SIGMA CHEMICAL CO -- P-XYLENE 99%, 134449 -- 6810-00N085041
===================== Product Identification ===================== Product ID:P-XYLENE 99%, 134449 MSDS Date:01/01/1996 FSC:6810 NIIN:00N085041 === Responsible Party === Company Name:SIGMA CHEMICAL CO Box:14508 City:ST LOUIS State:MO ZIP:63178 Country:US Info Phone Num:314-771-5765 Emergency Phone Num:314-771-5765 CAGE:21076 === Contractor Identification === Company Name:SIGMA CHEMICAL COMPANY Address:3050 SPRUCE ST Box:14508 City:ST LOUIS State:MO ZIP:63178 Country:US Phone:314-771-5765 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:P-XYLENE; (P-DIMETHYLBENZENE) (SARA 313) (CERCLA) CAS:106-42-3 RTECS #:ZE2625000 Fraction by Wt: 99% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) 5 GM/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. VAPOR OR MIST IS IRRITATING TO EYES, MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. EXPOSURE CAN CAUSE: NARCOTIC EFFECT; LUNG IRRITATION, C HEST PAIN AND EDEMA WHICH MAY BE FATAL;CENTRAL NERVOUS SYSTEM DEPRESSION; DERMATITIS; GASTROINTESTINAL(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:DISTURBS. CHRONIC:DMG TO THE LIVER & KIDNEYS. BLOOD EFTS. MAY CAUSE REPRO DISORDERS. TARGET ORGANS:NERVES, LIVER, KIDNEYS. TARGET ORGAN DATA:BEHAVIORAL (GEN ANESTH); CARDIAC (OTHER CHANGES); LUNGS, THORAX/RESPIRATION (RESP DEPRESS); EFTS ON FERTILITY (POST-IMPLANTATION MORTALITY; ABORTION); EFTS ON (SUPP DATA) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT LST 15 MINUTES. SKIN:IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT LST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES. REMOVE & WASH C ONTAMINATED CLOTHING PROMPTLY. INHAL:REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTF RESP. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGEST:WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point:81.0F,27.2C Lower Limits:1.1% Upper Limits:7% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROP FOAM. WATER MAY BE EFFECTIVE FOR COOLING, BUT MAY NOT EFT EXTINGUISHMENT. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . FLAMMABLE. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION & FLASH BACK. CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS. FORMS EXPLOSIVE MIXTURES IN AIR. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF IGNIT. WEAR NIOSH APPRVD SCBA, RUB BOOTS & HEAVY RUB GLOVES. COVER W/ACTIVATED CARBON ADSORBENT, TAKE UP & PLACE IN CLSD CNTNRS. TRANSPORT OUTDOORS. VENT AREA & WASH SPILL SITE AFTER MATL PICKUP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE VAP. AVOID CONT W/EYES, SKIN & CLTHG. AVOID PRLNG/RPTD EXPOS. READILY ABSORBED THRU SKIN. IRRITANT. REPRO HAZ. KEEP TIGHTLY CLOSED. Other Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. STORE IN A COOL, DRY PLACE. FLAMMABLE. HARMFUL BY INHAL, IN CONT W/SKIN & IF SWALLOWED. IRRITATING TO EYES, RESP SYS & SKIN. KEEP AWAY FROM SOURCES OF IGNITIO N. NO SMOKING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR. Ventilation:USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves:CHEMICAL-RESISTANT GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE SHOWER . WEAR OTHER SUITABLE PROTECTIVE CLOTHING. USE NON-SPARKING TOOLS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health VP:9 @ 20C; 16 @ 37.7C. EFTS OF OVEREXP:EMBRYO OR FETUS (FETAL DEATH); SPECIFIC DEVELOPMENTAL ABNORMALITIES (CRANIOFACIAL). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:280F,138C Melt/Freeze Pt:M.P/F.P Text:>54F,>12C Vapor Pres:SUPP DATA Vapor Density:3.7 Spec Gravity:0.866 Appearance and Odor:COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE & LOCAL ENVIRONMENTAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.