FISHER SCIENTIFIC, CHEMICAL DIV. -- TETRAHYDRONAPHTHALENE, T724 -- 6810-00N027730
===================== Product Identification ===================== Product ID:TETRAHYDRONAPHTHALENE, T724 MSDS Date:09/16/1991 FSC:6810 NIIN:00N027730 === Responsible Party === Company Name:FISHER SCIENTIFIC, CHEMICAL DIV. Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 OR 201-796-7523 Emergency Phone Num:201-796-7100/800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ING 16:ENDOTRACHEAL TUBE W/IN 15 MIN. IN ABSENCE OF DEPRESS/CONVULSIONS/IMPAIRED GAG REFLEX, IPECAC EMESIS CAN (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:BE DONE. WHEN VOMIT BEGINS, KEEP HEAD LOWER THAN HIPS TO PVNT ASPIR. AFTER VOMIT STOPS, GIVE 30-60ML OF (ING 19) RTECS #:9999999ZZ Ingred Name:ING 19:FLEET'S PHOSPHO-SODA DILUTED 1:4 IN WATER. MAINTAIN AIRWAY, BLOOD PRESSURE & RESPIRATION. GET MD IMMEDIATELY. RTECS #:9999999ZZ Ingred Name:SPILL PROC:AREA. KEEP UNNECESSARY PEOPLE AWAY. ISOLATE HAZARD AREA & RESTRICT ENTRY. RTECS #:9999999ZZ Ingred Name:OTHER PREC:MAY FORM EXPLOSIVE PEROXIDES ON PRLNGD CNTCT W/AIR/EXPOSUR TO HEAT/LIGHT. IF DISTILLED/EVAPORATED (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:TO DRYNESS, AN EXPLOSION MAY OCCUR. RTECS #:9999999ZZ Ingred Name:NAPHTHALENE, 1,2,3,4-TETRAHYDRO-; (TETRAHYDRONAPHTHALENE) CAS:119-64-2 RTECS #:QK3850000 Fraction by Wt: 100% Ingred Name:SUPP DATA:ISOLATE FOR 1/2 MILE IN ALL DIRECTIONS IF TANK, RAIL CAR/TANK TRUCK INVOLVED IN FIRE. EXTING ONLY IF (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:FLOW CAN BE STOPPED. USE FLOODING AMTS OF WATER AS FOG, SOLID STREAMS MAY BE INEFT. COOL CNTNRS W/FLOODING (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:AMOUNTS OF WATER. APPLY FROM AS FAR A DISTANCE AS POSSIBLE. AVOID BREATHING VAPORS. KEEP UPWIND. RTECS #:9999999ZZ Ingred Name:EXPLO HAZ:SOURCE OF IGNITION AND FLASH BACK. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:HOWEVER,TEST APPLICATION OF LIQ TO RABBIT EYES CAUSED NO INJURY. DETECTABLE 24 HRS LATER. (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:INGEST:NARCOTIC. HUMAN CASE INVOLVING INGEST OF 1/2-3/4 PINT OF TETRALIN HAS BEEN RECORDED. EFTS CONSISTED (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:OF NAUSEA, VOMIT, INTRAGASTRIC DISCOMFORT, TRANSIENT LIVER & KIDNEY DMG, GREEN-GRAY URINE & ENZYMATIC CHGS.(ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:ALL EFTS RETURNED TO NORM W/IN 2 WEEKS. OTHER SYSTEMIC EFTS AS DETAILED IN ACUTE INGEST MAY ALSO OCCUR. (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:ASPIR MAY RESULT IN CHEM PNEUM. CHRONIC:INHAL:RPTD/PRLNGD EXPOS MAY RESULT IN DIZZ, WEAKNESS, WT LOSS, (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:NERVOUSNESS, PAIN & NUMBNESS IN LIMBS & SEVERE LIVER & KIDNEY DMG. NEPHRITIC LESIONS & CATARACTS HAVE (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:BEEN REPORTED IN GUINEA PIGS. SKIN:RPTD & PRLNGD EXPOS TO IRRITANTS MAY CAUSE DERM. SYSTEMIC TOXICITY (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:MAY OCCUR AS DETAILED IN CHRONIC INHAL. EYE:RPTD & PRLNGD EXPOS MAY CAUSE CONJUNCT. INGEST:RPTD/PRLNGD (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:EXPOS MAY RESULT IN SYSTEMIC TOXICITY AS DETAILED IN CHRONIC INHAL. RPTD ORAL DOSES HAVE BEEN REPORTED (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:TO CAUSE CATARACTS IN RATS, RABBITS AND GUINEA PIGS. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:INGEST:EXTREME CARE MUST BE USED TO PVNT ASPIR. USE GASTRIC LAVAGE W/ACTIVATED CHARCOAL & CUFFED (ING 17) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT)2860 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:IRRITANT/NARCOTIC/TOXIC. LETHAL DOSE IN GUINEA PIGS IS 275PPM. MAY CAUSE IRRIT OF RESP TRACT & NASOTRACHEOBRONCHITIS. VAP MAY CAUSE NAUSEA, VOMIT & CNS EFTS INCLDG HDCH, DIZZ & DROWS. HIGH CONCS MAY LEAD TO NARCOSIS, UNCON & LIVER & KIDNEY DMG W/GREEN URINE & NEPHRITIC IRRIT. METHEMOGLOBIN (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:PRODUCTION MAY ALSO OCCUR. SKIN:IRRITANT. MAY CAUSE IRRIT W/REDNESS, PAIN & ECZEMATOID INFLAMM. MAY BE ABSORBED THRU SKIN RESULTING IN NAUSEA & TRANSIENT LIVER & KIDNEY DMG. OTHER SYSTEMIC EF TS AS DETAILED IN ACUTE INHAL MAY ALSO OCCUR. EYE:IRRITANT. VAP MAY CAUSE IRRIT W/TEARING, REDNESS & PAIN. (ING 6) Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN LESIONS AND/OR ASTHMA, INFLAMMATORY OR FIBROTIC PULMONARY DISEASE. ALCOHOL MAY ENHANCE TOXIC EFFECTS. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG STOPPED, GIVE ARTF RESP. KEEP WARM & AT REST. GET MD IMMED. SKIN:REMOVE CONTAMD CLTHG & SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LG AMTS OF WAT ER UNTIL NO EVID OF CHEM REMAINS (APPROX 15-20 MIN). GET MD IMMED. EYE:WASH IMMED W/LG AMTS OF WATER/NORM SALINE, LIFTING LIDS, UNTIL NO EVID OF CHEM REMAINS (APPROX 15-20 MIN). GET MD IMMED.(ING 16) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:160F,71C Lower Limits:0.8% @ 100C Upper Limits:5% @ 150C Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM. LARGER FIRES:USE WATER SPRAY, FOG OR REGULAR FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. MOVE CNTNR FROM FIRE AREA IF CAN BE DONE W/OUT RISK. APPLY COOLING WATER TO SIDES OF CNTNRS THAT(SUPP DATA) Unusual Fire/Explosion Hazard:MODERATE FIRE HAZ WHEN EXPSD TO HEAT/FLAME. VAPOR-AIR MIXT EXPLOSIVE ABOVE FLASH POINT. VAPS HEAVIER THAN AIR & MAY TRAVEL CONSIDERABLE DISTANCE TO (ING 5) ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF IGNIT SOURCES. STOP LEAK IF CAN BE DONE W/OUT RISK. USE WATER SPRAY TO REDUCE VAPS. SML:TAKE UP W/SAND/OTHER ABSORB MATL & PLACE INTO CNTNRS FOR LATER DISP. LG:DIKE FAR AHEAD OF SPILL FOR LAT ER DISP. NO SMOKING, FLAMES/FLARES IN HAZ (ING 20) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE I/A/W 29 CFR 1910.106. MAY FORM EXPLO PEROXIDES ON PRLNGD CNTCT W/AIR. STORE IN TIGHTLY CLOSED CNTNR. PROTECT FROM EXPOS TO HEAT & LIGHT. Other Precautions:CHECK PEROXIDE CONTENT OFTEN; NEVER DISTILL TO DRYNESS. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. VAPS MAY BE EXPLOSIVE. AVOID OVERHEATING OF CNTNRS; CNTNRS MAY VIOLENTLY RUPTURE IN HEAT OF FIRE. AVOID CONTAM OF WATER SOURCES. (ING 21) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM LEVELS FOUND IN WORK PLACE, ON SPECIFIC OPERATION, MUST NOT EXCEED WORKING LIMITS OF RESP & MUST BE NIOSH/MSHA APPROVED. FOR ADDITIONAL INFORMATION REFER TO ORIGINAL MSDS . Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION. VENTILATION EQUIPMENT MUST BE EXPLOSION-PROOF. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:IMPERVIOUS CLOTHING. EMERGENCY EYE WASH FOUNTAIN. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC:ARE EXPSD TO FLAMES UNTIL WELL AFTER FIRE OUT. STAY AWAY FROM ENDS OF TANKS. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER/MONITOR NOZZ. IF IMPOSS, W/DRAW FROM AREA & LET FI RE BURN. W/DRAW IMMED IN CASE OF RISINGSOUND FROM VENTING SAFETY DEVICE/ANY DISCOLORATION OF TANK DUE TO FIRE. (ING 2) ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:406F,208C Melt/Freeze Pt:M.P/F.P Text:-32F,-36C Vapor Pres:1 @ 38C Vapor Density:4.55 Spec Gravity:0.9702 Solubility in Water:INSOLUBLE Appearance and Odor:COLORLESS LIQUID W/AROMATIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO HALOGENS, MINERAL ACIDS, STRONG OXIDIZERS, LIQUID OXYGEN, OZONE, PEROXIDES. Stability Condition to Avoid:CONTACT W/HEAT, SPARKS, FLAMES OR OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN DISPOSING OF THIS SUBSNTACE. FOR ASSISTANCE, CONTACT DISTRICT DIRECTOR OF EPA. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.