VAN WATERS & ROGERS INC -- P1546, TETRAHYDROFURAN -- 6810-00-982-8496
===================== Product Identification ===================== Product ID:P1546, TETRAHYDROFURAN MSDS Date:05/04/1990 FSC:6810 NIIN:00-982-8496 === Responsible Party === Company Name:VAN WATERS & ROGERS INC Address:1600 NORTON BLDG City:SEATTLE State:WA ZIP:98104-1564 Country:US Info Phone Num:408-435-8700 Emergency Phone Num:800-424-9300(CHEMTREC) CAGE:DO735 === Contractor Identification === Company Name:VAN WATERS & ROGERS SUBSIDIARY OF UNIVAR Address:6100 CARILLON POINT City:KIRKLAND State:WA ZIP:98033 Country:US Phone:425-889-3400 CAGE:DO735 Company Name:VAN WATERS AND ROGERS INC., UNIVAR CORP. Address:1600 NORTON BLDG. 801 2ND AVENUE Box:City:SEATTLE State:WA ZIP:98104-1564 Country:US Phone:206-447-5911/800-424-9300(CHEMTREC) CAGE:87664 ============= Composition/Information on Ingredients ============= Ingred Name:FURAN, TETRAHYDRO-; (TERAHYDROFURAN) CAS:109-99-9 RTECS #:LU5950000 Fraction by Wt: >99% OSHA PEL:200PPM;250 PPM STEL ACGIH TLV:200PPM;250 PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:INHIBITOR Other REC Limits:NONE SPECIFIED Ingred Name:FIRST AID PROC:DO NOT GIVE ANYTHING BY MOUTH TO AN UNCON OR CONVULSING PERSON. RTECS #:9999999ZZ Ingred Name:SPILL PROC: ORG VAP MAY BE SATIS. IN ANY EVENT, ALWAYS WEAR EYE PROT. EXTING ALL IGNIT SOURCES & ENSURE THAT ALL (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:HNDLG EQUIP IS ELECTRICALLY GROUNDED. FOR SM SPILLS/DRIPS, MOP/WIPE UP & DISPOSE OF IN DOT-APPRVD WASTE (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:CONTR. FOR LG SPILLS, CNTN BY DIKING W/SOIL/OTHER NON-COMBUSTIBLE ABSORB MATL & THEN PUMP INTO DOT-APPRVD (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:WASTE CONTR/ABSORB W/NON-COMBUSTIBLE SORBENT MATL. PLACE RESIDUE IN DOT-APPRVD WASTE CONTR. KEEP OUT OF (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:SEWERS, STORM DRAINS, SURF H*2O, & SOIL. COMPLY W/ALL APPLIC GOVT REGS ON SPILL RPTG & HNDLG & DISP OF WASTE. RTECS #:9999999ZZ Ingred Name:OTHER PREC: CONT W/AIR, IT MAY BE APPROP TO FILL CONTR HEADSPACE W/AN INERT GAS, SUCH AS NITROGEN. DO NOT CUT, (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:GRIND/WELD/DRILL ON/NEAR CONTR. CONTR, EVEN THOSE HAVE BEEN EMPTIED, WILL RETAIN PROD RESIDUE & VAP. (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:ALWAYS OBEY HAZ WARNINGS & HNDLE EMPTY CONTR AS IF THEY WERE FULL. DISTILLATION, EVAP/EXPOSE TO LIGHT (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:WILL ACCELERATE PEROXIDE FORMATION. DO NOT DISTILL/BOIL TO DRYNESS. ADDN OF REDUCING AGENTS/H*2O TENDS (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:TO LESSEN PEROXIDE FORMATION. RTECS #:9999999ZZ Ingred Name:RESP PROT: SCBA IN PRESENCE DEMAND MODE, OR A NIOSH/MSHA APPROVED SUPPLIED-AIR RESPIRATOR. RTECS #:9999999ZZ Ingred Name:HYGIENE PRACT: TO THE SEVERITY OF AN EYE INJURY. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL: VAP & MISTS IRRITATE NOSE/THROAT/RESP TRACT. INHAL OF HIGHER CONC MAY CAUSE HDCH/NAUSA/VOMIT, DIZZ & NARC. INHAL OF VERY HIGH CONC/PRLNG EXPOS MAY CAUSE UNCON. EYE: VAP WILL IRRITATE EYES. LIQ & MISTS WILL IRRITATE & MAY BURN EYES. SKIN: BRIEF CONT MAY DRY SKIN. PRLNG/RPTD CONT MAY IRRITATE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: SKIN, CAUSING DERM. INGEST: SWALLOWING QTY CAUSES HDCH, NAUS, VOMIT & PERHAPS UNCON. CHRONIC: PRLNG/RPTD OVEREXPOS MAY RESULT IN DELAYED LIVER AND/OR KIDNEY DAMAGE. Medical Cond Aggravated by Exposure:THIS MATERIAL, OR ITS EMISSIONS MAY AGGRAVATE PULMONARY/BRONCHIAL DISEASE AND OR CAUSE BREATHING DIFFICULTY. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. GIVE ARTF RESP IF NOT BRTHG. GET IMMED MED ATTN. EYE: IMMED FLUSH W/LOTS OF RUNNING H*2O FOR @ LST 15 MIN, LIFT LIDS OCCAS. GET IMMED MED ATTN. SKIN: IMMED WASH W/LOTS OF SO AP & H*2O. REMOVE CONTAMD CLTHG & SHOES; WASH BEFORE REUSE. GET MED ATTN IF IRRIT PERSISTS AFTER WASHING. INGEST: DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE LOTS OF H*2O/MILK. GET IMMED MED ATTN. (ING 3) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:1F,-17C Lower Limits:2% Upper Limits:11.8% Extinguishing Media:USE DRY CHEM, ALCOHOL FOAM, OR CO*2. WATER MAY BE INEFFECTIVE TO FIGHT FIRE BUT MAY BE USED FOR VAPOR SUPPRESSION. Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL NEARBY CONTAINERS AND STRUCTURES EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:EXTING ALL NEARBY SOURCES OF IGNIT SINCE VAP ARE HVR/AIR & MAY TRAVEL CONSIDERABLE DIST TO IGNIT SOURCES & FLASHBACK. AVOID ACCUMULATION OF H*2O (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROT EQUIP INCL POLYVINYL ALCOHOL BOOTS, GLOVES, & APRON, & NIOSH/MSHA APPRVD SCBA IN PRESS DEMAND MODE/NIOSH/MSHA APPRVD SUPPLIED-AIR RESP. IF SPILL/LEAK IS SM, NIOSH/MSHA APPRVD FULL FACEPIECE AIR-PURIFYING CARTRIDGE RESP EQUIPPED FOR (ING 4) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT/SPARKS/FLAMES. STORE IN COOL, DRY, WELL-VENTD PLACE AWAY FROM INCOMPATIBLE MATL. KEEP AIR OUT OF CONTR. Other Precautions:ELECTRICALLY GROUND ALL EQUIP WHEN HNDLG PROD & USE ONLY NON-SPARKING TOOLS. KEEP CONTR TIGHTLY CLSD WHEN NOT IN USE. DO NOT USE PRESS TO EMPTY CONTR. DO NOT GET IN EYES, ON SKIN, OR CLTHG. SINCE PROD DEGRADES UPON STANDING & IN (ING 9) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF USE CNDTNS GENERATE VAP/MISTS, WEAR A NIOSH/MSHA APPRVD RESP APPROP FOR THOSE EMISSIONS LEVELS. APPROP RESP MAY BE A NIOSH/MSHA APPROVD FULL FACEPIECE AIR-PURIFYING CARTRIDGE RESP EQUIPPED FOR ORG VAP/MISTS. A NIOSH/MSHA APPRVD (ING 14) Ventilation:LOC MECH EXHAUST VENT CAPABLE OF MAINTAINING EMISSIONS @ POINT OF USE BELOW PEL. Protective Gloves:POLYVINYL ALCOHOL GLOVES. Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:LONG-SLEEVED SHIRT, TROUSERS, SFTY SHOES, POLYVINYL APRON. AN EYEWASH & SAFETY SHOWER SHOULD BE NEARBY & READY FOR USE. Work Hygienic Practices:WASH THORO AFTER HNDLG. CONT LENSES SHOULD NOT BE WORN WHEN WORKING W/CHEM BECAUSE CONT LENSES MAY CONTRIBUTE (ING 15) Supplemental Safety and Health EXPLO HAZ: BECAUSE PROD WILL FLOAT ON H*2O & MAY BE REIGNITED ON SURF OF H*2O. EXPLO VAP-AIR MIXT MAY BE FORMED ABOVE FL PT/BETWEEN LOWER & UPPER FLAMM LIM. HOT ORG CHEM VAP/MISTS ARE SUSCEPTIBLE TO SUDDEN SPONT COMBUSTION WHEN MIXED W/AIR. IGNIT MAY OCCUR @ TEMP BELOW "AUTOIGNITION" OR "IGNITION TEMPERATURE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:149F,65C Vapor Pres:129-160 Vapor Density:2.5 Spec Gravity:0.9(H*2O=1) Evaporation Rate & Reference:>1(BUTYL ACETATE=1) Solubility in Water:100 Appearance and Odor:ETHER-LIKE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, LITHIUM ALUMINUM HYDRIDE & ALKALINE EARTH HYDROXIDES. Stability Condition to Avoid:HEAT, SPARKS, & OPEN FLAMES. EXPOSURE TO LIGHT, PROLONGED EXPOSURE TO AIR. Hazardous Decomposition Products:ON STANDING AND IN CONTACT WITH AIR FORMS POTENTIALLY UNSTABLE PEROXIDES. Conditions to Avoid Polymerization:POLYM CAN OCCUR IN PRESENCE OF CATIONIC INITIATIORS SUCH AS SELECTGED LEWIS ACIDS/STRONG PROTON ACIDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF CONTAM PROD & MATL USED IN CLEANING UP SPILLS/LEAKS IN MANNER APPRVD FOR MATL. CONSULT APPROP FED/ST/LOC REGULATORY AGENCIES TO ASCERTAIN PROPER DISP PROC. NOTE:EMPTY CONTR CAN HAVE RESIDUE /GASES & MISTS & ARE SUBJECT TO PROPER WASTE DISP. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.