FISHER SCIENTIFIC CO CHEMICAL DIV. -- AMMONIUM HYDROXIDE -- 6810-00-243-4436
===================== Product Identification ===================== Product ID:AMMONIUM HYDROXIDE MSDS Date:07/20/1993 FSC:6810 NIIN:00-243-4436 === Responsible Party === Company Name:FISHER SCIENTIFIC CO CHEMICAL DIV. Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100 OR 201-796-7523 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 Company Name:SILFEN LEO INC, INDUSTRIAL CHEMICAL DIV Address:80 BUSINESS PARK DR SUITE 206 Box:City:ARMONK State:NY ZIP:10504-1710 Country:US Phone:800-431-1075 CAGE:1GJ71 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM HYDROXIDE (SARA III) CAS:1336-21-6 RTECS #:BQ9625000 Fraction by Wt: 28-30% Other REC Limits:NONE SPECIFIED OSHA PEL:35 PPM STEL ACGIH TLV:25 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 70-72% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50: 350 MG / KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: IMMEDIATELY DANGEROUS TO LIFE. IRRITATION TO THE RESPIRATORY TRACT. LARGNGITIS, TRACHEITIS. INGESTION: TOXIC! MAY CAUSE CORROSION TO THE ESPHAGUS AND STOMACH WITH PERFORATION AND PERITONIT IS. SKIN: BURNS WITH VESICATION. EYES:CORROSIVE, SPLASHES MAY CAUSE GLAUCOMA, CORNEAL SCARS, IRIS ATROPHY AND CATARACTS. Effects of Overexposure:INHALATION: COUGHING, SORE THROAT, AND LABORED BREATHING. INGESTION: PAIN IN THE MOUTH, CHEST, AND ABDOMEN, WITH COUGHING, VOMITING AND COLLAPSE. SKIN: BURNS. EYES: SEVERE PAIN, REDNESS. Medical Cond Aggravated by Exposure:EYE DISORDERS, IMPAIRED RESPIRATORY FUNCTION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION OR OXYGEN AS NEEDED. CALL A PHYSICIAN. INGESTION: GIVE SEVERAL GLASSES OF WATER. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MIN. WHILE REMOVING CONTAMINATED CLOTHING. CALL A PHYSICIAN. EYES: WASH EYES WITH WATER WHILE LIFTING EYELIDS FOR 15 MIN. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:1204F Extinguishing Media:DRY CHEMICALS, CARBON DIOXIDE, WATER SPRAY, OR REGULAR FOAM . Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK. APPLY COOLING WATER TO SIDES OF CONTAINERS THAT ARE EXPOSED TO FLAME UNTIL WELL AFTER FIRE IS OUT. Unusual Fire/Explosion Hazard:CORROSIVE VAPORS. AVOID BREATHING CORROSIVE VAPORS, KEEP UPWIND. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH SPILLED MATERIAL. STOP LEAK IF POSSIBLE WITHOUT RISK. SMALL SPILLS, TAKE UP WITH SAND OR OTHER ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. LARGER SPILLS, DIKE AHEAD OF SPILL. ISOLATE HAZARD AREA AND DENY ENTRY. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE SUBSTANCES. STORE IN A DRY, COOL, VENTILATED AREA. Other Precautions:MAY BURN BUT DOES NOT IGNITE READILY. FLAMMABLE, POISONOUS GASES MAY ACCUMULATE IN TANKS AND HOPPER CARS. MAY IGNITE COMBUSTIBLES (WOOD, PAPER, OIL). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON CONTAMINATION LEVELS FOUND IN THE WORK PLACE, MUST NOT EXCEED THE WORKING LIMITS OF THE RESPIRATOR AND BE JOINTLY APPROVED BY NIOSH-MSHA. Ventilation:PROVIDE LOCAL EXHAUST VENTILATION SYSTEM TO MEET PUBLISHED EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS PROTECTIVE GLOVES. Eye Protection:SAFETY GLASSES/FACE SHIELD. Other Protective Equipment:IMPERVIOUS CLOTHING, EYE WASH FOUNTAIN AND QUICK DRENCH SHOWER WITHIN THE IMMEDIATE WORK AREA. Work Hygienic Practices:WASH HANDS AFTER ANY CONTACT WITH THIS MATERIAL. Supplemental Safety and Health NONE. ================== Physical/Chemical Properties ================== HCC:B3 Boiling Pt:B.P. Text:97.0F,36.1C Melt/Freeze Pt:M.P/F.P Text:-107F,-77C Vapor Pres:115 @ 20C Vapor Density:1.2 Spec Gravity:0.9 pH:11.6 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID WITH SHARP, PUNGENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, ACROLEIN, DIMETHYL SULFATE, HALOGENS, SILVER NITRATE AND PERMANGANATE, PROPYLENE OXIDE, NITROMETHANE, OLEUM. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY PRODUCE CORROSIVE VAPORS OF AMMONIA AND TOXIC OXIDES OF NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE. EPA HAZARDOUS WASTE NUMBER D002. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.