FISHER SCIENTIFIC, CHEMICAL DIV. -- A200 212;NITRIC ACID -- 6810-00-241-1193
===================== Product Identification ===================== Product ID:A200 212;NITRIC ACID MSDS Date:12/20/1994 FSC:6810 NIIN:00-241-1193 === Responsible Party === Company Name:FISHER SCIENTIFIC, CHEMICAL DIV. Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100/800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID (SARA 302/313) (CERCLA) CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 69-71% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 PPM ACGIH TLV:2 PPM/4 STEL; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 29-31% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS >90 ML/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:**CORROSIVE** EYES:MAY CAUSE SEVERE BURNS AND IRREVERSIBLE EYE DAMAGE.SKIN:MAY CAUSE SEVERE IRRITATION AND DEEP PENETRATING ULCERS.INGEST:MAY CAUSE GI TRACT BURNS AND PERFORATIONS.INHAL:MAY BE FATAL I F INHALED OR RESPIRATORY TRACT IRRITATION.CHRONIC:CHRONIC BRONCHITIS,EROSION OF TEETH. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:IRRITATION,BURNS,ULCERS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER.GET MEDICAL ATTENTION IF IRRITATION PERSISTS.EYES:FLUSH WITH WATER FOR 15 MINUTES.GET MEDICAL ATTENTION IMMEDIATELY.INHAL:REMOVE TO FRESH AIR .GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SCBA. FIGHT FIRE AS FAR A DISTANCE AS POSSIBLE. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:NITRIC ACID MAY YIELD OXYGEN WHEN HEATED, WHICH WILL INCREASE THE RATE OF BURNING OF COMBUSTIBLE MATERIAL & MAY RESULT IN IGNITION, VIOLENT COMBUSTION OR EXPLSN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER RESPIRATORY AND PROTECTIVE EQUIPMENT.SOAK UP WITH NON-COMBUSTIBLE INERT ADSORBANT(EG.CLAY);PLACE COLLECTED MATERIAL IN AN APPROPRIATE CONTAINER FOR DISPOSAL. Neutralizing Agent:SLAKED LIME, SODIUM BICARBONATE OR CRUSHED LIMESTONE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE, HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. KEEP CONTAINERS CLOSED. Other Precautions:AVOID EXPOSING PRODUCT TO DIRECT SUNLIGHT. AVOID EYE AND SKIN CONTACT. DO NOT BREATHE VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR WITH ACID GAS CARTRIDGE OR SCBA AS APPROPIATE FOR EXPOSURE OF CONCERN. Ventilation:LOCAL EXHAUST VENTILATION TO KEEP EXPOSURE LEVELS BELOW PEL. Protective Gloves:NATURAL RUBBER, NEOPRENE OR PVC GLOVES. Eye Protection:SPLASH-PROOF GOGGLES AND FACE SHIELD. Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO MINIMIZE EXPOSURE FROM PROLONGED OR REPEATED CONTACT. EYE BATH AND SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health NONE. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:187F,86C Melt/Freeze Pt:M.P/F.P Text:-44F,-42C Vapor Pres:6.8 Spec Gravity:1.5 pH:1 Solubility in Water:COMPLETE Appearance and Odor:LIQUID,TRANSPARENT;CLEAR OR YELLOW;STRONG ACRID ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REDUCING AGENTS,ORGANICS AND COMBUSTIBLES.SEE NFPA FIRE PROTECTION GUIDE FOR SPECIFICS. Stability Condition to Avoid:DECOMPOSES WITH AIR,LIGHT OR ORGANIC MATTER.AVOID HIGH TEMPERATURES,MOISTURE. Hazardous Decomposition Products:NITROGEN OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER D002. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.