WARDS NATURAL SCIENCE ESTABLISHMENT INC -- N-HEXANE,39-1515 -- 6810-00-312-7109
===================== Product Identification ===================== Product ID:N-HEXANE,39-1515 MSDS Date:09/13/1995 FSC:6810 NIIN:00-312-7109 === Responsible Party === Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692 Country:US Info Phone Num:716-359-2502/226-6177 (NIGHT) Emergency Phone Num:716-359-2502/800-424-9300(CHEMTREC) Preparer's Name:MICHAEL RASZEJA CAGE:63759 === Contractor Identification === Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692-9012 Country:US Phone:(716) 359-2502 CAGE:63759 ============= Composition/Information on Ingredients ============= Ingred Name:HEXANE (N-HEXANE) (CERCLA) CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: 99- 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:50 PPM; 9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CYCLOHEXANE (SARA 313) (CERCLA) CAS:110-82-7 RTECS #:GU6300000 Fraction by Wt: 0 - 1% Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM ACGIH TLV:300 PPM, 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50(ORAL,RAT) HEXANE 28710 MG/KG(RTECS) Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, CNS, RESPIRATOR & GI TRACTS. ACUTE- CAUSES SEVERE EYE IRRITATION. PROLONGED/REPEATED SKIN CONTACT CAN CAUSE IRRITATION, DERMATITIS. MAY BE ABSORBED THROUGH SKIN. INHALATION C AN CAUSE IRRITATION, CNS EFFECTS. INGESTION CAN CAUSE GI TRACT IRRITATION. ASPIRATION HAZARD. CHRONIC- NERVE DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DRY SKIN, TEARING, BLURRED VISION, REDNESS, DEFATTING, DERMATITIS, HEADACHE, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, VOMITING, DIARRHEA, UNCONSCIOUSNESS Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES OF THE EYE, SKIN, RESPIRATORY TRACT, CNS MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES/SKIN:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. REMOVE CONTAMINATED CLOTHING. WASH BEFORE REUSE. ORAL:DO NOT INDUCE VOMITING. IFCONSCIOUS, RINSE MOUTH WITH WATER. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:-7F,-22C Autoignition Temp:Autoignition Temp Text:437F Lower Limits:1.08% Upper Limits:8.0% Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM. WATER MAY BE INEFFECTIVE, BUT SHOULD BE USED TO COOL FIRE-EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. SEE 1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE NO 27. Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES OF IGNITION. VENTILATE AREA. REMOVE SPILL WITH NON-FLAMMABLE ABSORBENT SUCH AS SAND/CLAY. PLACE IN CONTAINER FOR DISPOSAL. WASH SPILL SITE AFTER PICK UP IS COMPLETE. PREVENT LIQUID FROM ENTERINGSEWER Neutralizing Agent:NOT RELEVANT ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN VENTILATED AREA AWAY FROM IGNITION SOURCES & INCOMPATIBLES. KEEP OUT OF REACH OF CHILDREN. Other Precautions:HIGHLY FLAMMABLE. USE IN WELL VENTILATED AREA/HOOD. AVOID BREATHING VAPORS. DO NOT GET IN EYES, ON SKIN/ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. REMOVE CONTAMINATED C LOTHING PROMPTLY. LAUNDER BEFORE REUSE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED OR FOR SYMPTOMS OF OVER EXPOSURE, WEAR NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR OR AIR-SUPPLIED RESPIRATOR. IN EMERGENCY, WEAR A NIOSH-APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREAT HING APPARATUS. Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Protective Gloves:NITRILE RUBBER Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES Other Protective Equipment:EYE WASH STATION & SAFETY SHOWERS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. LAB COAT Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=68.C, 154.4F Melt/Freeze Pt:=-94.C, -137.2F Vapor Pres:100 @60.4F Vapor Density:3.0 Spec Gravity:0.660 Evaporation Rate & Reference:<1 (ETHER=1) Solubility in Water:INSOLUBLE Appearance and Odor:COLORLESS, VERY VOLATILE LIQUID - FAINT, PECULIAR ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, ACIDS, BASES, SELECTED AMINES Stability Condition to Avoid:HIGH HEAT, SPARKS, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. MAY BE BURNED IN AN APPROVED CHEMICAL INCINERATOR. 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