PHARMCO PRODUCTS INC. -- HEXANES -- 6810-00-949-0257
===================== Product Identification ===================== Product ID:HEXANES MSDS Date:11/01/1997 FSC:6810 NIIN:00-949-0257 === Responsible Party === Company Name:PHARMCO PRODUCTS INC. Address:58 VALE ROAD City:BROOKFIELD State:CT ZIP:06804-3967 Country:US Info Phone Num:800-424-9300, 203-740-3471 Emergency Phone Num:800-424-9300 Resp. Party Other MSDS Num.:055, REVISION 1.0 Chemtrec Ind/Phone:(800)424-9300 CAGE:69267 === Contractor Identification === Company Name:ALLIANCE CHEMICAL INC Address:3 OAKMOOR Box:79 City:ROUND ROCK State:TX ZIP:78680 Country:US Phone:512-365-6838 Contract Num:SP0450-00-M-SJ88 CAGE:1LT50 Company Name:PHARMCO PRODUCTS INC. Address:58 VALE ROAD Box:City:BROOKFIELD State:CT ZIP:06804-3967 Country:US Phone:203-740-3471 CAGE:69267 ============= Composition/Information on Ingredients ============= Ingred Name:HEXANES (N-HEXANE) CAS:110-54-3 RTECS #:MN9275000 = Wt:100. OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:SWALLOWING: THIS MATERIAL CAN ENTER LUNGS DURING SWALLOWING OR VOMITING AND CAUSE LUNG DAMAGE. MAY CAUSE IRRITATION OF THE DIGESTIVE TRACT, NAUSEA, NERVOUS SYSTEM DEPRESSION AND GIDDINESS. SKIN ABSORP TION: NO HARMFUL EFFECTS REPORTED. INHALATION: MAY CAUSE IRRITATION OF THE THROAT AND NOSE. SKIN: PROLONGED OR REPEATED CONTACT MAY CAUSE IRRITATION AND DRYING OF THE SKIN. EYE: MAY CAUSE IRRITATION I NCLUDING STINGING, TEARING, AND REDNESS. Effects of Overexposure:IRRITATION OF NOSE, THROAT OR DIGESTIVE SYSTEM. DEPRESSION OF NERVOUS SYSTEM. Medical Cond Aggravated by Exposure:REPEATED EXPOSURE MAY AGGRAVATE SKIN DISORDERS, RESPIRATORY DISORDER, MALE REPRODUCTIVE DISORDERS & PERIPHERAL NERVE DISORDERS. EXPOSURE TO HIGH CONCENTRATIONS MAY CAUSE IRREGULAR HEARTBEATS. ======================= First Aid Measures ======================= First Aid:OBTAIN MEDICAL ATTENTION FOR ALL CASES OF OVER-EXPOSURE. SWALLOWING: ASPIRATION HAZARD-DO NOT INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH SKIN WITH SOAP AND WATER FOR AT LEAST 15 MINUTES. INHALATION: REMOVE TO FRESH AIR; GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING; IF BREATHING IS DIFFICULT OXYGEN MAY BE GIVEN BY QUALIFIED PERSONNEL; OBTAIN MEDICAL ASSISTANCE IF DISCOMFORT P ERSISTS. EYE: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. OBTAIN MEDICAL ASSISTANCE. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=-22.C, -7.6F Lower Limits:1.0% Upper Limits:8.0% Extinguishing Media:SMALL FIRES-USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM. LARGE FIRES-WATER SPRAY, FOG OR FOAM. Fire Fighting Procedures:USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS AND STRUCTURES; USE WATER SPRAY TO DISPERSE VAPORS-REIGNITION IS POSSIBLE; USE SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL TO SOURCE OF IGNITION AND FLASH BACK. VAPORS MAY SETTLE IN LOW OR CONFINED SPACES. MAY PRODUCE A FLOATING FIRE HAZARD. STATIC IGNITION HAZARD CAN RESULT FROM HANDLING AND USE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES; GROUND ALL EQUIPMENT; DO NOT WALK THROUGH SPILL; STOP SPILL IF POSSIBLE; PREVENT ENTRY INTO SEWERS, CONFINED SPACES, ETC.; USE A VAPOR SUPPRESSING FOAM TO REDUCE VAPORS ; ABSORB SPILL WITH NON-COMBUSTIBLE MATTER AND TRANSFER TO CONTAINERS; USE NON-SPARKING TOOLS TO COLLECT ABSORBED MATERIAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:FLAMMABLE MATERIAL-KEEP AWAY FROM HEAT, SPARKS, & FLAME; SUDDEN RELEASES OF HOT ORGANIC VAPORS OR MISTS FROM PROCESS EQUIPMENT OPERATING AT ELEVATED TEMPERATURES MAY RESULT IN IGNITIONS WITHOUT THE PR ESENCE OF OBVIOUS IGNITION SOURECES. AVOID CONTACT WITH EYES. KEEP CONTAINER CLOSED. Other Precautions:USE WITH ADEQUATE VENTILATION. GROUND CONTAINER WHEN TRANSFERRING PRODUCT. VAPORS MAY COLLECT IN CONTAINERS; TREAT EMPTY CONTAINER AS HAZARDOUS. WASH THOROUGHLY AFTER HANDLING. VAPORS MAY SETTLE IN LO W OR CONFINED AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE SELF-CONTAINED BREATHING APPARATUS IN HIGH VAPOR CONCENTRATION. Ventilation:SPECIAL, LOCAL VENTILATION IS NEEDED WHERE VAPORS ESCAPE TO THE WORKPLACE AIR. Protective Gloves:WEAR GLOVES. Eye Protection:WEAR SAFETY GLASSES. Other Protective Equipment:WEAR LAB COAT OR UNIFORM, EYE WASH, SAFETY SHOWER. Supplemental Safety and Health PRODUCT: HEXANES. SYNONYMS: HYDROCARBON MIXTURES. FORMULA: CH3(CH2)4CH3; NOTE THAT THIS PRODUCT IS A MIXTURE OF N-HEXANE AND OTHER HEXANE ISOMERS. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:=67.8C, 154.F B.P. Text:APPROX. Melt/Freeze Pt:=-95.C, -139.F Vapor Pres:140 MM HG Vapor Density:3.0(AIR=1) Spec Gravity:.675@15.56C VOC Pounds/Gallon:674 Evaporation Rate & Reference:8.1(BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; CHARACTERISTIC ODOR. Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING/REDUCING AGENTS. Stability Condition to Avoid:HEAT, FLAMES, ETC. Hazardous Decomposition Products:CARBON MONOXIDE AND/OR CARBON DIOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:VAPORS MAY COLLECT IN EMPTY CONTAINERS, TREAT EMPTY CONTAINER AS HAZARDOUS. DISPOSE OF SPILL-CLEAN UP AND OTHER WASTE IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:PROPER SHIPPING NAME: HEXANE. HAZARD CLASS: 3. UN NUMBER: 1208. PACKING GROUP II. IMO INFORMATION: HEXANES. LABEL OF CLASS: 3. PACKING GROUP II. LOW FLASHPOINT GROUP. ===================== Regulatory Information ===================== SARA Title III Information:COMPONENTS PRESENT IN THIS PRODUCT AT A LEVEL WHICH COULD REQUIRE REPORTING UNDER SARA ARE: HEXANE. Federal Regulatory Information:CERCLA REQUIRES NOTIFICATION OF THE NATIONAL RESPONSE CENTER OF RELEASE QUANTITIES OF HAZARDOUS SUBSTANCES EQUAL TO OR GREATER THAN THE REPORTABLE QUANTITIES OF HAZARDOUS SUBSTANCES EQUAL TO OR GREATE R THAN THE REPORTABLE QUANTITIES (RQS) IN CFR. COMPONENTS PRESENT IN THIS PRODUCT AT A LEVEL WHICH COULD REQUIRE REPORTING UNDER THIS STATUTE ARE: HEXANES, CAS#110-54-3. THE INGREDIENTS OF THIS PRODU CT ARE ON THE TSCA INVENTORY. State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT MAY CONTAIN TRACE LEVELS OF BENZENE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. THIS PRODUCT MAY CONTAIN TRACE LEVELS OF TOLUENE KNOWN TO THE STATE OF CAL IFORNIA TO BE A DEVELOPMENTAL TOXICANT. THIS PRODUCT CONTAINS HEXANE WHICH MAY BE IDENTIFIED AS A HAZARDOUS SUBSTANCE BY INDIVIDUAL STATES. CALIFORNIA SCAQMD RULE 443.1 (VOCS). ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.