FISHER SCIENTIFIC -- CHROMIUM (III) CHLORIDE HEXAHYDRATE, S79962 -- -
===================== Product Identification ===================== Product ID:CHROMIUM (III) CHLORIDE HEXAHYDRATE, S79962 MSDS Date:12/12/1997 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIRLAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100 Chemtrec Ind/Phone:(800)424-9300 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:CHROMIUM (III) CHLORIDE, HEXAHYDRATE. LD50:(ORAL,RAT) 1790 MG/KG. EINECS/ELINCS: UNLISTED. CAS:10060-12-5 RTECS #:GB5450000 = Wt:100. ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: CAUSES IRRITATION. MAY RESULT IN CORNEAL INJURY. SKIN: CAUSES IRRITATION. MAY CAUSE SENSITIZATION, AN ALLERGIC REACTION, WHICH BECOMES EVIDENT UPON RE-EXPOSURE TO THIS MATERIAL. INGESTION: CAUSES GASTROINTESTINAL IRRITATION WITH NAUSEA, VOMITING AND DIARRHEA. INHALATION: CAUSES RESPIRATORY TRACT IRRITATION. CHRONIC: PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS. NO INFORMATIO N FOUND. TARGET ORGANS: NONE. Explanation of Carcinogenicity:CAS # 10060-12-5: ACGIH: A4 - NOT CLASSIFIABLE AS A HUMAN CARCINOGEN (LISTED AS CHROMIUM). IARC: GROUP 3 CARCINOGEN (LISTED AS CHROMIUM) - (INFORMATION TAKEN FROM MSDS). Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING UPPER & LOWER LIDS. IF IRRITATION DEVELOPS, GET MEDICAL AID. SKIN: GET MEDICAL AID. FLUSH WITH PLENTY OF SOAP & WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES. INGESTION: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. GET MEDICAL AID. INHALATION: REMOVE FROM EXPOSURE TO FR ESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL AID. NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY. ===================== Fire Fighting Measures ===================== Flash Point:NOT AVAILABLE Autoignition Temp:Autoignition Temp Text:N/AV Lower Limits:NOT AVAIL Upper Limits:NOT AVAIL Extinguishing Media:USE EXTINGUISHING MEDIA MOST APPROPRIATE FOR THE SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NFPA RATING: NOT PUBLISHED. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION SECTION. VACUUM OR SWEEP UP MATERIAL AND PLACE INTO A SUITABLE DISPOSAL CONTAINER. AVOID GENERATING DUST Y CONDITIONS. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. STORE IN A TIGHTLY CLOSED CONTAINERS. Other Precautions:AVOID CONTACT WITH SKIN AND EYES. KEEP CONTAINER TIGHTLY CLOSED. AVOID INGESTION AND INHALATION. USE WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH FACESHIELD . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT WITH SKIN. Supplemental Safety and Health PHYSICAL AND CHEMICAL PROPERTIES: MOLECULAR FORMULA: CRCL3.6H2O. MOLECULAR WEIGHT: N/P. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NOT AVAILABLE Melt/Freeze Pt:=83.C, 181.4F Decomp Temp:Decomp Text:NOT AVAILABLE Vapor Density:NOT AVAIL Spec Gravity:1.76 pH:2.4 (0.2M SOLN) Solubility in Water:58.5% @ 25C Appearance and Odor:VIOLET SOLID; NO ODOR REPORTED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS VIOLENTLY WITH LITHIUM UNDER NITROGEN ATMOSPHERE. Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. AVOID MOISTURE, STRONG OXIDANTS. Hazardous Decomposition Products:HYDROGEN CHLORIDE. Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED. =================== Toxicological Information =================== Toxicological Information:CAS # 10060-12-5: RTECS # GB5450000. EPIDEMIOLOGY; TERATOGENICITY; REPRODUCTIVE EFFECTS; NEUROTOXICITY; MUTAGENICITY; OTHER STUDIES: NO DATA AVAILABLE. ===================== Ecological Information ===================== Ecological:ECOTOXICITY: NO INFORMATION AVAILABLE. ENVIRONMENTAL FATE: NOT AVAILABLE. PHYSICAL/CHEMICAL: NO INFORMATION AVAILABLE. OTHER STUDIES: NO INFORMATION AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE AND LOCAL REGULATIONS. RCRA: D-SERIES MAXIMUM CONCENTRATION OF CONTAMANTS; D-SERIES CHRONIC TOXICITY REFERENCE LEVELS; F-SERIES; P-SERIES; & U-SER IES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:U.S. DOT: SHIPPING NAME: NO INFORMATION AVAILABLE. IATA: SHIPPING NAME: NO INFORMATION AVAILABLE. RID/ADR: SHIPPING NAME: NO INFORMATION AVAILABLE. IMO: SHIPPING NAME: NO INFORMATION AVAILABLE. CANADA TDG: SHIPPING NAME: NO INFORMATION AVAILABLE. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS IN THIS PRODUCT HAVE A TPQ. SARA CODES: CAS # 10060-12-5: ACUTE, CHRONIC. SECTION 313: THI S MATERIAL CONTAINS CHROMIUM (III) CHLORIDE, HEXAHYDRATE (LISTED AS CHROMIUM), 100%, (CAS # 10060-12-5) WHICH IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III AND 40 CFR PART 373. Federal Regulatory Information:TSCA:CAS #10060-12-5 IS NOT ON TSCA INVENTORY. IT IS HYDRATE & EXEMPT FROM TSCA INVENTORY REQUIREMENTS (40 CFR 720.3(U)(2)). HLTH & SFTY REPORTING LIST:NONE OF CHEMS ARE ON HLTH & SFTY REPORTING LIST. CHEM TEST RULES:NONE OF CHEMS IN THIS PROD ARE UNDER CHEM TEST RULE. SECTION 12B:NONE OF CHEMS ARE LISTED UNDER TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE:NONE OF CHEMS IN THIS MATL HAVE SNUR UN DER TSCA. CLEAN AIR ACT:THIS MATL DOES NOT CONTAIN ANY HAZ AIR POLLUTANTS. THIS MATL DOES NOT CONTAI N ANY CLASS 1 &/OR CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT:NONE OF CHEMS IN THIS PROD ARE LISTED AS HAZ SUBSTANCES;(STATE REGULATORY INFO) State Regulatory Information:CAS #10060-12-5 IS NOT PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL/NJ. CALIFORNIA NO SIGNIFICANT RISK LEVEL:NONE OF CHEMS IN THIS PROD ARE LISTED. -- FED REGULATORY:PRIORITY POLLUTANTS; &/OR TOX PO LLUTANTS UNDER CWA. OSHA:NONE OF CHEMS IN THIS PROD ARE CONSIDERED HIGHLY HAZ BY OSHA. EUROPEAN/INTERNATIONAL REGS:EUROPEAN LABELING I/A/W EC DIRECTIVES:HAZ SYMBOLS:XI. RISK PHRASES:R 36/38 - IRRIT TO EYES & SKIN. SFTY PHRASES: S 26 - IN CASE OF CONT W/EYES, RINSE IMMED W/PLENTY OF WATER & SEEK MED ADVICE; S 28 - AFTER CONT W/SKIN, WASH IMMED W/PLENTY OF ... (TO BE SPECIFIED BY MFR). WGK(WATER DANGER/PROT):CAS # 10060-12-5:(OTHER INFO) ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.