MALLINCKRODT BAKER INC -- TEMED, 4098 -- -
===================== Product Identification ===================== Product ID:TEMED, 4098 MSDS Date:02/16/1998 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:MALLINCKRODT BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151 Resp. Party Other MSDS Num.:T2080 Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE; (TETRAMETHYLETHYLENEDIAMINE) CAS:110-18-9 RTECS #:KV7175000 Minumum % Wt:90. Maxumum % Wt:100. ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) 268 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: CORROSIVE. EXTREMELY DESTRUCTIVE TO TISSUES OF THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. SYMPTOMS MAY INCLUDE BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH , HEADACHE, NAUSEA AND VOMITING. INHALATION MAY BE FATAL AS A RESULT OF SPASM, INFLAMMATION AND EDEMA OF THE LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA. INGESTION: CORROSIVE. SWALLOW ING CAN CAUSE SEVERE BURNS OF THE MOUTH, THROAT AND STOMACH. CAN CAUSE SORE THROAT, VOMITING, DIARRHEA. SKIN CONTACT: CORROSIVE. SYMPTOMS OF REDNESS, PAIN AND SEVERE BURN CAN OCCUR. MAY BE ABSORBED TH ROUGH THE SKIN (EFFECTS OF OVEREXPOSURE) Effects of Overexposure:HEALTH HAZARDS: WITH POSSIBLE SYSTEMIC EFFECTS. EYE CONTACT: CORROSIVE. CONTACT CAN CAUSE BLURRED VISION, REDNESS, PAIN AND SEVERE TISSUE BURNS. CHRONIC EXPOSURE: NO INFORMATION FOUND. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MED ATTN IMMED. INGEST: IF SWALLOWED, DO NOT INDUCE VOMITING. GIVE LARGE QUANTITI ES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. GET MED ATTN IMMED. SKIN: IMMED FLUSH SKIN W/PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. GET M ED ATTN IMMED. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE. EYES: IMMED FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING LOWER AND UPPER EYELIDS OCCASIONALLY. GET MED ATTN IMMED. ===================== Fire Fighting Measures ===================== Flash Point:=10.C, 50.F Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE. WATER MAY BE INEFFECTIVE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:FIRE: FLAMMABLE. CONTACT WITH OXIDIZABLE SUBSTANCES MAY CAUSE EXTREMELY VIOLENT COMBUSTION. EXPLOSION: ABOVE THE FLASH POINT, EXPLOSIVE VAPOR-AIR MIXTURES MAY BE FORMED. SEALED CONTAINERS MAY RUPTURE WHEN HEATED. VAPORS CAN FLOW ALONG SURFACES TO DISTANT IGNITION SOURCE AND FLASH BACK. SENSITIVE TO STATIC DISCHARGE. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA OF LEAK OR SPILL. REMOVE ALL SOURCES OF IGNITION. WEAR APPROP PERSONAL PROT EQUIP AS SPECIFIED IN SECTION ON EXPOS CONTROLS/PERSONAL PROT. ISOLATE HAZ AREA. KEEP UNNEC & UNPROTECTED PERS FRO M ENTERING. CONTAIN & RECOVER LIQ WHEN POSS. USE NON-SPARKING TOOLS & EQUIP. COLLECT LIQ IN APPROP CNTNR OR ABSORB W/INERT MATL (EG, VERMICULITE, DRY SAND, EARTH) & PLACE IN CHEM WASTE CNTNR. (SUPDAT) ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DMG. STORE IN COOL, DRY WELL-VENTD LOCATION, AWAY FROM ANY AREA WHERE FIRE HAZ MAY BE ACUTE. OUTSIDE OR DETACHED STORAGE IS PREFERRED. SEPARATE FROM INCOMPATS. CNTNRS SHOULD B E BONDED & GROUNDED FOR TRANSFERS TO AVOID STATIC SPARKS. STORAGE & USE AREAS (ECOLOGICAL INFO) Other Precautions:CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTY SINCE THEY RETAIN PROD RESIDUES (VAPS, LIQS); OBSERVE ALL WARNINGS & PRECS LISTED FOR PROD. DO NOT ATTEMPT TO CLEAN EMPTY CNTNRS SINCE RESIDUE IS DFCLT TO REM OVE. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CNTNRS TO HEAT, (ECOLO GICAL INFO) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR CONDITIONS OF USE WHERE EXPOSURE TO SUBSTANCE IS APPARENT, CONSULT AN INDUSTRIAL HYGIENIST. FOR EMERGENCIES OR INSTANCES WHERE THE EXPOSURE LEVELS ARE NOT KNOWN, USE A NIOSH APPROVED FULL-FACEPIEC E POSITIVE-PRESSURE, AIR-SUPPLIED RESPIRATOR. WARNING: AIR PURIFYING RESPIRATORS DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT ATMOSPHERES. Ventilation:SYSTEM OF LOC &/OR GEN EXHST IS RECOM TO KEEP EMPLOYEE EXPOSURES AS LOW AS POSS. LOC EXHST VENT IS GENERALLY PREFERRED BECAUSE IT CAN CONTROL (ECOLOGICAL INFO) Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:EYE WASH & DELUGE SHOWER MTG ANSI DESIGN CRITERIA . WEAR IMPERVIOUS PROTECTIVE CLOTHING INCLUDING BOOTS, GLOVES, LAB COAT, APRON OR COVERALLS AS APPROPRIATE TO PREVENT SKIN CONTACT. Supplemental Safety and Health SPILL PROC: DO NOT USE COMBUST MATLS, SUCH AS SAW DUST. DO NOT FLUSH TO SEWER! IF A LEAK OR SPILL HAS NOT IGNITED, USE WATER SPRAY TO DISPERSE THE VAPS, TO PROTECT PERS ATTEMPTING TO STOP LEAK & TO FL USH SPILLS AWAY FROM EXPOSURES. JT BAKER SOLUSORB SOLVENT ABSORBENT IS RECOM FOR SPILLS OF THIS PROD. ================== Physical/Chemical Properties ================== Boiling Pt:>120.C, 248.F B.P. Text:120-122C(248-252F) Melt/Freeze Pt:=-55.C, -67.F Vapor Pres:NO INFO FOUND Vapor Density:NO INFO Spec Gravity:0.78 @ 20C/4C pH:NO INFO FOUND Evaporation Rate & Reference:NO INFO FOUND Solubility in Water:SOLUBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; SLIGHT AMMONIA ODOR. Percent Volatiles by Volume:100 @ 21C ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, ACID CHLORIDES, ACID ANHYDRIDES, STRONG OXIDIZING AGENTS, CARBON DIOXIDE, COPPER AND COPPER ALLOYS. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE. AVOID HEAT, FLAMES, IGNITION SOURCES AND INCOMPATIBLES. Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES. =================== Toxicological Information =================== Toxicological Information:INHALATION RAT LC50: 1318 PPM/4-HOUR; SKIN RABBIT LD50: 5390 MG/KG; IRRITATION EYE RABBIT, STANDARD DRAIZE: 750 UG, SEVERE. CANCER LISTS - TETRAMETHYLETHYLENEDIAMINE (110-18-9): NTP CARCINOGEN: KNOWN- NO, ANTICIPATED-NO; IARC CATEGORY-NONE. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL TOXICITY: NO INFORMATION FOUND. --HNDLG/STOR PRECS: SHOULD BE NO SMOKING AREAS. USE NON-SPARKING TYPE TOOLS & EQUIP, INCLUDING EXPLOSION PROOF V ENT. --OTHER PRECS: SPARKS, FLAME, STATIC ELEC OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE & CAUSE INJURY OR DEATH. --VENT: THE EMISSIONS OF THE CONTAMINANT AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO GEN WORK AREA. PLEASE REFER TO ACGIH DOCUMENT, INDUSTRIAL VENTILATION, A MANUAL OF RECOMMENDED PRACTICES, MOST RECENT EDITION, FOR DETAILS. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR RECYCLING SHOULD BE HANDLED AS HAZ WASTE & SENT TO RCRA APPRVD WASTE FACILITY. PROCESSING, USE OR CONTAM OF THIS PROD MAY CHANGE WASTE MANAGEMENT OPTIONS. STAT E & LOCAL DISPOSAL REGS MAY DIFFER FROM FEDERAL DISPOSAL REGS. DISPOSE OF CNTNR & UNUSED CONTENTS I/ A/W FEDERAL, STATE & LOCAL REQS. =================== MSDS Transport Information =================== Transport Information:DOMESTIC (LAND, DOT) - PROPER SHIPPING NAME: 1,2-DI-(DIMETHYLAMINO)ETHANE. HAZARD CLASS: 3. UN/NA: UN2372. PACKING GROUP: II. INFORMATION REPORTED FOR PRODUCT/SIZE: 50ML. INTERNATIONAL (WATER, IMO) - PROPER SHIPPING NAME: 1,2-DI-(DIMETHYLAMINO)ETHANE. HAZARD CLASS: 3.2. UN/NA: UN2372. PACKING GROUP: II. INFORMATION REPORTED FOR PRODUCT/SIZE: 50 ML. ===================== Regulatory Information ===================== SARA Title III Information:FEDERAL, STATE AND INTERNATIONAL REGULATIONS - PART 1: TETRAMETHYLETHYLENEDIAMINE (110-18-9): SARA 302: RQ-NO; TPQ-NO; SARA 313: LIST-NO; CHEMICAL CATG-NO. SARA 311/312: ACUTE: YES; CHRONIC: NO; FIRE: YES; PRESSURE: NO; REACTIVITY: NO (PURE / LIQUID). Federal Regulatory Information:TETRAMETHYLETHYLENEDIAMINE (110-18-9): CHEMICAL INVENTORY STATUS - PART 1: TSCA-YES; EC-YES; JAPAN-YES; AUSTRALIA-YES. CHEMICAL INVENTORY STATUS - PART 2: KOREA-YES; CANADA DSL-YES; NDSL-NO; PHIL-YES. FEDERAL, STATE AND INTERNATIONAL REGULATIONS - PART 2: CERCLA-NO; RCRA 261.33-NO; TSCA 8(D)-NO. CHEMICAL WEAPONS CONVENTION: NO. TSCA 12(B): NO. CDTA: NO. AUSTRALIAN HAZCHEM CODE: 3WE. POISON SCHEDUL E: NONE ALLOCATED. WHMIS: THIS MSDS HAS BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF THE CONTRO LLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS ALL OF THE INFO REQUIRED BY THE CPR. State Regulatory Information:N/P. OTHER INFO: SWALLOWED, DO NOT INDUCE VOMIT. GIVE LG QTYS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. IN ALL CASES GET MED ATTN IMMED. PROD USE: LABORATORY REAGENT. REVISION INFO: MSDS SECTIONS CHANGED SINCE LAST REVISION OF DOCUMENT INCL: 14,15. PREPARED BY: STRATEGIC SERVICES DIVISION (314-539-1600) (USA). MELECULAR WT: 116.21. CHEM FORMULA: C6H16N2. JT BAKER SAF-T-DATA RATINGS: HEALTH: 2-MODERATE; FLAM: 4-EXTREME (FLAM); REACTIVITY: 1-SLIGHT; CONTACT: 2-MODERATE; LAB PROT EQUI P: GOGGS, LAB COAT, VENT HOOD, PROPER GLOVES, CLASS. STORAGE COLOR CODE: RED (FLAM). ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.