SIGMA CHEMICAL CO -- D-(+)-GLUCOSE ANHYDROUS ACS REAGENT, G5767  -- 6550-00N093195
<pre>=====================  Product Identification  =====================

Product ID:D-(+)-GLUCOSE ANHYDROUS ACS REAGENT, G5767
MSDS Date:01/01/1999
FSC:6550
NIIN:00N093195
Status Code:A
=== Responsible Party ===
Company Name:SIGMA CHEMICAL CO
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:314-771-5765
Emergency Phone Num:314-771-5765
CAGE:21076
=== Contractor Identification ===
Company Name:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076

=============  Composition/Information on Ingredients  =============

Ingred Name:D(+)-GLUCOSE
CAS:50-99-7
RTECS #:LZ6600000
= Wt:100.

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50: (ORAL,RAT) 25800 MG/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE EFFECTS: MAY BE HARMFUL BY
    INHALATION, INGESTION, OR SKIN ABSORPTION. MAY CAUSE IRRITATION.
Effects of Overexposure:SEE HEALTH HAZARDS.

=======================  First Aid Measures  =======================

First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS
    AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. IN CASE OF CONTACT,
    IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. IF
    INHALED, REMOVE T O FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED,
    WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A
    PHYSICIAN. WASH CONTAMIN ATED CLOTHING BEFORE REUSE.

=====================  Fire Fighting Measures  =====================

Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
    APPROPRIATE FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

==================  Accidental Release Measures  ==================

Spill Release Procedures:CHEMICAL SAFETY GOGGLES. USE PROTECTIVE
    CLOTHING, GLOVES AND MASK. SWEEP UP, PLACE IN A BAG AND HOLD FOR
    WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL
    SITE AFTER MATERIAL PICKUP IS  COMPLETE.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN
    EYES, ON SKIN, ON CLOTHING. KEEP TIGHTLY CLOSED. STORE IN A COOL
    DRY PLACE.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH -APPROVED RESPIRATOR IN NONVENTILATED
    AREAS AND/OR FOR EXPOSURE ABOVE THE ACGIH TLV.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:COMPATIBLE CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
WASTE DISP METH: DOUBT ABOUT SUITABILITY OF METHOD USE LICENSED WASTE
    DISP COMPANY. OBSERVE ALL FEDERAL, STATE & LOCAL ENVIRONMENTAL
    REGS. TOX INFO: SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTU
    AL ENTRY IN RTECS FOR COMPLETE INFORMATION.

==================  Physical/Chemical Properties  ==================

Melt/Freeze Pt:>153.C, 307.4F
M.P/F.P Text:153 C TO 156 C
Appearance and Odor:WHITE POWDER.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
    CARBON DIOXIDE.

===================  Toxicological Information	===================

Toxicological Information:SEE HEALTH HAZS. RTECS #: LZ6600000.
    D-GLUCOSE. TOX DATA: ORL-RAT LD50:25800 MG/KG 85AIAL -,39,1973.
    IPR-MUS LD50:18 GM/KG PSEBAA 35,98,1936. IVMUS LD50:9 GM/KG ARZNAD
    18,666,1968. TARGET ORGAN DATA:  MATERNAL EFTS (OTHER EFT ON
    FEMALE). EFTS OF FERTILITY (POST-IMPLANTATION MORTALITY) EFTS ON
    EMBRYO/FETUS (OTHER EFTS TO EMBYRO/FETUS). SPECIFIC DEVELOPMENTAL
    ABNORMALITIES (CRANIOFACIAL), (HEPATOBILI ARY SYS), (UROGENITAL
    SYS), (OTHER DEVELOPMENTAL ABNORMALITIES). EFTS ON NEWBORN
    (BIOCHEMICAL & METABOLIC), (BEHAVIORAL). ONLY SELECTED REGISTRY OF
    TOXIC EFTS OF CHEM (SUPDAT)

=====================  Ecological Information  =====================

Ecological:DATA NOT YET AVAILABLE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISSOLVE IN WATER & DILUTE TO 5% SOLN. CHECK PH
    & ADJUST IT TO 7 IF NECESSARY. POUR SOLN DOWN DRAIN W/RUNNING WATER
    & CONTINUE TO FLUSH DRAIN SYS FOR 10 MINS, PROVIDED RULES AT PLACE
    OF EMPLOYMENT/LOC AL, STATE & FEDERAL GUIDELINES ALLOW YOU TO DO
    SO. IF YOU ARE UNABLE TO FLUSH SOLN DOWN DRAIN OR IN  (SUPDAT)

===================  MSDS Transport Information  ===================

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
    INFORMATION.

=====================  Regulatory Information  =====================

Federal Regulatory Information:REVIEWS, STANDARDS, AND REVIEWS.
    OEL=MAK. NOHS 1974: HZD 81836; NIS 117; TNF 16738; NOS 90; TNE
    136870. NOES 1983: HAZD 81836; NIS 86; TNF 11017; NOS 102; TNE
    363666; TFE 186490. EPA GENETOX PROGRAM 1 988, NEGATIVE: SPERM
    MORPHOLOGY-MOUSE. EPA GENETOX PROGRAM 1988, INCONSLUSIVE: MAMMALIAN
    MICRONUCLEUS. EPA TSCA SECTION 8(B) CHEMICAL INVENTORY. EPA TSCA
    SECTION 8 (D) UNPLUBHISED HEATH/SAFETY STUDIES . EPA TSCA TEST
    SUBMISSION (TSCATS) DATA BASE, JUNE 1998.

=======================  Other Information  =======================

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