEMICAL SPLASH GOGGLES/FACE SHIELD Other Protective Equipment:EYEBATH, WASHING FACILITY, SAFETY SHOWER, UNIFORM Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:G3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:-22F,-30C Vapor Pres:4886 @ 77F Vapor Density:4.26 @ 77F Spec Gravity:1.315 (LIQUID) Viscosity:NOT RELEVANT Evaporation Rate & Reference:NOT RELEVANT (GAS) Solubility in Water:0.028 WT% @ 25C/77F Appearance and Odor:CLEAR, COLORLESS LIQUEFIED GAS - SLIGHT ETHEREAL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI OR ALKALINE EARTH METALS, POWDERED ALUMINUM, ZINC, BERYLLIUM, ETC. Stability Condition to Avoid:FLAME, GLOWING METAL SURFACES, HIGH TEMPERATURES Hazardous Decomposition Products:MAY FORM HYDROGEN FLUORIDE, HYDROGEN CHLORIDE AND TRACES OF CARBONYL HALIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECLAIM BY DISTILLATION. CONSULT LOCAL, STATE AND FEDERAL AUTHORITIES. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.