ALDRICH CHEMICAL CO INC -- ETHYLMERCURITHIOSALICYLIC ACID, SODIUM SALT, E35257 -- 6810-00N092203
===================== Product Identification ===================== Product ID:ETHYLMERCURITHIOSALICYLIC ACID, SODIUM SALT, E35257 MSDS Date:07/01/1999 FSC:6810 NIIN:00N092203 Status Code:A === Responsible Party === Company Name:ALDRICH CHEMICAL CO INC Address:1001 WEST ST PAUL City:MILWAUKEE State:WI ZIP:53233 Country:US Info Phone Num:414-273-3850 Emergency Phone Num:414-273-3850 CAGE:60928 === Contractor Identification === Company Name:ALDRICH CHEMICAL CO INC Address:1001 WEST ST PAUL AVE Box:355 City:MILWAUKEE State:WI ZIP:53233 Country:US Phone:414-273-3850 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLMERCURITHIOSALICYLATE SODIUM SALT CAS:54-64-8 RTECS #:OV8400000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL,RAT) 75 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY BE FATAL IF INHALED, SWALLOWED, OR ABSORBED THROUGH SKIN. CAUSES EYE & SKIN IRRITATION. MATL IS IRRITATING TO MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. MAY CAUSE ALLERGIC REACTION. POSSIB LE ALLERGIC REACTION TO DUST IF INHALED,INGESTED OR IN CONTACT WITH SKIN. HYPERSENSITIVITY REACTIONS MAINFESTED BY ERYTHEMA, PAPULAR OR VESICULAR ERUPTIONS OCCUR OCCASIONALLY. ALLERGIC CONJUNCTIVITIS HAS BEEN REPORTED. TARGET ORGAN(S): NERVES, KIDNEYS. TO BEST OF OUR KNOWLEDGE, CHEMICAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. (SYMPTOMS OF OVEREXPOSURE) Effects of Overexposure:HEALTH HAZARDS (CONT): MERCURY-CONTAINING COMPOUNDS APPEAR ON THE NAVY LISTING OF OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST SAFE HANDLING AND EXPOSURE INFORMATION ======================= First Aid Measures ======================= First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHI NG GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN IMMEDIATELY. WASH CONTAMINATED CLOTHING B EFORE REUSE. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. THIS MATERIAL, LIKE MOST MATERIALS IN POWDER FORM, IS CAPABLE OF CREATING A DUST EXPLOSION. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR NIOSH APPRVD SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. ====================== Handling and Storage ====================== Handling and Storage Precautions:HIGHLY TOXIC. VERY TOXIC BY INHAL, IN CONT W/SKIN & IF SWALLOWED. DANGER OF CUMULATIVE EFTS. MAY CAUSE SENSITIZATION BY INHAL & SKIN CONT. IRRITATING TO EYES, RESP SYS & SKIN. KEEP AWAY FROM FOOD, DRI NK & ANIMAL FEEDINGSTUFFS. WEAR SUITABLE PROTECTIVE CLOTHING. DO NOT BREATHE DUST. Other Precautions:DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR. Ventilation:USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves:CHEMICAL-RESISTANT GLOVES. Eye Protection:ANSI APPRVD CHEMICAL WORKERS GOGGLES . Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . OTHER PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health TOX INFO: EFTS ON EMBRYO/FETUS (FETAL DEATH). TUMORIGENIC EFTS (UTERINE TUMORS). NUTRITIONAL & GROSS METABOLIC (CHANGES IN: METABOLIC ACIDOSIS). TUMORIGENIC (NEOPLASTIC BY RTECS CRITERIA), (TUMORS AT SITE OF APPLICATION). ONLY SELECTED REGISTRY OF TOXIC EFTS OF CHEM SUBSTANCES (RTECS) DATA IS PRESENTED HERE.(ECOL INFO) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:>232.C, 449.6F Appearance and Odor:WHITE TO OFF-WHITE POWDER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG BASES. MAY DISCOLOR ON EXPOSURE TO LIGHT. Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE, CARBON DIOXIDE, SULFUR OXIDES. MERCURY/MERCURY OXIDES. =================== Toxicological Information =================== Toxicological Information:IRRIT DATA: EYE-RBT 8 UG MID. TOX DATA:IAL-CHD LDLO: 60 MG/KG/4W-I. ORL-RAT LD50: 75 MG/KG. SCU-RAT LD50: 98 MG/KG. UNR-RAT LD50: 40 MG/KG. ORL-MUS LD50: 91 MG/KG. IPR-MUS LD50: 54 MG/KG. SCU-MUS LD50 : 66 MG/KG. IVN-MUS LD50: 45 MG/KG. JOPDAB 104, 311, 1984. PCOC** -, 2230, 1966. CTOXAO 4, 185, 1971. 30ZDA9 -, 290, 1971. NYKZAU 58, 235, 1962. NYKZAU 58, 235, 1962. QJPPAL 12, 212, 1939. QJPPAL 12, 212, 1939. TARGET ORGAN DATA: BEHAVIORAL (ATAXIA), (COMA). LUNGS, THORAX/RESP (OTHER CHANGES). GI (NAUS/VOMIT). KIDNEY, URETER, BLADDER (CHANGES IN TUBULES). EFTS ON FERTILITY (POST-IMPLANTATION MORTA LITY), (ABORTION). (SUPDAT) ===================== Ecological Information ===================== Ecological:DATA NOT YET AVAILABLE. SUPDAT: ACTUAL ENTRY IN RTECS FOR COMPLETE INFO. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE TO DISPOSE OF THIS MATERIAL. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION. ===================== Regulatory Information ===================== SARA Title III Information:THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS. Federal Regulatory Information:EUROPEAN INFO: VERY TOXIC. R 26/27/28. VERY TOXIC BY INHAL, IN CONT W/SKIN & IF SWALLOWED. R 33. DANGER OF CUMULATIVE EFTS. S 13. KEEP AWAY FROM FOOD, DRINK & ANIMAL FEEDINGSTUFFS. S 28. AFTER CONT W/ SKIN, WASH IMMED W/PLENTY OF WATER. S 36. WEAR SUITABLE PROT CLTHG. S 45. IN CASE OF ACCIDENT/IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED (SHOW LBL WHERE POSS). REVIEWS, STDS, & REGS. OEL=MAK. ACGIH TLV -TWA 0.1 MG(HG)/M3 (SKIN). DTLVS* TLV/BEI, 1997. MSHA STD-AIR: TWA 0.05 MG(HG)/M3 DTLWS* 3,22,1973. OSHA PEL (GEN INDU):8H TWA 0.01 MG(HG)/M3 CFRGBR 29, 1910.1000, 1994. (STATE REGULATORY INFO) State Regulatory Information:FED REGULATORY: OSHA PEL (SHIPYARD): 8H TWA 0.01 MG(HG)/M3 (SKIN) CFRGBR 29, 1915.1000, 1993. OSHA PEL (FED CONT): 8H TWA 0.01 MG(HG)/M3 (SKIN) CFRGBR 41,50-204.50,1994. OEL-AUSTRIALIA: TWA 0.05 MG(HG )/M3;;SKIN JAN 1993. OEL-BELGIUM: TWA 0.05 MG(HG)/M3;SKIN JAN 1993. OEL-DENMARK: TWA 0.05 MG(HG)/M3 JAN 1993. OEL-FINLAND: TWA 0.05 MG(HG)/M3 JAN 1993. OEL-FRANCE: TWA 0.05 MG(HG)/M3 JAN 1993. OEL-GER MANY: TWA 0.01 PPM (0.1 MG(HG/M3) JAN 1993. OEL-HUNGARY: TWA 0.02 MG(HG)/M3;STEL 0.04 MG(HG)/M3 JAN 1993. OEL-JAPAN: TWA 0.05 MG(HG)/M3 JAN 1993. OEL-THE NETHERLANDS: TWA 0.05 MG(HG)/M3; (OTHER INFO) ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.