FISHER SCIENTIFIC -- METHYL ALCOHOL 14280, A412J500 -- 6810-00N087045
===================== Product Identification ===================== Product ID:METHYL ALCOHOL 14280, A412J500 MSDS Date:09/02/1997 FSC:6810 NIIN:00N087045 === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:703-527-3887;800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA). LD50: (ORAL, RAT) 5628 MG/KG. CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: >99% OSHA PEL:200 PPM, S ACGIH TLV:200 PPM; 250 STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPDAT: BERYLLIUM DIHYDRIDE, CARBON TETRACHLORIDE + METALS, CHLOROFORM + HEAT, CHLOROFORM + SODIUM HYDROXIDE, (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: CYANURIC CHLORIDE, DIETHYL ZINC, NITRIC ACID & POTASSIUM TERTBUTOXIDE. PLEASE REFER TO THE NFPA FIRE (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: PROTECTION GUIDE FOR ALL SPECIFICS. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: TO THOSE DESCRIBED FOR INGEST. CHRONIC: PRLNGD/RPTD SKIN CONTACT MAY CAUSE DERM. CHRONIC INHAL (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: & INGEST MAY CAUSE EFTS SIMILAR TO THOSE OF ACUTE INHAL & INGEST. TARGET ORGANS: KIDNEYS, CNS, LIVER, EYES. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: VOMIT BY GIVING ONE TEASPOON OF SYRUP OF IPECAC. INHAL: GET MED AID IMMED. REMOVE FROM EXPOS TO (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. NOTE TO MD: EFTS MAY BE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: DELAYED. ETHANOL MAY INHIBIT METABOLISM. ANTIDOTE: NO SPECIFIC ANTIDOTE EXISTS. RTECS #:9999999ZZ Ingred Name:OTHER PRECS: CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE EMTPY CNTNRS TO HEAT, SPARKS OR OPEN FLAMES. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYE: CAUSES MODERATE IRRIT. VAPS MAY CAUSE IRRIT. MAY CAUSE PAINFUL SENSIT TO LIGHT. SKIN: MAY CAUSE SKIN IRRIT. MAY BE ABSORBED THRU SKIN IN HARMFUL AMTS. INGEST: MAY CAUSE IRRIT OF DIGEST TRACT. MAY CAUSE CNS DEPRESS CHARACTERIZED BY EXCITEMENT, FOLLOWED BY HDCH, DIZZ, DROW & NAUS. ADVANCED STAGES (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: MAY CAUSE COLLAPSE, UNCON, COMA & POSS DEATH DUE TO RESP FAILURE. MAY CAUSE KIDNEY FAILURE. INHAL: MAY CAUSE RESP TRACT IRRIT. MAY CAUSE LIVER & KIDNEY DMG. MAY CAUSE ADVERSE CNS EFTS INCLUD ING HDCH, CONVULSIONS & POSS DEATH. MAYCAUSE VISUAL IMPAIRMENT & POSS PERM BLINDNESS. MAY CAUSE EFTS SIMILAR (ING 5) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH EYES W/PLENTY OF WATER FOR AT LST 15 MIN, OCCASNLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB OR KEEP EYES CLOSED. SKIN: FLUSH SKIN W/PLENTY OF SOAP & WATER FOR AT LST 15 MIN WHILE REMOVING CONTAMCLTHG & SHOES. GET MED AID IF IRRIT DEVELOPS OR PERSISTS. INGEST: IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. GET MED AID IMMED. INDUCE (ING 7) ===================== Fire Fighting Measures ===================== Flash Point:53.6F,12.0C Lower Limits:6.0% Upper Limits:31.0% Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESIST FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. WATER MAY BE INEFFECTIVE. Unusual Fire/Explosion Hazard:CNTNRS CAN BUILD UP PRESS IF EXPOSED TO HEAT &/OR FIRE. VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK. DURING FIRE, IRRITATING & HIGHLY TOX GASES MAY (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP UP WITH NONSPARKING TOOL, THEN PLACE INTO SUITABLE CONTAINER FOR DISPOSAL. USE WATER SPRAY TO DISPERSE GAS/VAPOR. REMOVE ALL SOURCES OF IGNITION. ABSORB SPILL USING ABSORBENT, NON-COMBUSTIBLE MA TERIAL SUCH AS EARTH, SAND OR VERMICULITE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM SOURCES OF IGNITION. STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:WASH THOROUGHLY AFTER HNDLG. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. USE W/ADEQ VENT. EMPTY CNTNRS RETAIN PROD RESIDUE (LIQ &/OR VAP) & CAN BE DANGEROUS. DO NOT GET ON SKIN OR IN EYES. DO NOT INGEST OR INHALE. DO NOT PRESSURIZE, (ING 10) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ: BE GENERATED BY THERMAL DECOMP OR COMBUSTS. FLAM LIQ. CAN RELS VAPS THAT FORM EXPLO MIXS AT TEMPS ABOVE FLASH POINT. MATL TO AVOID: SODIUM HYPOCHLORITE). ACTIVE METALS (SUCH AS POTASSIUM & MAGNESIUM). SUBSTANCE IS ALSO INCOMPAT W/SPECIFIC CHEMS INCLUDING: ACETYL BROMIDE, ALKYL ALUMINUM SALTS, (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:148F,65C Melt/Freeze Pt:M.P/F.P Text:-144F,-98C Vapor Pres:96 Vapor Density:1.1 Spec Gravity:0.7910 Evaporation Rate & Reference:5.2 (ETHER =1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; SLIGHT ALCOHOL-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDANTS (SUCH AS BARIUM PERCHLORATE, BROMINE, CHLORINE, HYDROGEN PEROXIDE, LEAD PERCHLORATE, PERCHLORIC ACID, (SUPDAT) Stability Condition to Avoid:STABLE AT ROOM TEMP IN CLSD CNTNRS UNDER NORM STORAGE & HNDLG CNDTNS. AVOID HIGH TEMPS, INCOMPAT MATLS, IGNIT SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN A MANNER CONSISTENT WITH FEDERAL, STATE AND LOCAL REGULATIONS. THIS MATERIAL IS BANNED FROM LAND DISPOSAL ACCORDING TO RCRA. 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