FISHER SCIENTIFIC -- CHLOROFORM 04770, BPC298RB-200 -- 6810-00N089568
===================== Product Identification ===================== Product ID:CHLOROFORM 04770, BPC298RB-200 MSDS Date:02/13/1998 FSC:6810 NIIN:00N089568 Status Code:A === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:CHLOROFORM (SARA 302/313) (CERCLA). LD50: (ORAL, RAT) 908 MG/KG. CAS:67-66-3 RTECS #:FS9100000 Fraction by Wt: >99% OSHA PEL:50 PPM, C ACGIH TLV:10 PPM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:EFTS OF OVEREXP: TESTS W/LAB ANIMALS. CHRONIC INGEST MAY CAUSE LIVER DMG. PRLNGD/RPTD SKIN CONTACT MAY CAUSE (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: DERMATITIS. PRLNGD/RPTD EXPOS MAY CAUSE ADVERSE REPRO EFTS. MAY CAUSE FETAL EFTS. CHRONIC EXPOS HAS BEEN (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: ASSOC W/INCREASED INCIDENCE OF KIDNEY, LIVER, RECTAL, BLADDER, COLON, BRAIN & LYMPH NODE CANCER. TOXICITY (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: MAY BE INCREASED BY EXPOS TO ALCOHOL, STEROIDS & KETONES. TARGET ORGANS: KIDNEYS, HEART, CNS, LIVER, GI (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: SYSTEM, EXCRETORY SYSTEM. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: INHAL: GET MED AID IMMED. REMOVE FROM EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: CAUSES CARD SENSIT TO ENDOGENOUS CATELCHOLAMINES WHICH MAY LEAD (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: TO CARD ARRHYTHMIAS. DO NOT USE ADRENERGIC AGENTS SUCH AS EPINEPHRINE OR PSEUDOEPINEPHRINE. ANTIDOTE: NO (ING 8) RTECS #:9999999ZZ Ingred Name:ING 9: SPECIFIC ANTIDOTE EXISTS. RTECS #:9999999ZZ Ingred Name:EYE PROT: & FULL LENGTH FACESHIELD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYE: CONTACT W/LIQ OR VAP CAUSES SEV BURNS & POSS IRREVERSIBLE EYE DMG. VAPS MAY CAUSE EYE IRRIT. SKIN: MAY CAUSE IRRIT W/BURNING PAIN, ITCHING & REDNESS. INGEST: MAY CAUSE CNS DEPRESS, KIDNEY DMG & L IVER DMG. MAY CAUSE GI IRRIT W/NAUS, VOMIT & DIARR. MAY CAUSE CARD DISTURBS. ASPIR OF MATL INTO LUNGS (EFTS OF OVEREXP) Explanation of Carcinogenicity:CHLOROFORM: IARC MONO, SUPP, VOL 7, PG 152, 1987:GROUP 2B. NTP 7TH ANNUAL REPORT ON CARCINS, 1994:ANTIC TO BE CARCIN. Effects of Overexposure:HLTH HAZ: MAY CAUSE CHEM PNEUMIT WHICH MAY BE FATAL. INHAL: INHAL OF HIGH CONCS MAY CAUSE CNS EFTS CHARACTERIZED BY HDCH, DIZZ, UNCON & COMA. CAUSES RESP TRACT IRRIT. MAY CAUSE LIVER & KIDNEY DMG. MAY CAUSE CARD SENSIT & POSS FAILURE. CHRONIC: OVEREXP MAY CAUSE DELAYED KIDNEY INJURY. POSS CANCER HAZ BASED ON (ING 2) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH EYES W/PLENTY OF WATER FOR AT LST 15 MIN, OCCASNLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB OR KEEP EYES CLOSED. SKIN: GET MED AID. RINSE AREA W/LARGE AMTS OF WATER FOR AT LEAST 15 MIN. REMOVE CONTAM CLTHG & SHOES. INGEST: DO NOT INDUCE VOMIT. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. POSS ASPIR HAZ. GET MED AID IMMED. (ING 7) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL OR FOAM. USE EXTINGUISHING MEDIA MOST APPROPRIATE FOR THE SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . SUBSTANCE IS NONFLAMMABLE. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED. ABSORB SPILL WITH INERT MATERIAL (EG, DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. AVOID RUNOFF INTO STORM SEWERS AND DITCHES WHICH LEAD TO WATERWAYS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:WASH THOROUGHLY AFTER HNDLG. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. USE W/ADEQ VENT. DO NOT GET ON SKIN OR IN EYES. AVOID INGEST & INHAL. Other Precautions:DO NOT STORE IN DIRECT SUNLIGHT. STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP AWAY FROM ACIDS. DO NOT STORE NEAR ALKALINE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENT TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 11) Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MATL TO AVOID: ACID, PHOSPHORUS PENTOXIDE, POTASSIUM, POTASSIUM HYDROXIDE, METHYL ALCOHOL, POTASSIUM TERT-BUTOXIDE, SODIUM, SODIUM HYDROXIDE, SODIUM METHYLATE, SODIUM-POTASSIUM ALLOY, TRIISOPROPYLPHOS PHINE, CALCIUM HYDROXIDE, FLUORINE, & ANY STRONG OXIDIZERS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:143F,62C Melt/Freeze Pt:M.P/F.P Text:-82F,-63C Vapor Pres:160 Vapor Density:4.12 Spec Gravity:1.5 (H*2O=1) Evaporation Rate & Reference:11.6 (BUTYL ACETATE=1) Solubility in Water:INSOL (0.5% @ 77F) Appearance and Odor:CLEAR, COLORLESS LIQUID; SWEET, FRUITY ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACETONE, ALKALIS, ALUMINUM, DISILANE, LITHIUM, MAGNESIUM, DINITROGEN DIOXIDE, NITROGEN TETROXIDE, PERCHLORIC (SUPDAT) Stability Condition to Avoid:STABLE AT ROOM TEMP IN CLOSED CNTNRS UNDER NORMAL STORAGE & HNDLG CNDTNS. AVOID HIGH TEMPS, INCOMPATIBLE MATLS, LIGHT. Hazardous Decomposition Products:HYDROGEN CHLORIDE, CARBON DIOXIDE, CHLORINE, PHOSGENE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE AND LOCAL REGULATIONS. CAS #67-66-3 IS BANNED FROM LAND DISPOSAL ACCORDING TO RCRA; RCRA D-SERIES WASTE NUMBER D022; RCRA U-SERIES WASTE NUMBER U0 44. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.