SHERWIN-WILLIAMS CO THE SPECIALTY DIV. -- 1502 FLAT WHITE SPRAY PAINT AEROSOL,800743 -- 8010-00D007419
===================== Product Identification ===================== Product ID:1502 FLAT WHITE SPRAY PAINT AEROSOL,800743 MSDS Date:04/10/1989 FSC:8010 NIIN:00D007419 === Responsible Party === Company Name:SHERWIN-WILLIAMS CO THE SPECIALTY DIV. Address:31500 SOLON RD City:SOLON State:OH ZIP:44146-5000 Country:US Info Phone Num:800-777-2966/247-3266 Emergency Phone Num:216-566-2917/292-7400 CAGE:DO642 === Contractor Identification === Company Name:BLICK DICK CO Address:P O BOX 1267 Box:City:GALESBURG State:IL ZIP:61401 Country:US Phone:309-343-6181 CAGE:06608 Company Name:SHERWIN-WILLIAMS CO THE SPECIALTY DIV. Address:6830 COCHRAN RD. Box:6709 City:SOLON State:OH ZIP:44139-3908 Phone:216-292-7400 CAGE:DO642 Company Name:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC. Address:26300 FARGO AVENUE Box:City:BEDFORD HEIGHTS State:OH ZIP:44146 Country:US Phone:216-292-7400 OR 216-595-8634 CAGE:09800 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONE (SARA 313) (CERCLA) CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 30 - 50% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:750PPM/1000STEL;9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 10 - 30% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9596 Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA 313) (CERCLA) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 5 - 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:200 PPM/300STEL;9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ISOBUTYL KETONE (HEXONE) (SARA 313) (CERCLA) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 1 - 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:50 PPM/75 STEL; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-PROPANOL 1-METHOXY ACETATE/PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE CAS:108-65-6 RTECS #:AI8295000 Fraction by Wt: 5 - 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT ESTABLISHED. ACGIH TLV:NOT ESTABLISHED. Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 1 - 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 10 - 30% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 5 - 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, CNS, LUNGS. ACUTE- INHALATION OF VAPORS MAY CAUSE CNS DEPRESSION. MAY CAUSE IRRITATION OF EYES, SKIN & RESPIRATORY TRACT. MAY CAUSE SKIN DEFATTING. HARMFUL IF SWALLOWED. MAY CAUSE VOMITING. ASPIRATION HAZARD. CHRONIC- OVEREXPOSURE MAY CAUSE DERMATITIS, LIVER, KIDNEYS, BRAIN & CNS DAMAGE Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, DIFFICULTY IN BREATHING, NAUSEA, VOMITING, DEFATTING, DIZZINESS, LOSS OF COORDINATION, FATIGUE, CONFUSION, DERMATITIS, BLURRED VISION, TEARING, UNCONSCIOUSNESS Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES OF THE EYE, SKIN, RESPIRATORY TRACT, LIVER, KIDNEYS, CNS MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES/SKIN:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. INHALED:MOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NECESSARY. ORAL:SEEK MEDICAL ATTEN TION IMMEDIATELY. IF CONSCIOUS, DRINK LARGE AMOUNT OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:FLAMMABL AEROSOL Extinguishing Media:USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE. WATER MAY BE INEFFECTIVE BUT SHOULD BE USED TO COOL FIRE-EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. VAPORS ARE HEAVIER THAN AIR, CAN TRAVEL TO IGNITION SOURCES AND FLASH BACK. Unusual Fire/Explosion Hazard:SPRAY CANS UNDER PRESSURE. EXTREMELY FLAMMABLE. EXPLOSION HAZARD EXISTS WHEN SPRAY CANS HEATED. DO NOT ENTER SPRAY CAN STORAGE AREA IF FIRE PRESENT. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. REMOVE IGNITION SOURCES. LEAKING CONTAINERS SHOULD BE PLACED OUTDOORS, IN AN OPEN CONTAINER, AWAY FROM SOURCES OF IGNITION. ALLOW PRESSURE TO DISSIPATE. ABSORB LIQUID WITH NON-FLAMMABL E ABSORBENT AND PLACE IN CONTAINER FOR DISPOSAL. Neutralizing Agent:NOT RELEVANT ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE SPRAY CANS IN COOL, WELL VENTILATED AREAS AWAY FROM SOURCES OF IGNITION & SUNLIGHT. Other Precautions:"EMPTY" CONTAINERS RETAIN RESIDUE AND CAN BE DANGEROUS. FOLLOW ALL LABEL INSTRUCTIONS. AVOID REPEATED/PROLONGED SKIN CONTACT. KEEP OUT OF REACH OF CHILDREN. DO NOT BREATHE VAPORS. DO NOT SPRAY TOWARD FACE/HOT SURFACES. WASH AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED, WEAR NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR OR AIR-PURIFYING RESPIRATOR. IN EMERGENCY, WEAR A NIOSH-APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS. Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Protective Gloves:BUTYL IF SKIN CONTACT IS POSSIBLE Eye Protection:CHEMICAL SAFETY GOGGLES/GLASSES Other Protective Equipment:EYE WASH STATION & SAFETY SHOWERS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING, DRINKING/SMOKING. Supplemental Safety and Health EXTREMELY FLAMMABLE. CONTENTS UNDER PRESSURE. CONTAINS FLAMMABLE GAS SUCH AS PROPANE AND FLAMMABLE LIQUID. DO NOT USE IN CONFINED AREA OR AREA WITH LITTLE AIR MOVEMENT. EMPLOY MEANS TO PREVENT VAPOR B UILDUP. ================== Physical/Chemical Properties ================== HCC:V3 NRC/State Lic Num:NOT RELEVANT Vapor Pres:3862 @ 70F Vapor Density:>1 Spec Gravity:<1 Viscosity:NOT KNOWN Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1) Solubility in Water:SLIGHT Appearance and Odor:AEROSOL - SOLVENT ODOR Percent Volatiles by Volume:81- 89 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, DIRECT SUNLIGHT, TEMPERATURES ABOVE 120F, SPARKS, SMOKING Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT PUNCTURE, INCINERATE SPRAY CANS EVEN AFTER USE. DO NOT FLUSH INTO DRAINS. REUSING OR RECYCLING IS RECOMMENDED. 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