MATHESON TRI-GAS, INC. -- N-AMYLAMINE -- -
===================== Product Identification ===================== Product ID:N-AMYLAMINE MSDS Date:Jan 24 1989 Kit Part:=== Responsible Party === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 Chemtrec Ind/Phone:18004249300 === Contractor Identification === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST Box:City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. Address:530 WATSON STREET Box:City:WHITBY State:ZIP:L1N 5R9 Country:ONTARIO, CANADA Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:N-AMYLAMINE CAS:110-58-7 Fraction by Wt: 100.0% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:No OSHA:No Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: burns, difficulty breathing, lung congestion LONG TERM EXPOSURE: same as effects reported in short term exposure SKIN CONTACT: SHORT TERM EXPOSURE: burns, blisters LONG TERM EXPOSURE: same as effects reported in short term exposure EYE CONTACT: SHORT TERM EXPOSURE: irritation (possibly severe), blurred vision LONG TERM EXPOSURE: eye damage INGESTION: SHORT TERM EXPOSURE: burns, sore throat, vomiting, digestive disorders, difficulty breathing LONG TERM EXPOSURE: same as effects reported in short term exposure Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing and shoes before reuse. Destroy contaminated shoes. EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: Never make an unconscious person vomit or drink fluids. Give large amounts of water or milk. DO NOT induce vomiting. If vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. NOTE TO PHYSICIAN: For inhalation, consider oxygen. Avoid gastric lavage or emesis. ===================== Fire Fighting Measures ===================== Flash Point:30 F (-1 C) (CC) Lower Limits:2.2% Upper Limits:22% Extinguishing Media:regular dry chemical, carbon dioxide, water, regular foam, alcohol resistant foam Large fires: Use regular foam or flood with fine water spray. Fire Fighting Procedures:Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Water may be ineffective. Unusual Fire/Explosion Hazard:Severe fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point. ================== Accidental Release Measures ================== Spill Release Procedures:Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:Protect from physical damage. Keep separated from incompatible substances. Avoid heat, flames, sparks and other sources of ignition. Store outside or in a detached building. Store with flammable liquids. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. Protective Gloves:Wear appropriate chemical resistant gloves. Eye Protection:Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:Wear appropriate chemical resistant clothing. Supplemental Safety and Health N-AMYLAMINE: No occupational exposure limits established. ================== Physical/Chemical Properties ================== Boiling Pt:210 F (99 C) Melt/Freeze Pt:-67 F (-55 C) Vapor Pres:Not available Vapor Density:3.0 Spec Gravity:0.8 pH:Not available Evaporation Rate & Reference:Not available Solubility in Water:soluble Appearance and Odor:PHYSICAL STATE:liquid COLOR:colorless ODOR:ammonia odor Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:Stability Condition to Avoid:Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Dangerous gases may accumulate in confined spaces. Keep out of water supplies and sewers. Conditions to Avoid Polymerization:Will not polymerize. =================== Toxicological Information =================== Toxicological Information:N-AMYLAMINE: LOCAL EFFECTS: Corrosive: inhalation, skin, eye, ingestion ACUTE TOXICITY LEVEL: Insufficient Data. ===================== Ecological Information ===================== Ecological:ECOTOXICITY DATA: FISH TOXICITY: 177000 ug/L 96 hour(s) LC50 (Mortality) Fathead minnow (Pimephales promelas) ENVIRONMENTAL SUMMARY: Harmful to aquatic life. ==================== Disposal Considerations ==================== Waste Disposal Methods:Dispose in accordance with all applicable regulations. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: Amylamines ID NUMBER: UN1106 HAZARD CLASS OR DIVISION: 3 PACKING GROUP: II LABELING REQUIREMENTS: Flammable liquid; Corrosive ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes REACTIVE: No SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40 CFR 372.65): Not regulated. Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY (29CFR1910.119): Not regulated. State Regulatory Information: California Proposition 65: Not regulated. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.