FISHER SCIENTIFIC -- IODINE SOLUTION, 0.1N, SI861 -- 6810-00N091256
===================== Product Identification ===================== Product ID:IODINE SOLUTION, 0.1N, SI861 MSDS Date:12/12/1997 FSC:6810 NIIN:00N091256 Status Code:A === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIRLAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100 Chemtrec Ind/Phone:(800)424-9300 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:IODINE. LD50: 14 GM/KG CAS:7553-56-2 RTECS #:NN1575000 = Wt:1.3 OSHA PEL:C1 MG/M3;C0.1 PPM ACGIH STEL:C1.0 MG/M3;C0.1 PPM Ingred Name:POTASSIUM IODIDE CAS:7681-11-0 RTECS #:TT2975000 = Wt:2.8 Ingred Name:WATER. LD50: (ORAL,RAT) >90 ML/KG CAS:7732-18-5 RTECS #:ZC0110000 > Wt:95. ===================== Hazards Identification ===================== Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MEDICAL AID. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR AT LST 15 MINS WHILE REMOVING CONTAMD CLTHG & SHOES. GET MEDICAL AID IF IRRIT DEVELOPS/PERSISTS. INGEST: IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. GET MEDICAL AID. INHAL: REMVOE TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. GET MEDICAL AID IF COUGH/OTHER SYMPTOMS APPEAR. NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY AND SUPPORTIVELY. ===================== Fire Fighting Measures ===================== Lower Limits:N/AV Upper Limits:N/AV Extinguishing Media:USE EXTINGUISHING MEDIA MOST APPROPRIATE FOR THE SURROUDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . MATERIAL WILL NOT BURN. Unusual Fire/Explosion Hazard:NFPA RATING: NOT PUBLISHED. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP SPILLS IMMEDIATELY, OBSERVING PRECAUTIONS IN THE PROTECTIVE EQUIPMENT SECTION. COVER WITH SAND, DRY LIME OR SODA ASH AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. USE WITH ADEQUATE VENTILATION. Other Precautions:STORE IN A COOL, DRY PLACE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A RESP PROT PROGRAM THAT MEETS OSHA'S 29 CFR: 1910.134 & ANSI Z88.2 REQUIREMENT/EUROPEAN STD EN 149 MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:USE PROCESS ENCLOSURE, LOC EXHST VENT/OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health STATE REGULATORY: CAS 7553-56-2: 1. CAS # 7681-11-0: 1. CAS # 7732-18-5: NO INFO AVAIL. CANADA: CAS # 7553-56-2, 7681-11-0, 7732-18-5 IS LISTED ON CANADA'S DSL/NDSL LIST. THIS PROD HAS WHMIS CLASSIFIC ATION OF D2A. CAS # 7553-56-2, 7681-11-0 & 7732-18-5 IS NOT LISTED ON CANADA'S INGRED DISCLOSURE LIST. (OTHER INFO) ================== Physical/Chemical Properties ================== Boiling Pt:=100.C, 212.F Melt/Freeze Pt:=0.C, 32.F Vapor Pres:14 MM HG Vapor Density:0.7 Spec Gravity:1.0 Evaporation Rate & Reference:>1 Solubility in Water:SOLUBLE Appearance and Odor:DARK AMBER LIQUID. IODINE-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES POWDERED ALUMINUM, ACTIVE METALS, STRONG REDUCING AGENTS. ACETYLENE & ACETALDEHYDE CAUSES EXPLOSIVE REACTIONS W/IODINE. MIXTURES W/AMMONIUM HYDROXIDE FORM SHOCK SENSITIVE COMPOUNDS. Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES & PRESSURES. INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:HYDROGEN IODIDE, IODINE, IODIDE IONS (I-). =================== Toxicological Information =================== Toxicological Information:LD50/LC50: CAS # 7553-56-2: ORAL, MOUSE: LD50 = 22 GM/KG; ORAL, RABBIT: LD50 = 10 GM/KG; ORAL,RAT: LD50 = 14 GM/KG. CAS# 7681-11-0. CAS# 7732-18-5: ORAL, RAT: LD50 = >90 ML/KG. CARCINOGENICITY: IODINE , POTASSIUM IODIDE, WATER: NOT LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA. TERATOGENICITY: POTASSIUM IODIDE HAS BEEN OBSERVED TO CAUSE DEVELOPMENTAL ABNORMALITIES OF THE ENDOCRINE SYSTEM IN HUMAN FETU SES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA O-SERIES MAX CONC OF CONTAMINANTS: NONE LISTED. RCRA O-SERIES CHRONIC TOX REFERENCE LEVELS: NONE LISTED. RCRA F,P, & U SERIES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:US DOT, IMO, IATA, RID/ADR & CANADIAN TDG: NO INFORMATION AVAILABLE. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ): NONE OF CHEMICALS IN THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF CHEMICALS IN PRODUCT HAVE TPQ. SARA CODES: CAS # 7553-56-2: ACUTE, CHRONIC, FLAMMABLE. CAS # 7681-11-0: ACUT E, CHRONIC: SECTION 313: NO CHEMICALS ARE REPORTABLE UNDER SECTION 313. Federal Regulatory Information:CLEAN AIR ACT: THIS MATERIAL DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS, CLASS 1 OZONE DEPLETORS & CLASS 2 DEPLETORS. CLEAN WATER ACT: NONE OF CHEMICALS IN THIS PRODUCT ARE LISTED AS HAZARDOUS SUBS TANCES, PRIORITY POLLUTANTS & TOXIC POLLUTANTS UNDER THE CWA.TSCA CAS# 7553-56-2, 7681-11-0, 7732-18-5 ARE LISTED ON THE TSCA INVENTORY. HLTH & SAFETY REPORTING LIST: NONE OF CHEMS ARE ON HLTH & SFT Y REPORTING LIST. CHEM TEST RULES: NONE OF CHEMS IN PROD ARE UNDER A CHEM TEST RULE. SEC 12B: NONE OF CHEMS LISTED UNDER TSCA SEC 12B. TSCA SIGNIFICANT NEW USE RULE: NONE CHEMS IN MATL HAVE SNUR UNDER TSCA. State Regulatory Information:IODINE CAN BE FOUND N FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. POTASSIUM IODIDE IS NOT PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL, OR NJ. WATER IS NOT (PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL, OR NJ. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF CHEMICALS IN PROD ARE LISTED. EUROPEAN/INTERNATIONAL REGS: EUROPEAN LBLG I /A/W EO DIRECTIVES: HAZARD SYMBOLS: XN. RISK PHRASES: ? 22 HARMFUL IF SWALOWED. SAFETY PHRASES: ? 24 /25 AVOID CONT W/SKIN & EYES. WOX (WATER DANGER/PROTECTION): (SUPDAT) ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.