FISHER SCIENTIFIC -- M143I50, MERCURIC ACETATE -- 6810-00N027032
===================== Product Identification ===================== Product ID:M143I50, MERCURIC ACETATE MSDS Date:10/29/1991 FSC:6810 NIIN:00N027032 === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410-2802 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:FIRST AID PROC:OF CHEM REMAINS (APPROX 15-20 MIN). GET MED ATTN IMMED. EYE: WASH IMMED W/LG AMTS OF WATER/NORM (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:SALINE, OCASIONALLY LIFTING UPPER & LOWER LIDS, UNTIL NO EVIDENCE OF CHEM REMAINS (APPROX 15-20 MIN).GET (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:MED ATTN IMMED. INGEST: REMOVE BY GASTRIC LAVAGE/EMESIS. MAINTAIN BLOOD PRESS & AIRWAY. GIVE O*2 IF RESP (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:DEPRESSED.DO NOT PERFORM GASTRIC LAVAGE/EMESIS IF UNCON. GET MED ATTN IMMED. ADMIN OF GASTRIC LAVAGE/O*2 (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:SHLD BE PERFORMED BY QUALIFIED MED PERSONNEL.ANTIDOTE: DECISION AS TO WHETHER SEVERITY OF POISONING REQS (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:ANTIDOTE & ACTUAL DOSE REQD SHLD BE MADE BY QUALIFIED MED PERSONNEL. GIVE N-ACETYL-D, L-PENICILLAMINE (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:(OR IF NOT AVAIL D-PENICILLAMINE) BY MOUTH, 250 MG, 4 TIMES DAILY FOR 5-10 DAYS.DIMERCAPROL IS LESS (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:EFFECTIVE AND MAY BE CONTRAINDICATED. ANTIDOTE SHLD BE ADMINISTERED BY QUALIFIED MEDICAL PERSONNEL. RTECS #:9999999ZZ Ingred Name:SPILL PROC: DIKE FAR AHEAD OF SPILL FOR LATER DISPOSAL. KEEP UNNEC PEOPLE AWAY. ISOLATE HAZARD AREA AND DENY ENTRY. RTECS #:9999999ZZ Ingred Name:MERCURIC ACETATE CAS:1600-27-7 RTECS #:AI8575000 Fraction by Wt: 100% OSHA PEL:0.1 (HG) MG/M3, C, S ACGIH TLV:0.1 (HG) MG/M3, S Ingred Name:SUPP DATA: NEUROPATHY & KIDNEY DAM. EYE: ACUTE: MAY CAUSE IRRIT. CORR SOLNS MAY CAUSE CORNEAL INJURY/BURNS. (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:CHRONIC:MAY BE DEPOSITIED IN LENS OF EYE, CAUSING VISUAL DISTURBANCES. INGEST:ACUTE:NECROSIS BEGINS IMMED (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:IN MOUTH, THROAT, ESOPHAGUS & STOM. W/IN FEW MIN, VIOLENT PAIN, PROFUSE VOMIT & SEV PURGING OCCUR. PATIENT (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:MAY DIE FEW MINS FROM FLUID/ELECTROLYTE LOSSES & PERIPHERAL VASULAR COLLAPSE, BUT DEATH (FROM UREMIA) IS (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:USUALLY DELAYED 5-12 DAYS. IF SURVIVES PRIMARY GI DISTURBANCES USUALLY SUBSIDE. SECOND PHASE DEVELOPS W/IN (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:1-3 DAYS AFTER EXPOS. CHARACTERIZED BY INFLAMM OF MOUTH, MEMBRANOUS COLITIS & TUBULAR NEPHROSIS. SALIVARY (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:GLANDS, KIDNEYS, AND GI MUCOSA SLOWLY EXCRETE MERCURY. DEATH MAY OCCUR FROM RENAL FAILURE. LETHAL DOSE FOR (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:ADULTS IS 1-4 GRAMS.CHRONIC: MANIFESTATIONS OF POISONING ARE METALLIC TASTE, EXCESSIVE (ING 8) RTECS #:9999999ZZ Ingred Name:ING 9:SALIVATION, GINGIVITIS, PYORRHEA W/LOOSE TEETH, DIGESTIVE DISORDERS, ABDOM DISTRESS & SKIN ERUPTIONS (ING 9) RTECS #:9999999ZZ Ingred Name:ING 10:PROGRESSING TO DERM. SENSORY & MOTOR NERVES MAY BE AFFECTED W/NUMBNESS & WEAKNESS. LIVER & KIDNEY DAM (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:OCCUR PROGRESSING TO ACUTE RENAL FAILURE W/ANURIA. SUBTLE/DRAMATIC BEHAVIOR & PERSONALITY CHANGES (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:(ERITHISM) HAVE BEEN ASSOCIATED W/POISONING. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) 40.9 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL:DUST MAY CAUSE SORE THROAT, COUGHING, DYSPNEA, LABORED BRTHG & PULMONARY EDEMA. VAP CAN CAUSE ALMOST IMMEDIATE DYSPNEA, COUGH, FEVER, NAUS, VOM, DIARR, INFLAMM OF MOUTH, SALIVATION & METALLIC TA STE. MAY RESOLVE/PROGRESS TO NECROTOZING BRONCHIOLITIS, PNEUMONITIS, PULM EDEMA & PNEUMOTHORAX. (EFTS OF OVEREXPOS) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:ACIDOSIS & RENAL DAM & FAILURE MAY OCCUR.CHRONIC:MAY CAUSE MERCURIALISM, W/TREMORS, SALIVATION, INFLAMM OF MOUTH, LOOSE TEETH W/BLUE LINES ON GUMS,PAIN & NUMBNESS IN EXTREMETIES, NEPHRITIS, D IARR, ANXIETY, HDCH, WT LOSS, ANOREXIA,MENTAL DEPRESS, INSOMNIA, IRRITABILITY, INSTABILITY & HALLUCINATIONS.(SUPP DATA) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE TO FRESH AIR IMMED. IF BRTHG HAS STOPPED, GIVE ARTF RESP. MAINTAIN AIRWAY & BLOOD PRESS & ADMIN O2 IF AVAIL. KEEP AFFECTED PERS WARM & @ REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. ADMIN OF O2 SHLD BE PERFORMED BY QUALIFIED PERSONNEL. GET MED ATTN IMMED. SKIN: REMOVE CONTAMD CLTHG & SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LG AMTS OF WATER UNTIL NO EVIDENCE (ING 14) ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY/REGULAR FOAM. FOR LARGER FIRES USE WATER SPRAY, FOG OR REGULAR FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . MOVE CNTNR FROM FIRE AREA IF CAN DO WITHOUT RISK. USE AGENTS SUITABLE FOR TYPE OF FIRE. USE (SUPP DATA) Unusual Fire/Explosion Hazard:NEGLIG FIRE HAZ WHEN EXPOS TO HEAT/FLAME.MAY BURN BUT DOES NOT IGNITE READILY.PVNT DISPERSION OF DUST IN AIR. DO NOT ALLOW SPILLED MATL TO CONTAM WATER SOURCES. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH SPILLED MATL.STOP LEAK IF W/OUT RISK.SM SPILLS: TAKE UP W/SAND/OTHER ABSORBENT & PLACE INTO CNTNRS FOR LATER DISP.SM DRY SPILLS:W/CLEAN SHOVEL PLACE MATL INTO CLEAN, DRY CNTNR & COVER.MOV E CNTNRS FROM SPILL AREA. LARGER SPILLS: (ING 22) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE. FOR ASSITANCE, CONTACT DISTRICT DIRECTOR OF EPA. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:THE SPECIFIC RESIRATOR SELECTED MUST BE BASED ON CONTAMINATION LEVELS FOUND IN WORK PLACE, MUST NOT EXCEED THE WORKING LIMITS OF THE RESPIRATOR AND BE JOINTLY APPROVED BY NIOSH/MSHA. FOR MORE SPECIFIC INFORMATION CONTACT NEHC . Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS. VENTILATION EQUIPMENT MUST BE EXPOSION-PROOF. Protective Gloves:PROTECTIVE GLOVES. Eye Protection:CHEM WORK GOG & FULL LGTH FSHLD . Other Protective Equipment:IMPERV CLTHG & EQUIP TO PVNT RPTD/PRLNGD SKIN CONT. EYE WASH FOUNTAIN & QUICK DRENCH SHOWER W/IN IMMEDIATE WORK AREA. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC: WATER IN FLOODING AMOUNTS AS FOG. AVOID BREATHING TOXIC VAPORS, KEEP UPWIND.HLTH HAZ:SKIN:ACUTE:MAY CAUSE REDNESS, IRRIT & SENSITIZATION DERM IN PREVIOUSLY EXPOSED WORKERS. MAY BE ABS ORBED THRU SKIN CAUSING ANURIA. CHRONIC: MAY CAUSE IRRIT & SENSITIZATION DERM, PSYCHIC DISTURBANCES, PERIPHERAL (ING 2) ================== Physical/Chemical Properties ================== HCC:T3 Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:M.P/F.P Text:354F,179C Spec Gravity:3.3 Solubility in Water:25% @ 10C Appearance and Odor:WHITE CRYSTALLINE POWDER; ACETIC ODOR; SENSITIVE TO LIGHT. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO DATA AVAILABLE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY RELEASE TOXIC AND HAZARDOUS MERCURY VAPORS AND CARBON MONOXIDE UNDER THERMAL DECOMP/UPON EXPOSURE TO LIGHT. ==================== Disposal Considerations ==================== Waste Disposal Methods:MATLS WHICH CONTAIN MERCURY-REGULATORY LEVEL: 0.2 MG/L @/> REGULATORY LEVEL MEET EPA CHARACTERISTIC OF TOXICITY, AND MUST BE DISPOSED OF I/A/W 40 CFR PART 262. EPA HAZ WASTE NUMBER D009. DISPOSE OF I/ A/W FEDERAL, STATE AND LOCAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.