FISHER SCIENTIFIC -- LANTHANUM NITRATE HEXAHYDRATE, L10500 -- 6810-00N050018
===================== Product Identification ===================== Product ID:LANTHANUM NITRATE HEXAHYDRATE, L10500 MSDS Date:08/30/1993 FSC:6810 NIIN:00N050018 === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIRLAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:800-424-9300 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ING 12:FACEPIECE, HELMET/HOOD OPERATED IN CONTINUOUS-FLOW MODE. ANY SCBA W/FULL FACEPIECE OPERATED IN PRESS- (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:DEMAND/OTHER POS PRESS MODE. FOR FIREFIGHTING & OTHER IMMED DANGEROUS TO LIFE/HLTH CNDTNS:ANY SCBA THAT (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:HAS FULL FACEPIECE & IS OPERATED IN PRESS-DEMAND/OTHER POS-PRESS MODE IN COMBINATION W/AUXILIARY SCBA (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE-PRESSURE MODE. RTECS #:9999999ZZ Ingred Name:ING 11:ANY TYPE 'C' SUPPLIED-AIR RESP W/FULL FACEPIECE OPERATED IN PRESS-DEMAND/OTHER POS PRESS MODE/WITH FULL (ING 13) RTECS #:9999999ZZ Ingred Name:LANTHANUM (III) NITRATE, HEXAHYDRATE (1:3:6); (LANTHANUM NITRATE HEXAHYDRATE) CAS:10277-43-7 RTECS #:OE5250000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:FLOOD W/WATER. COOL CNTNRS. APPLY WATER FROM AS GREAT A DISTANCE AS POSSIBLE. EVAC TO DISTANCE OF 2500 FEET. RTECS #:9999999ZZ Ingred Name:EXPLO HAZ:OF COMBUST MATTER. CONT W/EASILY OZIDIZABLE, ORG/OTHER COMBUST MATLS MAY RSLT IN IGNIT. VIOLENT COMBUST/EXPLO. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:SALINE, OCCASNLY LIFTING UPPER & LOWER LIDS, UNTIL NO EVID OF CHEM REMAINS (@ LST 15 MINS). GET (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:MED ATTN IMMED. INGEST:TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET MED ATTN IMMED. IF VOMIT OCCURS, KEEP (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:HEAD LOWER THAN HIPS TO PREVENT ASPIRATION. RTECS #:9999999ZZ Ingred Name:SPILL PROC:ABSORB MATL & PLACE INTO CNTNRS FOR LATER DISP. FOR LARGER SPILLS:DIKE FAR AHEAD OF SPILL FOR LATER (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:DISP. KEEP UNNECESSARY PEOPLE AWAY. ISOLATE HAZARD AREA AND DENY ENTRY. RTECS #:9999999ZZ Ingred Name:RESP PROT: SPECIFIC OPERATION. MUST NOT EXCEED WORKING LIMITS OF RESP & MUST BE APPROVED BY NIOSH. ANY (ING 10) RTECS #:9999999ZZ Ingred Name:ING 11:DUST & MIST RESP W/FULL FACEPIECE. ANY AIR-PURIFYING FULL FACEPIECE RESP W/HIGH-EFFICIENCY PARTICULATE (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:FILTER. ANY POWERED AIR-PURIFYING RESP W/TIGHT-FITTING FACEPIECE & HIGH-EFFICIENCY PARTICULATE FILTER. (ING 12) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) 4500 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:MAY BE IRRITATING TO MUC MEMB. INHAL EXPOS TO SOME RARE EARTH SALTS HAVE CAUSED SENSITIVITY TO HEAT, ITCHING, & INCR AWARENESS OF ODOR & TASTE. SKIN:MAY BE IRRITATING. EYE:MAY BE IRRITATIN G. INGESTION:ORAL TOXICITY OF RARE EARTH SALTS IS ASSUMED TO BE LOW DUE TO POOR GASTROINTESTINAL ABSORPTION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. IF BRTHG HAS STOPPED, PERFORM ARTF RESP. KEEP PERSON WARM & @ REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET MED ATTN IMMED. SKIN:REMOVE CONTAMD CLTHG & SHOES IMMED. WASH AFFECTED AREA W/SOAP OR MILD DETERGENT & LG AMTS OF WATER UNTIL NO EVID OF CHEM REMAINS (APPROX 15-20 MINS). GET MED ATTN IMMED. EYES:WASH IMMED W/LG AMTS OF WATER/NORMAL (ING 4) ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER ONLY, NO DRY CHEM, CO*2/HALON(1990 EMER RESPONSE GUIDEBOOK, DOT 5 5800.5). LARGER FIRES:FLOOD AREA WITH (SUPDAT) Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE CNTNR FROM FIRE AREA IF CAN BE DONE W/OUT RISK. APPLY COOLING WATER TO SIDES OF CNTNR EXPOS TO FLAMES (SUPDAT) Unusual Fire/Explosion Hazard:NEGLIG FIRE HAZ WHEN EXPOS TO HEAT/FLAME. OXIDIZER:OXIDIZERS DECOMPOSE, ESPECIALLY WHEN HEATED, TO YIELD OXYG/OTHER GASES WHICH WILL INCR BURNING RATE (ING 3) ================== Accidental Release Measures ================== Spill Release Procedures:OCCUP SPILL:KEEP COMBUST(WOOD, PAPER, OIL, ETC) AWAY FROM SPILLED MATL. DO NOT TOUCH SPILLED MATL. SM DRY SPILLS:W/CLEAN SHOVEL PLACE MATL INTO CLEAN DRY CNTNR & COVER; MOVE CNTNRS FROM SPILL AREA. SM LIQ SPILLS:TAKE UP W/SAND, EARTH/OTHER(ING 7) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOWING RESPS ARE REC BASED ON INFO FOUND IN PHYSICAL DATA, TOX & HLTH EFTS SECTIONS. THEY ARE RANKED IN ORDER FROM MIN TO MAX RESP PROT. SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM LEVELS FOUND IN WORK PLACE, MUST BE BASED ON (ING 9) Ventilation:PROVIDE LOCAL EXHAUST/GENERAL DILUTION VENTILATION. VENTILATION EQUIPMENT MUST BE EXPLOSION PROOF. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . IMPERVIOUS CLTHG & EQUIP TO PVNT RPTD/PRLNGD SKIN CONT WITH SUBSTANCE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXTING MEDIA:WATER FROM DIST(1990 EMER RESPONSE GUIDEBOOK, DOT P 5800.5). FIRE FIGHT PROC:UNTIL WELL AFTER FIRE IS OUT. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER/MONITOR NOZZ:IF THIS IS IMPOSSIBLE, WITHDRAW FROM AREA & LET FIRE BURN(1990 EMER RESPONSE GUIDEBOOK, DOT P 5800.5, GUIDE PAGE 35). (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:259F,126C Melt/Freeze Pt:M.P/F.P Text:104F,40C Spec Gravity:1.0 Evaporation Rate & Reference:NOT KNOWN Solubility in Water:SOLUBLE Appearance and Odor:ODORLESS, COLORLESS TO WHITE DELIQUESCENT TRICLINIC CRYSTALS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES COMBUSTIBLE MATERIALS:OXIDIZING AMTERIALS MAY REACT VIOLENTLY. REDUCING AGENTS:MAY REACT. Stability Condition to Avoid:AVOID CONT W/COMBUST MATLS (WOOD, PAPER, FUEL, OILS, ETC); IGNIT/EXPLO MAY RSLT. AVOID CONTAM OF WATER SOURCES. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.