MALLINCKRODT INC SCIENCE PRODUCTS DIVISION -- NICKEL CHLORIDE -- 6810-00-201-1802
===================== Product Identification ===================== Product ID:NICKEL CHLORIDE MSDS Date:07/30/1985 FSC:6810 NIIN:00-201-1802 === Responsible Party === Company Name:MALLINCKRODT INC SCIENCE PRODUCTS DIVISION Address:PARIS BYPASS Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:606-987-7000 Emergency Phone Num:606-987-7000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 Company Name:SHAPE PRODUCTS Address:1127 57TH AVE. Box:City:OAKLAND State:CA ZIP:94621-4427 Country:US Phone:510-534-1186 OR 800-444-0015 CAGE:3D869 ============= Composition/Information on Ingredients ============= Ingred Name:NICKEL CHLORIDE (SARA III) CAS:7718-54-9 RTECS #:QR6475000 Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG NI/M3 ACGIH TLV:0.1 MG NI/M3; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV: 0.1 MG (NI)/M3 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION-IRRITATING TO THE MUCOUS MEMBRANES. INGESTION-IRRITATING TO THE DIFESTIVE TRACT. SKIN-MAY CAUSE SKIN IRRITATION. ABSORPTION IS POOR, BUT SYMPTOMS MAY INCLUDE GIDDINESS, CAPILLARY DAMAGE, MY OCARDIAL WEAKNESS, CNS DEPRESSION, & KIDNEY & LIVER DAMAGE. EYE-IRRITATING TO THE EYES. Explanation of Carcinogenicity:NICKEL CHLORIDE IS A CANCER SUSPECT AGENT. Effects of Overexposure:INHALATION-METALLIC TASTE IN THE MOUTH AND SORE THROAT. INGESTION-ABDOMINAL APIN, DIARRHEA, NAUSEA & VOMITING. SKIN-SOME INDIVIDULAS MAY SUFFER "NICKEL ITCH", A FORM OF DERMATITIS. EYE-MAY PRODUCE RED NESS, PAIN & POSSIBLLY EYE DAMAGE. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL ADVICE. INHALATIO N: REMOVE TO FRESH AIR. GIVE MOUTH-TO-MOUTH RESUSCITATION IF NOT BREATHING. GET MEDICAL ATTENTION. INGESTION: INDUCE VOMITING BY GIVING 2 GLASSES OF WATER & STICKING FINGER DOWN THROAT. SEE PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND MODE. Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF SPILL OR LEAK, CLEAN-UP PERSONNEL REQUIRE PROTECTIVE CLOTHING & RESPIRATORY PROTECTION FROM DUST. PICK UP & PLACE IN A SUITABLE CONTAINER FOR RECLAMATION OR DISPOSAL IN A METHOD THAT DOES NOT GENERATE DUST. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE. ISOLATE FROM INCOMPATIBL SUBSTANCES. Other Precautions:SOLUTIONS ARE ACIDIC. AREAS IN WHICH EXPOSURE TO NICKEL METAL OR SOLUBLE NICKEL COMPOUNDS MAY OCCUR SHOULD BE IDENTIFIES BY SIGNS OR APPROPIATE MEANS AND ACCESS TO THE AREA SHOULD BE LIMITED TO AUTHOR IZED PERSONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED, A DUST/MIST RESPIRATOR WITH CHEMICAL GOGGLES MAY BE WORN, IN GENERAL, UP TO TEN TIMES THE TLV. CONSULT RESPIRATOR SUPPLIER FOR LIMITATIONS. Ventilation:A SYSTEM OF LOCAL EXHAUST IS RECOMMENDED TO KEEP EMPLOYEE EXPOSURE BELOW THE AIRBORNE EXPOSURE LIMITS. Protective Gloves:NEOPRENE OR RUBBER GLOVES Eye Protection:SAFETY GOGGLES OR FULL FACE SHIELD Other Protective Equipment:ADDITIONAL PROTECTION INCLUDING IMPERVIOUS BOOTS, APRON OR COVERALLS, AS NEEDED IN AREAS OF UNUSUAL EXPOSURE. Work Hygienic Practices:EATING, DRINKING & SMOKING SHOULD NOT BE PERMITTED IN AREAS WHERE SOLIDS OR LIQUIDS CONTAINING SOLUBLE NICKEL IS HANDLED Supplemental Safety and Health NIOSH RECOMMENDS PRE-PLACEMENT AND PERIODIC MEDICAL EXAMS, WITH MAINTAINING OF RECORDS FOR ALL EMPLOYEES EXPOSED TO NICKEL IN THE WORKPLACE. ================== Physical/Chemical Properties ================== HCC:T4 NRC/State Lic Num:NOT RELEVANT Melt/Freeze Pt:=1001.1C, ######F Solubility in Water:SOLUBLE IN WATER Appearance and Odor:YELLOW OR LIGHT GREEN DELIQUESCENT CRYSTALS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES VIOLENT REACTION WITH POTASSIUM. Stability Condition to Avoid:SUBSTANCE WITLL PICK UP MOISTURE FROM AIR & GO INTO SOLUTION IF EXPOSED IN OPEN CONTAINER. A WATER SOLUTION IS ACIDIC. Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION, EMITS VERY TOXIC FUMES OF CHLORIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DISPOSED IN A RCRA APPROVED HAZARDOUS WASTE FACILITY. ENSURE COMPLIANE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.