FISHER SCIENTIFIC -- PROPYLENE GLYCOL, P3554 -- -
===================== Product Identification ===================== Product ID:PROPYLENE GLYCOL, P3554 MSDS Date:04/01/1998 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:FISHER SCIENTIFIC Address:ONE REAGENT LANE City:FAIRLAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:800-424-9300 Chemtrec Ind/Phone:(800)424-9300 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:PROPYLENE GLYCOL CAS:57-55-6 RTECS #:TY2000000 = Wt:100. ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL,RAT) 20 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE EYE IRRITATION. SKIN: MAY CAUSE SKIN IRRITATION. INGESTION: MAY CAUSE GASTROINTESTINAL IRRITATION WITH NAUSEA, VOMITING AND DIARRHEA. MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. IN HALATION: LOW HAZARD FOR USUAL INDUSTRIAL HANDLING. CHRONIC: MAY CAUSE FETAL EFFECTS. TARGET ORGANS: CENTRAL NERVOUS SYSTEM. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/ PLENTY OF WATER FOR AT LST 15 MINS, OCCASNLY LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR AT LST 15 MINS WHILE REMOVING CONTAMD CLTHG AND SHOES. GET MEDICAL AID IF IRRIT DEVELOPS/PERSISTS. INGESTION: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. GET MEDICAL AID IF IRRIT/SYMPTOM S OCCUR. INHAL: REMOVE FROM EXPOSURE TO FRESH AIR IMMED. GET MEDICAL AID IF COUGH/OTHER SYMPS APPEAR. NOTES TO PHYS: TREAT SYMPTOMATICALLY & SUPPORTIVELY. ===================== Fire Fighting Measures ===================== Flash Point:=98.9C, 210.F Autoignition Temp:=415.6C, 780.F Lower Limits:2.60% Upper Limits:12.50% Extinguishing Media:IN CASE OF FIRE, USE WATER, DRY CHEMICAL, CHEMICAL FOAM, OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF-CONTAINED BREATHING APPARATUS IN PRESSURE-DEMAND, NIOSH (APPROVED OR EQUIVALENT), AND FULL PROTECTIVE GEAR. ================== Accidental Release Measures ================== Spill Release Procedures:GEN INFO: USE PROPER PERSONAL PROT EQUIP AS INDICATED IN SECTION 8. ABSORB SPILL WITH INERT MATERIAL (E.G., DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:WASH THOROUGHLY AFTER HANDLING. USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH SKIN AND EYES. KEEP CONTAINER TIGHTLY CLOSED. AVOID INGESTION AND INHALATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS LOW. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health TOX INFO: DEFORMITIES. REPRODUCTIVE EFTS, NEUROTOXICITY, MUTAGENICITY, OTHER STUDIES: NO DATA AVAILABLE. ================== Physical/Chemical Properties ================== Boiling Pt:=188.C, 370.4F Melt/Freeze Pt:=-60.C, -76.F Vapor Pres:0.07 Vapor Density:2.62 Spec Gravity:1.0360 Viscosity:45 MPA S 20 DEG Solubility in Water:MISCIBLE IN WATER Appearance and Odor:CLEAR, COLORLESS LIQUID. ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACID CHLORIDES; ACID ANHYDRIDES; OXIDIZING AGENTS; CHLOROFORMATES; REDUCING AGENTS; HYDROFLUORIC ACID AND NITRIC ACID. Stability Condition to Avoid:INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. =================== Toxicological Information =================== Toxicological Information:RTECS#: CAS# 57-55-6: TY2000000. LD50/LC50: CAS# 57-55-6: ORAL, MOUSE: LD50 = 22 GM/KG; ORAL,RABBIT: LD50 = 18500 MG/KG; ORAL,RAT: LD50 = 20 GM/KG; SKIN RABBIT: LD50 = 20800 MG/KG. CARCINOGENICITY: CA S# 57-55-6: NOT LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA. EPIDEMIOLOGY: NO DATA AVAIL. TERATOGENICITY: PROPYLENE GLYCOL CAUSED HIGH MORTALITY OF CHICK EMBRYOS WHEN INJECTED INTO THE AIR SACK ON THE 4TH DAY OF DEVELOPMENT & UNILATERAL MICROMELIA IN ABOUT 20 PERCENT OF SURVIVORS. CHICKS FED HIGH LEVELS OF PROPYLENE GLYCOL DEVELOPED A HIGH INCIDENT OF TOE (SUPDAT) ===================== Ecological Information ===================== Ecological:EXOTOXICITY, ENVIRONMENTAL FATE, PHYSICAL/CHEMICAL, OTHER: NOT AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAX CONC OF CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOX REFERENCE LEVELS: NONE LISTED. RCRA F-SERIE S, P-SERIES, U-SERIES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:US DOT, IATA, RID/ADR, IMO, CANADA TDG: NO INFORMATION AVAILABLE. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302(RQ): NONE OF CHEMS IN THIS MATL HAVE AN RQ. SECTION 302 (TPQ): NONE OF CHEMS IN THIS PROD HAVE A TPQ. SECTION 313: NO CHEMS ARE REPORTABLE UNDER SECTION 313. CLEAN AIR ACT: MATL DOES NOT C NTN ANY CLASS 1 OZONE DEPLETORS. THIS MATL DOES NOT CNTN ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED AS HAZ SUBSTANCES UNDER CWA. NONE OF CHEMS IN PROD ARE LISTED AS PRIORITY POLLUTANTS UNDER CWA. NONE OF CHEMS IN PROD ARE LISTED AS TOXIC POLLUTANTS UNDER CWA. OSHA: NONE OF CHEMS IN PROD ARE CONSIDERED HIGHLY HAZ BY OSHA. Federal Regulatory Information:TSCA: CAS# 57-55-6 LISTED ON TSCA INVENTORY. HEALTH & SAFETY REPORTING LIST: NONE OF CHEMS ARE ON HEALTH & SAFETY REPROTING LIST. CHEMICAL TEST RULES: NONE OF CHEMS IN PROD ARE UNDER CHEMICAL TEST RUL E. SECTION 12B: NONE OF CHEMS ARE LISTED UNDER TSCA SECTON 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF CHEMS IN MATL HAVE SNUR UNDER TSCA. State Regulatory Information:CAS# 57-55-6 CAN BE FOUND ON THE FOLLOWING STATE RIGHT TO KNOW LISTS: PENNSYLVANIA, MINNESOTA. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF CHEMICALS IN THIS PRODUCT ARE LISTED. EUROPEAN/INTERNATIONA L REGS EUROPEAN LABELING I/A/W EC DIRECTIVES HAZARD SYMBOLS: NOT AVAILABLE. WGK (WATER DANGER/PROTECTION): CAS# 57-55-6: 0. CANADA: CAS# 57-55-6 IS LISTED ON CANADA'S DSL/NDSL LIST. THIS PRODUCT HAS W HMIS CLASSIFICATION OF NOT CONTROLLED. CAS# 57-55-6 IS NOT LISTED ON CANADA'S INGREDIENT DISCLOSURE LIST. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.