FISHER SCIENTIFIC -- SODIUM PERCHLORATE -- 6810-00N015570
===================== Product Identification ===================== Product ID:SODIUM PERCHLORATE MSDS Date:05/18/1988 FSC:6810 NIIN:00N015570 === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:FIRST AID PROC:GIVE 2-4 GLASSES OF WATER, & INDUCE VOMIT BY TOUCHING FINGER TO BACK OF THROAT. GET MD IMMED. RTECS #:9999999ZZ Ingred Name:SPILL PROC:LG:DIKE FAR AHEAD OF SPILL FOR LATER DISP. KEEP UNNEC PEOPLE AWAY. ISOLATE HAZARD AREA & DENY ENTRY. RTECS #:9999999ZZ Ingred Name:RESP PROT:VAP CANISTER (CHIN-STYLE OR FRONT- OR BACK-MOUNTED CANISTER) W/FULL FACEPIECE & PARTICULATE FILTER.(SEE ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:TYPE "C" SUPPLIED-AIR RESP W/FULL FACEPIECE OPERATED IN PRESS-DEMAND/OTHER POS PRESS MODE OR W/FULL (SEE ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:FACEPIECE, HELMET OR HOOD OPERATED IN CONTINUOUS-FLOW MODE. SCBA W/FULL FACEPIECE OPERATED IN PRESS- (SEE ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:DEMAND/OTHER POS PRESS MODE. FOR FIREFIGHTING/OTHER IMMED DANGEROUS TO LIFE/HLTH COND:SCBA W/FULL (SEE ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:FACEPIECE OPERATED IN PRESS DEMAND/OTHER POS PRESS MODE. SUPPLIED-AIR RESP W/FULL FACEPIECE & (SEE ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:OPERATED IN PRESS-DEMAND/OTHER POS PRESS MODE IN COMBINATION W/AUXILIARY SCBA OPERATED IN PRESS-DEMAND(SEE ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:OR OTHER POSITIVE PRESSURE MODE. RTECS #:9999999ZZ Ingred Name:PERCHLORIC ACID, SODIUM SALT, MONOHYDRATE (SODIUM PERCHLORATE) CAS:7791-07-3 RTECS #:SC9850000 Fraction by Wt: 100% Ingred Name:MATLS TO AVOID:REDUCING AGENTS, STRONTIUM HYDRIDE, ORGANIC MATLS, SULFURIC ACID. LD50-LC50 MIX:LD50:(IPT,MUS)551 MG/KG. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORL,RAT)2100 MG/KG; (SEE ING 2) Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:IRRIT. DUSTS MAY CAUSE MUC MEMB IRRIT. SKIN:IRRIT. MAY CAUSE IRRIT W/REDNESS & PAIN. EYE:IRRIT. MAY CAUSE IRRIT W/REDNESS & PAIN. 0.08 M SOLN WAS APPLIED TO CORNEA OF RABBIT EYES AFTER REM OVAL OF EPITHELIUM W/ONLY SLIGHT RXN OCCURING. INGEST:NEPHROTOXIN. MAY CAUSE GI UPSET W/NAUSEA (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:& VOMIT. SERIOUS CASES MAY RESULT IN KIDNEY DMG & DEATH. CHRONIC:INHAL:NO DATA AVAILABLE. SKIN:RPTD/PRLNGD CNTCT MAY CAUSE DERMATITIS. EYE:MAY CAUSE CONJUNCTIVITIS AFTER RPTD/PRLNGD EXPOS. IN GEST:NO DATA AVAILABLE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG STOPPED, GIVE ARTF RESP. KEEP WARM/AT REST. GET MD IMMED. SKIN:REMOVE CONTAMD CLTHG/SHOES IMMED. WASH W/SOAP/MILD DETERGENT & LG AMTS OF WATER UNTIL NO EVID O F CHEM REMAINS ( 15-20 MIN). GET MD IMMED. EYE:WASH IMMED W/LG AMTS OF WATER, LIFTING LIDS, UNTIL NO EVID OF CHEM REMAINS (AT LEAST 15-20 MIN). GET MD IMMED. INGEST:IF CONSCIOUS, IMMED (SEE ING 3) ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON OR WATER SPRAY. LG FIRES:USE WATER SPRAY OR FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . MOVE CNTNRS FROM FIRE AREA IF POSS. COOL CNTNRS EXPOSED TO FLAMES W/WATER FROM SIDE UNTIL WELL (SUPP DATA) Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:OCCUPATIONAL:KEEP COMBUSTS AWAY FROM MATL. DO NOT TOUCH MATL. SML/DRY:W/CLEAN SHOVEL PLACE MATL INTO CLEAN, DRY CNTNR & COVER; MOVE CNTNRS FROM AREA. SML LIQ:TAKE UP W/SAND, EARTH/OTHER ABSORB MATL & PLACE INTO CNTNRS FOR LATER DISP. (SEE ING 4) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:PROT AGAINST PHYS DMG. STORE IN COOL, DRY PLACE OF NONCOMBUST CONSTRUCT. CONSULT NFPA PUB 43A, STOR OF LIQ/SOLID OXIDIZING MATLS, FOR STOR RQMNTS. Other Precautions:SEPARATE FROM COMBUST, ORGANIC, READILY OXIDIZABLE MATLS, ACIDS, SULFUR, CARBONACEOUS MATLS & COTTON. IMMED REMOVE & CAREFULLY DISPOSE OF ANY SPILLED PERCHLORATE (NFPA 49, HAZARDOUS CHEMICALS DATA, 19 75). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOWING RESP RECOMM BASED ON DATA IN PHYS DATA, HLTH EFTS & TOXICITY, RANKED IN ORDER FROM MINIMUM TO MAXIMUM RESP PROT:NIOSH/MSHA APPRVD CHEM CARTRIDGE RESP W/ORG VAP CARTRIDGE W/FULL FACEPIECE & D UST FILTER. GAS MASK W/ORG (SEE ING 5) Ventilation:PROVIDE LOCAL EXHAUST OR GENERAL DILUTION VENTILATION SYSTEM. Protective Gloves:APPROPRIATE PROTECTIVE GLOVES. Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:IMPERVIOUS CLOTHING. Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN. Supplemental Safety and Health FIRE FIGHT PROC:AFTER FIRE OUT. STAY AWAY FROM STOR TANK ENDS. FOR MASSIVE FIRE IN STOR AREA, USE UNMANNED HOSE HOLDER/MONITOR NOZZ, ELSE WITHDRAW FROM AREA & LET FIRE BURN. FLOOD W/WATER. COOL CNTNRS W/FLOODING QTYS OF WATER. APPLY FROM AS FAR A DISTANCE AS POSS. EVACUATE TO RADIUS OF 2500 FT FOR UNCONTROLLABLE FIRES. ================== Physical/Chemical Properties ================== HCC:D1 Boiling Pt:B.P. Text:900F,482C Melt/Freeze Pt:M.P/F.P Text:266F,130C Spec Gravity:2.0 Solubility in Water:209% Appearance and Odor:COLORLESS TO WHITE, DELIQUESCENT, RHOMBOHEDRAL CRYSTALS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER-SOLUBLE FUELS, OXIDIZABLE MATLS, HYDRAZINE, AMMONIUM NITRATE, CHARCOAL, MAGNESIUM, CALCIUM HYDRIDE, (SEE ING 2) Stability Condition to Avoid:MAY IGNITE OTHER COMBUST MATLS. RXN W/FUELS MAY BE VIOLENT. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD. Hazardous Decomposition Products:WHEN HEATED TO THERMAL DECOMPOSITION, IT EMITS TOXIC FUMES OF HYDROGEN CHLORIDE & NAO. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.