J T BAKER INC -- V015 SODIUM AZIDE -- 6810-00F027579
===================== Product Identification ===================== Product ID:V015 SODIUM AZIDE MSDS Date:01/15/1986 FSC:6810 NIIN:00F027579 === Responsible Party === Company Name:J T BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865-2219 Country:US Info Phone Num:201-859-2151 Emergency Phone Num:201-859-2151 CAGE:DO803 === Contractor Identification === Company Name:J T BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:1-800-582-2537 CAGE:DO803 Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM AZIDE, AZIDE CAS:26628-22-8 RTECS #:VY8050000 Fraction by Wt: 90-100% Other REC Limits:0.1 PPM OSHA PEL:0.1 PPM ACGIH TLV:C 0.29 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (MOUSE): 27 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. INHALATION: UPPER RESPIRATORY TRACT IRRITATION W/HEADACHE, NAUSEA, DIZZINESS, FATIGUE, CYANOSIS, WEAKNESS IN ARMS & LEGS. SKIN: ABSORPTION & IRRITATION. INGESTION: NAUSEA, VOMITING, HEADACHE, DIZZINESS, GASTROINTESTINAL IRRITATION, BLURRED VISION, LOWERING OF BLOOD PRESSURE. POISON Explanation of Carcinogenicity:NONE Effects of Overexposure:INGESTION/INHALATION: HARMFUL & MAY BE FATAL. POISON ======================= First Aid Measures ======================= First Aid:INGESTION: IF CONSCIOUS, GIVE PLENTY OF WATER. INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR. IF BREATHING STOPS, GIVE ARITIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. EYES/SKIN: FL USH W/WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL OR CO2. DON'T USE WATER. Fire Fighting Procedures:WEAR PROPER PROTECTIVE EQUIPMENT & SELF-CONTAINED BREATHING APPARATUS W/FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE EXPOSED CONTAINERS FROM AREA. Unusual Fire/Explosion Hazard:CAN REACT VIOLENTLY W/SHOCK, FRICTION OR HEAT. DECOMPOSES AT MELTING POINT. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES OR SMOKING IN AREA. SHOVEL INTO CLEAN, DRY CONTAINER & COVER. FLUSH SPILL AREA W/WATER. DON'T A LLOW TO ENTER DRAINS OR SEWER SYSTEM. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE IN COOL, DRY WELL-VENTILATED AREA AWAY FROM IGNITION SOURCES. DON'T STORE NEAR ACIDS OR IN METAL CONTAINERS. Other Precautions:WHEN USING SODIUM AZIDE IN ORGANIC SYNTHESIS REACTIONS, PRODUCTION OF SIGNIFICANT AMOUNTS OF HYDRAZOIC ACID IS POSSIBLE. HYDRAZOIC ACID IS A HIGH EXPLOSION RISK. DON'T GET IN EYES, ON SKIN OR CLOTHING . DON'T BREATH DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE SELF-CONTAINED BREATHING APPARATUS WHEN TLV IS EXCEEDED Ventilation:GENERAL OR LOCAL EXHAUST TO MEET TLV REQUIREMENTS Protective Gloves:RUBBER Eye Protection:SAFETY GOGGLES & FACE SHIELD Other Protective Equipment:UNIFORM OR PROTECTIVE SUIT Supplemental Safety and Health INCOMPATIBLES (CONT'D): BARIUM CARBONATE, BROMINE, DIMETHYL SULFATE. PRODUCT DECOMPOSES AT MELTING POINT. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:275C/527F Decomp Temp:Decomp Text:275C/527F Vapor Density:2.2 Spec Gravity:1.84 Solubility in Water:APPRECIABLE Appearance and Odor:COLORLESS HEXAGONAL CRYSTALS, ODORLESS Percent Volatiles by Volume:0% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, MINERAL ACIDS, HALOGEN ACIDS, HALOGEN COMPOUNDS, COMMON METALS, CARBON DISULFIDE (SEE SUPP) Stability Condition to Avoid:HEAT, FLAME, MOISTURE, SHOCK, FRICTION, & OTHER IGNITION SOURCES Hazardous Decomposition Products:AMMONIA, NITROGEN OXIDES, HYDRAZOIC ACID FUMES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.