EASTMAN KODAK COMPANY -- 146 4106 RAPID FIXER, PART A -- 6750-01-367-0971
===================== Product Identification ===================== Product ID:146 4106 RAPID FIXER, PART A MSDS Date:01/14/1998 FSC:6750 NIIN:01-367-0971 Kit Part:Y === Responsible Party === Company Name:EASTMAN KODAK COMPANY Address:343 STATE STREET City:ROCHESTER State:NY ZIP:14650 Country:US Info Phone Num:716-477-3194 Emergency Phone Num:716-722-5151 CAGE:19139 === Contractor Identification === Company Name:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS Address:343 STATE ST Box:City:ROCHESTER State:NY ZIP:14650-1115 Country:US Phone:716-722-5151/(800) 242-2424 CAGE:19139 Company Name:EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES Address:800 LEE RD Box:City:ROCHESTER State:NY ZIP:14650-3129 Country:US Phone:800-828-6203 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 40-45% Other REC Limits:NONE RECOMMENDED Ingred Name:AMMONIUM THIOSULFATE CAS:7783-18-8 RTECS #:XN6465000 Fraction by Wt: 40-45% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM ACETATE CAS:127-09-3 RTECS #:AJ4300010 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED Ingred Name:BORIC ACID CAS:10043-35-3 RTECS #:ED4550000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG BORATES/M3 ACGIH TLV:5 MG BORATES/M3 Ingred Name:AMMONIUM SULFITE (CERCLA) CAS:10196-04-0 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID (CERCLA) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM BISULFITE (SASA III) (CERCLA) CAS:7631-90-5 RTECS #:VZ2000000 Fraction by Wt: < 1% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): > 2540 MG/KG Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EXPECTED TO BE A LOW INHALATION HAZARD FOR RECOMMENDED HANDLING. MAY LIBERATE SULFUR DIOXIDE WHICH IS IRRITATING TO RESPIRATORY TRACT. MAY CAUSE TRANSIENT EYE IRRITATION. MAY BE ABSORBED IN TOXIC AMOU NTS THROUGH DAMAGED OR ABRADED SKIN. MAY CAUSE SKIN SENSITIZATION. MAY BE HARMFUL IF SWALLOWED. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:RESPIRATORY TRACT IRRITATION,DIFFICULT BREATHING,EYE IRRITATION,SKIN SENSITIZATION,WHEEZING,CHEST TIGHTNESS,STOMACH UPSET,HIVES,FAINTNESS,WEAKNESS,DIARRHEA. BASED ON REPEATED-DOSE INGESTION STUDIES IN ANIMALS, MAY CAUSE ADVERSE REPRODUCTIVE AND DEVELOPMENTAL EFFECTS. HOWEVER, DOSES MUCH HIGHER THAN NORMAL EXPOSURE. Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING, WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS, DIARRHEA. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: ONLY INDUCE VOMITING AT ADVICE OF MEDICAL PERSONNEL. CALL PHYSICIAN OR POISON CONTROL ASAP. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:NONFLAMMABLE. USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER IF ALLOWABLE WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE TO REMOVE RESIDUA L CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. USE WITH ADEQUATE VENTILATION. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. Other Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. A FULL-FACE POSITIVE-PRESSURE AIR-SUPPLIED RESPIRATOR MUST BE WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE RELEASED OR HAVE BEEN RELEASED. Ventilation:GOOD GENERAL VENTILATION, TYPICALLY 10 AIR CHANGES PER HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS. Protective Gloves:IMPERVIOUS Eye Protection:SAFETY GLASSES W/SIDE SHIELDS OR GOGGLES Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health KEY1:N1. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:>212F,>100C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Decomp Temp:Decomp Text:NOT GIVEN Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.32 pH:5.0 Viscosity:NOT GIVEN Evaporation Rate & Reference:NOT GIVEN Solubility in Water:COMPLETE Appearance and Odor:LIGHT YELLOW LIQUID, SLIGHT SULFUR DIOXIDE, ACETIC ACID ODOR Percent Volatiles by Volume:40-45% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASES, SODIUM HYPOCHLORITE (BLEACH), STRONG OXIDIZING AGENTS, STRONG ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, SULFUR DIOXIDE, AMMONIA, CHLORAMINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL LAWS. MAY REQUIRE NEUTRALIZATION IF PH < 2.0 OR PH > 12.5. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.