J.T. BAKER INC -- ETHER, ANHYDROUS, 9244 -- 6810-00-201-2990
===================== Product Identification ===================== Product ID:ETHER, ANHYDROUS, 9244 MSDS Date:01/04/1994 FSC:6810 NIIN:00-201-2990 Status Code:A === Responsible Party === Company Name:J.T. BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:908-859-2151 Emergency Phone Num:908-859-2151/800-424-8802 Resp. Party Other MSDS Num.:E2350-05 Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYL ETHER; LD50 (ORAL RAT): 1215 MG/KG CAS:60-29-7 RTECS #:KI5775000 Minumum % Wt:97. Maxumum % Wt:100. Other REC Limits:N/K OSHA PEL:1200 MG/M3;400 PPM OSHA STEL:N/K ACGIH TLV:1210 MG/M3;400 PPM ACGIH STEL:1520 MG/M3;500 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ETHANOL; LD50 (ORAL RAT): 7060 MG/KG CAS:64-17-5 RTECS #:KQ6300000 < Wt:2.5 Other REC Limits:N/K OSHA PEL:1900 MG/M3;1000 PPM OSHA STEL:N/K ACGIH TLV:1880 MG/M3;1000 PPM ACGIH STEL:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: CNS DEPRESSION, HEADACHE, NAUSEA, VOMITING, DROWSINESS, IRRITATION OF UPPER RESPIRATORY TRACT, JAUNDICE, LIVER DAMAGE, UNCONSCIOUSNESS. SKIN CONTACT: IRRITATION. PROLONGED CONTACT MAY CAUSE SKIN SENSITIZATION. EYES: IRRITATION. SKIN ABSORPTION: RAPID ABSORPTION, CNS DEPRESSION, HEADACHE, NAUSEA, VOMITING, DROWSINESS, JAUNDICE, LIVER DAMAGE. INGESTION: CNS DEPRESSION, HEADAC HE, NAUSEA, VOMITING, DROWSINESS, NERVOUSNESS, JAUNDICE, LIVER DAMAGE, HEART FAILURE, RESPIRATORY FAILURE, UNCON. CHRONIC: CNS DEPRESSION. TARGET ORGANS: CNS, EYES, SKIN, MUCOUS MEMBRANES, RESPIRATO RY SYSTEM, LUNGS, HEART, LIVER. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE IDENTIFIED. ======================= First Aid Measures ======================= First Aid:INGESTION: CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BR EATHING IS DIFFICULT, GIVE OXYGEN. SKIN: IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE REUSE. EYES: IMMEDI ATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=-45.C, -49.F Autoignition Temp:=180.C, 356.F Lower Limits:1.9% Upper Limits:36% Extinguishing Media:USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. (WATER MAY BE INEFFECTIVE.) Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. NFPA 704AM RATING: 2-4- 1. Unusual Fire/Explosion Hazard:VAPS MAY FLOW ALONG SURFACES OF DISTANT IGNIT SOURCES & FLASH BACK. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONT W/STRONG OXIDIZERS MAY CAUSE FIRE. MAY FORM EXPLOSIVE PEROXIDES, ESPECIALLY W HEN HEATED. FORMS SHOCK-SENSITIVE MIXTURES W/CERTAIN OTHER MATLS. TOX GASES PRODUCED: CARBON MONOXIDE, CARBON DIOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER. Neutralizing Agent:J. T. BAKER SOLUSORB(R) SOLVENT ABSORBENT IS RECOMMENDED FOR SPILLS OF THIS PRODUCT. ====================== Handling and Storage ====================== Handling and Storage Precautions:STOR COLOR CODE: RED (FLAMM). KEEP CONTR TIGHTLY CLSD. STORE IN COOL, DRY, WELL-VENTILATED, FLAMM LIQ STOR AREA. ISOLATE FROM INCOMPATIBLE MATLS. BOND & GROUND CONTRS WHEN TRANSFERRING LIQ. ETHER IS SUBJECT TO PEROXIDE FORM IN OPENED CONTRS & SHOULD BE PROT FROM EXPOS TO AIR AS MUCH AS POSS. Other Precautions:WHEN LOW PEROXIDE ETHER REQ, USE ONLY MATL FROM UNOPENED CAN. DO NOT LET EVAP TO NEAR DRYNESS. ADDN OF WATER/APPROP REDUCING AGENTS WILL LESSEN PEROXIDE FORM. DISCARD ANY REMAINING ETHER IN OPENED CONTRS THAT IS NOT CONSUMED AFTER 2-3 DAYS. USE CAUTION WHEN OPENING CAP. IMPORTANT-DO NOT USE AFT ER EXPIRATION DATE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 1000 PPM, A NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE IS RECOMMENDED. ABOVE THIS LEVEL, A NIOSH APPROVED SCBA IS RECOMMENDED. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Protective Gloves:NITRILE GLOVES. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . UNIFORM, APRON ARE RECOMMENDED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:=35.C, 95.F B.P. Text:@ 760 MM HG Melt/Freeze Pt:=-115.6C, -176.F M.P/F.P Text:@ 760 MM HG Vapor Pres:442 MMHG @ 20C Vapor Density:2.6(AIR=1) Spec Gravity:0.71 (H*2O=1) Evaporation Rate & Reference:37.5 (BUTYL ACETATE=1) Solubility in Water:MODERATE (1-10%) Appearance and Odor:CLEAR, COLORLESS LIQUID WITH CHARACTERISTIC ODOR. Percent Volatiles by Volume:100 @ 21C ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG BASES, STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION, LIGHT, AIR. Hazardous Decomposition Products:EXPLOSIVE PEROXIDES, CARBON MONOXIDE, CARBON DIOXIDE. =================== Toxicological Information =================== Toxicological Information:DIETHYL ETHER: INTRAVENOUS MOUSE LD50: 996 MG/KG. INTRAPERITONEAL MOUSE LD50: 2420 MG/KG. INHALATION-2HR RAT LC50: 73.0 PPT. ETHANOL: INTRAPERITONEAL RAT LD50: 4070 MG/KG. INTRAVENOUS RAT LD50: 14 40 MG/KG. INHALATION-4HR MOUSE LC50: 39 G/M. CARCINOGENICITY: NONE IDENTIFIED. REPRODUCTIVE EFFECTS: NONE IDENTIFIED. ===================== Ecological Information ===================== Ecological:DIETHYL ETHER: MARINE POLLUTANTS: NO. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: U117 (TOXIC WASTE). =================== MSDS Transport Information =================== Transport Information:DOMESTIC (D.O.T.): PROPER SHIPPING NAME: DIETHYL ETHER. HAZARD CLASS: 3. UN/NA: UN1155. PACKAGING GROUP: I. LABELS: 3 FLAMMABLE LIQUID. REGULATORY REFERENCES: 49CFR 172.101. INTERNATIONAL (I.M. O.): PROPER SHIPPING NAME: DIETHYL ETHER. HAZARD CLASS: 3.1. I.M.O. PAGE: 3117. UN: UN1155. PACKAGING GROUP: I. LABELS: FLAMMABLE LIQUID. REGULATORY REFERENCES: 49CFR PART 176; IMDG CODE. AIR (I.C.A.O.): PROPER SHIPPING NAME: DIETHYL ETHER. HAZARD CLASS: 3. UN: UN1155. PACKAGING GROUP: I. LABELS: FLAMMABLE LIQUID. U.S CUSTOMS HARMONIZATION NUMBER: 29091100005 ===================== Regulatory Information ===================== SARA Title III Information:SARA 313 TOXIC CHEMICALS: NO Federal Regulatory Information:REGULATORY REFERENCES: 49CFR PART 175; ICAO. EXTREMELY HAZARDOUS SUBSTANCE: NO. CERCLA HAZARDOUS SUBSTANCE: YES CONTAINS ETHANE, 1,1'-OXYBIS- (RQ = 100 LBS), SARA 313 TOXIC CHEMICALS: NO. TSCA IN VENTORY: YES. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.