GOUGEON BROTHERS, INC -- WEST SYSTEM 205 FAST HARDENER, 205 -- 8030-00N026606
===================== Product Identification ===================== Product ID:WEST SYSTEM 205 FAST HARDENER, 205 MSDS Date:01/03/1998 FSC:8030 NIIN:00N026606 Status Code:A === Responsible Party === Company Name:GOUGEON BROTHERS, INC Address:100 PATTERSON AVE City:BAY CITY State:MI ZIP:48706 Country:US Info Phone Num:517-684-7286 Emergency Phone Num:313-745-5711 Resp. Party Other MSDS Num.:205-98A Chemtrec Ind/Phone:(800)424-9300 CAGE:7S147 === Contractor Identification === Company Name:GOUGEON BROTHERS INC Address:100 PATTERSON AVE City:BAY CITY State:MI ZIP:48706 Country:US Phone:517-684-7286 CAGE:75147 Company Name:GOUGEON BROTHERS, INC Address:100 PATTERSON AVE Box:City:BAY CITY State:MI ZIP:48706 Country:US Phone:517-684-7286 CAGE:7S147 ============= Composition/Information on Ingredients ============= Ingred Name:POLYAMINE N 7; (POLYETHYLENEPOLYAMINE) CAS:29320-38-5 < Wt:25. Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K Ingred Name:REACTION PRODUCTS OF TETA WITH PHENOL/FORMALDEHYDE CAS:32610-77-8 < Wt:25. Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K Ingred Name:TRIETHYLENETETRAMINE (TETA) CAS:112-24-3 RTECS #:YE6650000 < Wt:15. Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K Ingred Name:HYDROXYBENZENE CAS:108-95-2 RTECS #:SJ3325000 < Wt:12. Other REC Limits:N/K OSHA PEL:19 MG/M3;5 PPM OSHA STEL:N/K ACGIH TLV:19 MG/M3;5 PPM ACGIH STEL:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TRIETHYLENETETRAMINE, POLYMER WITH PROPYLENE OXIDE; (REACTION PRODUCTS OF TETA AND PROPYLENE OXIDE) CAS:26950-63-0 < Wt:12. Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K Ingred Name:TETRAETHYLENEPENTAMINE (TEPA) CAS:112-57-2 RTECS #:KH8585000 < Wt:12. Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION. COUGHING AND CHEST PAIN MAY RESULT. SKIN: MAY CAUSE STRONG IRRITATION, REDNESS. EYES: MODERATE TO SEVERE EYE IRRITANT. CONCENTRATED VAPORS CA N BE ABSORBED IN EYE TISSUE AND CAUSE EYE INJURY. CONTACT CAUSES IRRITATION, REDNESS AND DISCOMFORT AND POSSIBLE CORNEAL INJURY OR CONJUNCTIVITIS. INGESTION: SINGLE DOSE ORAL TOXICITY IS MODERATE. MAY CAUSE GASTROINTESTINAL TRACT IRRITATION AND PAIN. CHRONIC: INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION, COUGHING, SORE THROAT, SHORTNESS OF BREATH OR CHEST PAIN. (EFFECTS OF OVEREXPOSURE) Effects of Overexposure:HEALTH HAZARDS: SKIN: PROLONGED OR REPEATED CONTACT MAY CAUSE AN ALLERGIC REACTION AND POSSIBLE SENSITIZATION IN SUSCEPTIBLE INDIVIDUALS. MAY BE ABSORBED IN HARMFUL AMOUNTS. SYMPTOMS OF OVEREXPOSURE: RESPIRATORY TRACT IRRITATION. SKIN IRRITATION AND REDNESS. POSSIBLE ALLERGIC REACTION SEEN AS HIVES AND RASH. EYE IRRITATION. Medical Cond Aggravated by Exposure:CHRONIC RESPIRATORY DISEASE, ASTHMA. EYE DISEASE. SKIN DISORDERS AND ALLERGIES. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET PROMPT MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. IMMEDIATELY WASH SKIN WITH SOAP AND WATER. DO NOT APPLY GREASES OR OINTMEN TS. INHALATION: MOVE TO FRESH AIR AND CONSULT PHYSICIAN IF EFFECTS OCCUR. INGESTION: GIVE CONSCIOUS PERSON AT LEAST 2 GLASSES OF WATER. DO NOT INDUCE VOMITING. IF VOMITING SHOULD OCCUR SPONTANEOUSLY, KEEP AIRWAY CLEAR. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>132.2C, 270.F Extinguishing Media:WATER FOG, ALCOHOL FOAM, CARBON DIOXIDE (CO*2), DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . IF SPILL HAS IGNITED, USE WATER SPRAY TO DISPERSE VAPORS AND PROTECT PERSONNEL ATTEMPTING TO STOP LEAK. USE WATER TO COOL FIRE-EXPOSED CO NTAINERS. Unusual Fire/Explosion Hazard:WHEN MIXED WITH SAWDUST, WOOD CHIPS, OR OTHER CELLULOSIC MATERIAL, SPONTANEOUS COMBUSTION CAN OCCUR UNDER CERTAIN CONDITIONS. IF HARDENER IS SPILLED INTO OR MIXED WITH SAWDUST, HEAT IS GENERATED AS TH E AIR OXIDIZES THE AMINE. IF THE HEAT IS NOT DISSIPATED QUICKLY ENOUGH, IT CAN IGNITE THE SAWDUST. ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK W/OUT ADDNL RISK. WEAR PROPER PERS PROT EQUIP. DIKE & CONTAIN SPILL. VENT AREA. LGE SPILL: DIKE & PUMP INTO APPROP CONTR FOR RECOVERY. SML SPILL: DILUTE W/WATER & RECOVER/USE INERT, NON-COMB UST ABSORB MATL (E.G., SAND) & SHOVEL INTO SUITABLE CONTR. DO NOT USE SAWDUST, WOOD CHIPS/OTHER CELLULOSIC MATLS TO ABSORB SPILL, AS POSS FOR SPONT COMBUT EXISTS. (SUP DAT) ====================== Handling and Storage ====================== Handling and Storage Precautions:STORAGE TEMPERATURE (MIN/MAX): 40F (4C)/90F (32C). SHELF LIFE: TWO YEARS OR MORE IN ORIGINAL SEALED CONTAINER. STORE IN COOL, DRY PLACE AWAY FROM HIGH TEMPERATURES AND MOISTURE. KEEP CONTAINER TIGHTLY CLOSED. USE WITH ADEQUATE VENTILATION. AVOID EXPOSURE TO CONCENTRATED VAPORS. AVOID SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE WITH ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION TO MEET EXPOSURE LIMITS. IN POORLY VENTILATED AREAS, USE A NIOSH APPROVED RESPIRATOR WITH AN ORGANIC VAPOR CARTRIDGE. Ventilation:USE WITH ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION TO MEET EXPOSURE LIMITS. Protective Gloves:LIQUID-PROOF, CHEM RESIST GLOVES (NITRILE-BUTYL RUBB, BUTYL RUBB/NATURAL RUBB). Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR FULL BODY-COVERING CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. CONTACT LENS SHOULD NOT BE WORN WHEN WORKING WITH THIS MATERIAL. Supplemental Safety and Health SPILL PROC: WASH SPILL RESIDUE W/WARM, SOAPY WATER IF NEC. PHYSICAL/CHEM PROPERTIES: BULK DENSITY: 8.85 LBS/GAL; % VOLAT BY WT: EPA METH 24, AS DESCRIBED IN 40 CFR PART 60, WAS USED TO DETERMINE VOLAT MATTER CONTENT OF MIXED EPOXY RESIN & HARDENER. THIS METH STATES THAT TWO-COMPONENT COATING SYS SHOULD BE (OTHER INFO) ================== Physical/Chemical Properties ================== Boiling Pt:>226.7C, 440.F Melt/Freeze Pt:=-5.C, 23.F Vapor Pres:<1 MMHG @ 20C Vapor Density:HVR/AIR Spec Gravity:1.05 pH:ALKALINE Viscosity:1,100 CPS Solubility in Water:APPRECIABLE Appearance and Odor:AMBER LIQUID, WITH AMMONIA-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID ACIDS, OXIDIZING MATLS, HALOGENATED ORG CMPDS (E.G., METHYLENE CHLORIDE). EXTERNAL HEATING/SELF-HEATING COULD RSLT IN RAPID TEMP INCR & SERIOUS HAZ. IF SUCH A RXN WERE TO TAKE PLACE IN WASTE DRUM, DRUM COULD EXPAND & Stability Condition to Avoid:AVOID EXCESSIVE HEAT. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND OXIDES OF NITROGEN WHEN BURNED; AMMONIA WHEN HEATED. =================== Toxicological Information =================== Toxicological Information:THE RESULTS OF ONE COMPONENT'S IN VITRO MUTAGENICITY TESTS HAVE BEEN POSITIVE. HOWEVER, IT DID NOT CAUSE CANCER IN LONG TERM ANIMAL STUDIES. ===================== Ecological Information ===================== Ecological:WASTES FROM THIS PRODUCT MAY PRESENT LONG TERM ENVIRONMENTAL HAZARDS. DO NOT DUMP INTO SEWERS, ON THE GROUND OR IN ANY BODY OF WATER. HYDROXYBENZENE (PHENOL) (CAS # 108-95-2) BIODEGRADABILITY = 99.5% AT 7 DAYS. ==================== Disposal Considerations ==================== Waste Disposal Methods:EVALUATION OF THIS PRODUCT USING RCRA CRITERIA SHOWS THAT IT IS NOT A HAZARDOUS WASTE, EITHER BY LISTING OR CHARACTERISTICS, IN ITS PURCHASED FORM. IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE PR OPER DISPOSAL METHODS. INCINERATION OR LANDFILL MAY BE PREFERRED METHODS WHEN CONDUCTED IN ACCORDANC E WITH FEDERAL, STATE AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:D.O.T. SHIPPING NAME: NOT REGULATED BY DOT. TECHNICAL SHIPPING NAME: NOT APPLICABLE. D.O.T. HAZARD CLASS: NOT APPLICABLE. U.N./N.A. NUMBER: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. THE CORROSIVI TY POTENTIAL OF WEST SYSTEM 205 FAST HARDENER WAS EVALUATED IN GENERAL COMPLIANCE WITH THE CONDITIONS SPECIFIED BY THE DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATION (49 CFR 173). THE MAT ERIAL IS CLASSIFIED AS NON-CORROSIVE BY DERMAL APPLICATION, AS DEFINED BY THE DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIAL GUIDELINES. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: HYDROXYBENZENE (PHENOL). SECTION 313 TOXIC CHEMICALS: THIS PRODUCT CONTAINS HYDROXYBENZENE (PHENOL) AND IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. Federal Regulatory Information:OSHA STATUS: SEVERE IRRITANT; POSSIBLE SENSITIZER. TSCA STATUS: ALL COMPONENTES LISTED ON TSCA INVENTORY. State Regulatory Information:THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES; OTHER PRODUCTS SPECIFIC HEALTH AND SAFETY DATA IN OTHER SECTIONS OF THIS MSDS MAY ALSO BE APPLICABLE FOR STATE REQUIREMENTS. FOR D ETAILS ON YOUR REGULATORY REQUIREMENTS YOU SHOULD CONTACT THE APPROPRIATE AGENCY IN YOUR STATE. HYDROXYBENZENE (PHENOL), CAS # 108-95-2, <12% CONCENTRATION, PA (PENNSYLVANIA HAZARDOUS SUBSTANCE LIST). ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.