J T BAKER INC -- AMMONIUM HYDROXIDE, 9721 -- 6810-01-046-0265
===================== Product Identification ===================== Product ID:AMMONIUM HYDROXIDE, 9721 MSDS Date:09/07/1989 FSC:6810 NIIN:01-046-0265 === Responsible Party === Company Name:J T BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:201-859-2151 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:DO803 === Contractor Identification === Company Name:J T BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:1-800-582-2537 CAGE:DO803 Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM HYDROXIDE (CERCLA). LD50:(ORAL,RAT)350 MG/KG CAS:1336-21-6 RTECS #:BQ9625000 Fraction by Wt: 20-30% OSHA PEL:35 PPM (MFR) ACGIH TLV:25 PPM (MFR) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 70-80% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:SPRAY. IN CASE OF SPILL, CAREFULLY NEUT SPILL W/DILUTE HCL. FLUSH SPILL AREA W/WATER. INTERNATIONAL LBLG: (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:IRRITATING TO EYES, RESP SYS & SKIN. KEEP OUT OF REACH OF CHILDREN. IN CASE OF CONT W/EYES, RINSE IMMED (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:WITH PLENTY OF WATER & SEEK MEDICAL ADVICE. RTECS #:9999999ZZ Ingred Name:EYE PROT:FULL FACESHIELD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHALATION:SEVERE IRRITATION OR BURNS OF RESPIRATORY SYSTEM, PULMONARY EDEMA, LUNG INFLAMMATION. SKIN:SEVERE IRRITATION OR BURNS. EYE:SEVERE IRRITATION OR BURNS, PROLONGED CONTACT MAY CAUSE PERM ANENT CORNEAL DAMAGE, BLINDNESS. INGESTION:IS HARMFUL AND MAY BE FATAL, SEVERE BURNS TO MOUTH, THROAT, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:AND STOMACH, NAUSEA, VOMITING, DIARRHEA. TARGET ORGANS:RESPIRATORY SYSTEM, LUNGS, EYES, SKIN, MUCOUS MEMBRANES. Medical Cond Aggravated by Exposure:SKIN DISORDERS, RESPIRATORY SYSTEM DISEASE. ======================= First Aid Measures ======================= First Aid:INGEST:CALL PHYS. IF SWALLOWED, DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE LG AMTS OF WATER. FOLLOW W/DILUTED VINEGAR, FRUIT JUICE/WHITES OF EGGS, BEATEN W/WATER. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. SKIN:IMMED FLUSH W/PLENTY OF WATER FOR @ LEAST 15 MINS WHILE REMOVING CONTAMD CLTHG & SHOES. WASH CLTHG BEFORE RE-USE. EYE:IMMED FLUSH W/PLENTY (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER SPRAY. Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA W/FULL FACEPIECE OPERATED IN POS PRESS MODE. MOVE EXPOS CNTNRS FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK. USE WATER TO KEEP (SUPDAT) Unusual Fire/Explosion Hazard:GIVES OFF FLAM VAPS. VAPS MAY FORM EXPLO MIX W/AIR. CLSD CNTNRS EXPOS TO HEAT MAY EXPLODE. ANHYDROUS AMMONIA HAS FOLLOWING FLAM LIMS:UPPER-25% & LOWER- (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG. STOP LEAK IF YOU CAN DO SO W/OUT RISK. VENTILATE AREA. CAREFULLY NEUTRALIZE SPILL W/DILUTE HCL. FLUSH AREA W/FLOODING AMTS OF WATER. (USE CAUTION). Neutralizing Agent:J T BAKER NEUTRACIT(R)-2 OR BUCAIM CAUSTIC NEUTRALIZERS. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD. STORE IN CORR-PROOF AREA. STORE BELOW 25C. DO NOT STORE IN DIRECT SUNLIGHT. ISOLATE FROM INCOMPATIBLE MATERIALS. Other Precautions:U.S. PRECAUT LBL:POISON DANGER:CAUSES BURNS. HARMFUL IF INHAL. MAY BE FATAL IF SWALLOWED. EXCEPTIONAL HLTH & CONT HAZ:READ MATL SFTY DATA SHEET. DO NOT GET IN EYES, ON SKIN, ON CLTHG. DO NOT BREATHE V AP. KEEP IN TIGHTLY CLSD CNTNR. (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AT CONC UP TO 300 PPM, NIOSH/MSHA APPRVD CHEM CARTRIDGE RESP W/AMMONIA/AMINE CARTRIDGE & DUST/MIST FILTER IS REC. ABOVE THIS LEVEL, NIOSH/MSHA APPRVD SCBA IS ADVISED. Ventilation:GENERAL OR LOCAL EXHAUST VENT TO MEET TLV REQUIREMENTS. Protective Gloves:RUBBER GLOVES. Eye Protection:ANSI APPRVD CHEM WORK GOGG & (ING 6) Other Protective Equipment:UNIFORM, PROT SUIT, LAB COAT & APRON; VENT HOOD. ANSI APPRVD EMER EYE BATH, AND DELUGE SHOWER . Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING. Supplemental Safety and Health FIRE FIGHT PROC:FIRE-EXPOS CNTNRS COOL; DO NOT GET WATER INSIDE CNTNRS. EXPLO HAZ:16%. AUTOIGNIT TEMP FOR AMMONIA GAS IS 1204F. MATLS TO AVOID:MERCURY, DIMETHYL SULFATE. FIRST AID PROC:OF WATER FOR @ LEAST 15 MINS. OTHER PRECAUT:USE W/ADEQVENT. KEEP CNTNR OUT OF SUN & AWAY FROM HEAT. IN CASE OF FIRE, USE WATER (ING 3) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:-108F,-78C Vapor Pres:570 @ 20C Vapor Density:0.60 Spec Gravity:0.90 (H*2O=1) pH:14 Solubility in Water:COMPLETE (100%) Appearance and Odor:CLEAR, COLORESS LIQUID, PUNGENT ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, MOST COMMON METALS, STRONG OXIDIZING AGENTS, BROMINE, CHLORINE, ALUMINUM, COPPER, BRASS, BRONZE, (SUPDAT) Stability Condition to Avoid:HEAT, SUNLIGHT. Hazardous Decomposition Products:AMMONIA, OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.