Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
75-64-9	tert-Butylamine	99	200-888-1

Section 3 - Hazards Identification

Appearance: colorless liquid. Flash Point: -9 deg C.
Danger! Extremely flammable liquid. Corrosive. Harmful if swallowed. May cause respiratory and digestive tract burns. Causes eye and skin irritation and possible burns. Causes digestive and respiratory tract irritation. Air sensitive.
Target Organs: None.


Potential Health Effects
Eye: Causes eye irritation and possible burns.
Skin: Causes severe skin irritation and possible burns.
Ingestion: Harmful if swallowed. Causes gastrointestinal tract burns. May cause perforation of the digestive tract.
Inhalation: Causes chemical burns to the respiratory tract. May cause pulmonary edema and severe respiratory disturbances. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic: No information found.

Section 4 - First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. Extremely flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Contact professional fire-fighters immediately.
Flash Point: -9 deg C ( 15.80 deg F)
Autoignition Temperature: 380 deg C ( 716.00 deg F)
Explosion Limits, Lower:1.70 vol %
Upper: 8.90 vol %
NFPA Rating: (estimated) Health: ; Flammability: ; Instability:

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Use a spark-proof tool.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Use only in a well-ventilated area. Ground and bond containers when transferring material. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Take precautionary measures against static discharges. Keep away from heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
tert-Butylamine	none listed	none listed	none listed

OSHA Vacated PELs: tert-Butylamine: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: colorless
Odor: amine-like
pH: Not available.
Vapor Pressure: 362 mm Hg @ 25 C
Vapor Density: 2.5
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 46 deg C @ 760.00mm Hg
Freezing/Melting Point:-67 deg C
Decomposition Temperature:Not available.
Solubility: Miscible.
Specific Gravity/Density:.6960g/cm3
Molecular Formula:C4H11N
Molecular Weight:73.13

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: High temperatures, mechanical shock, ignition sources.
Incompatibilities with Other Materials: Strong oxidizing agents, acids, organic acids, isocyanates, alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene glycol), phenols and cresols (e.g. carbolic acid, creosote, cresol, phenol, resorcinol).
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:      
CAS# 75-64-9: EO3330000
LD50/LC50:
CAS# 75-64-9:
     Inhalation, rat: LC50 = 3800 mg/m3/4H;
     Oral, rat: LD50 = 44 mg/kg;
.

Carcinogenicity:
CAS# 75-64-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	AMINES, FLAMMABLE, CORROSIVE, N.O.S.	AMINES, CORROSIVE,FLAMMABLE NOS
Hazard Class:	3	3(8)
UN Number:	UN2733	UN2733
Packing Group:	II	II
Additional Info:		FLASHPOINT -10 C

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 75-64-9 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 75-64-9: 1000 lb final RQ (Listed under Butylamine); 454 kg final RQ (Listed under Butyla
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 75-64-9: immediate, fire.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 75-64-9 is listed as a Hazardous Substance under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 75-64-9 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN F+
Risk Phrases:
     R 11 Highly flammable.
     R 25 Toxic if swallowed.
     R 34 Causes burns.
     R 20 Harmful by inhalation.

Safety Phrases:
     S 16 Keep away from sources of ignition - No smoking.
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 29 Do not empty into drains.
     S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
     otection.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).
     S 28A After contact with skin, wash immediately with plenty of water
     .

WGK (Water Danger/Protection)
     CAS# 75-64-9: 1
Canada - DSL/NDSL
     CAS# 75-64-9 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of B2, D1B, D2B, E.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 5/12/1998
Revision #4 Date: 10/03/2005

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.