MALLINCKRODT INC.SCIENCE PRODUCTS DIV -- POTASSIUM DICHROMATE -- 6810-00N008841
===================== Product Identification ===================== Product ID:POTASSIUM DICHROMATE MSDS Date:08/08/1985 FSC:6810 NIIN:00N008841 === Responsible Party === Company Name:MALLINCKRODT INC.SCIENCE PRODUCTS DIV Address:PARIS BYPASS Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:314-982-5000 Emergency Phone Num:314-982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM BICHROMATE (SARA III) CAS:7778-50-9 RTECS #:HX7680000 Fraction by Wt: Other REC Limits: OSHA PEL:C,0.1 MG/M3 CRO3 ACGIH TLV:0.5 MG CR/M3; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:SEE SIGNS & SYMPTOMS OF OVEREXPOSURE Explanation of Carcinogenicity:HEXAVALENT CHROMIUM COMP ARE LISTED AS CARC BY NTP, & BY IARC.HEXAVALENT CHROMIUM COMP SUFFICIENT EVIDENCE FOR CARC(MFR) Effects of Overexposure:INHAL:IRRIT TO RESP TRACT,COUGH,WHEEZE,FEVER,HDCH,& LABORED BREATH.MAY PRODUC PULMONARY SENSITIZTION.INGEST:ABD PAIN,VOMIT,DIZZY,INTENSE THIRST,FEVER,COMA,LIVER DAMAGE,DEATH FROM CIRC COLLAPSE/RENAL F AILURE.EST LETHAL DOSE 5MG.SKIN:IRRIT ULCER,SCARRING,POS SYSTEMIC POISON,PARALLEL INGEST.EYE:IRRIT,RED,PAIN SEE SUP DATA Medical Cond Aggravated by Exposure:PERSONS W/ PRE-EXISTING SKIN,DISORDERS MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR.NOT BREATHING GIVE ARTIFICIAL RESP.BREATH DIFFICULT GIVE O*2 CALL PHYS.INGEST:INDUCE VOMITING IMMED.GIVE TWO LARGE GLASSES OF H*2O & STICK FINGER DOWN THROAT CALL PHYS.SKIN:I MMED FLUSH W/H*2O FOR AT LEAST 15 MIN.WHILE REMOVING CONTAM CLOTHING,SHOES,CALL PHYS.EYE: WASH W/ H*2O FOR AT LEAST 15 MIN LIFT LOWER & UPPER LID OCCASIONALLY.GET MED ATT IMMED. ===================== Fire Fighting Measures ===================== Flash Point: Lower Limits: Upper Limits: Extinguishing Media:FLOOD W/ LG AMTS OF H*2OH*2O SPRAY MAY BE USED TO KEEP FIRE EXPOS CONTR COOL. DO NOT ALLOW H*2O RUNOFF TO SEWER. Fire Fighting Procedures:IN EVENT OF FIRE,WEAR FULL PROTECTIVE CLOTHING & NIOSH-APPROVED SCBA W/ FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:NOT COMBUSTIBLE.SUBSTANCE IS STRONG OXIDIZER & ITS HEAT OF REACT W/ REDUCING AGENTS/COMBUSTIB. MAY CAUSE IGNITION.RELEAS O*2 UPON DECON ENHANCES COMBUS SUP DATA ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA.CLEAN UP PERSONNEL REQUIRE PROT CLOTHING & RESP PROT FROM DUST.SPILL:PICK UP,PLACE IN SUITABLE CONTR FOR RECLAM/DISPOSE OF IN A METHOD THAT DOES NOT GENERATE DUST. Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE.STORE IN DRY LOCAT,SEP FROM COMBUSTIBL ORGANIC,OXIDIZAB MAT.AVOID STORON WOOD FLOOR.DO NOT RET.SPILLAGE TO ORIG CONT Other Precautions:WEAR SPECIAL PROT EQUIP FOR MAINT BREAKIN.WASH HANDS,FACE,FOREARMS,NECK WHEX EXIT RESTRICTED AREA.SHOWER,DISPOSE OUTER CLOTH,CHANGE TO CLEAN GARMENTS AT END OF WORKDAY.WASH HANDS,DO NOT EAT, DRINK OR SMOKE IN THE WORK PLACE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:TLV EXCEEDED.DUST/MIST RESP MAY BE WORN,ALTERNATIVELY.SUPPLIED AIR FULL FACEPIECE RESP OR AIRLINED HOOD MAY BE WORN. Ventilation:LOCAL/GENERAL EXHAUST IS RECOM.KEEP AIR BORN LIMITS BELOW EXPOS LIMIT.LOCAL EXHAUST PREFERRED. Protective Gloves:IMPERVIOUS Eye Protection:CHEM SAFETY GOGGLES/FULL FACESHIELD Other Protective Equipment:IMPERVIOUS CLOTHING,BOOTS,LAB COAT,APRON OR COVERALLS TO PREVENT SKIN CONTACT.EYE WASH,FOUNTAIN QUICK DRENCH FACILITY. Work Hygienic Practices:OBSERVE GOOD WORK HYGIENIC PRACTICES. Supplemental Safety and Health BP:DECOMPOSES AT 500 C,932F.UNUSUAL FIRE EXPLO HAZ:CONTACT W/ OXIDIZABLE SUBSTANCES MAY CAUSE EXTREME,VIOLENT COMBUSTION.EXPLAIN CARC:NTP:KNOWN TO BE CARC.IARC:HUMAN CARC SIGN & SYMPTOM OVEREXP: CONJUNCTIVITIS:CHRONIC EXPOS: RPT/PROLOG SKIN CONT.ECZEMATOUS DERM.INHAL DUST,ULCER,BLEED,PERFORATION NASAL SEPTUM. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SUP DATA Melt/Freeze Pt:M.P/F.P Text:398.C 784.F Decomp Temp:Decomp Text:NO INFO Vapor Pres:NO INFO Vapor Density:NO INFO Spec Gravity:2.69 pH: Evaporation Rate & Reference:NO INFO FOUND Solubility in Water:6.5% AT 10C(50F) H2O Appearance and Odor:ORANGE-RED CRYSTALS OR POWDER Percent Volatiles by Volume: Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REDUCING AGENTS,ACETONE,PLUS SULFURIC ACID,HYDRAZINE & HYDROXYLAMINE. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE & STORAGE. Hazardous Decomposition Products:EMITS OXYGEN & TOXIC FUMES OF CHROMIUM TRIOXIDE WHEN HEATED TO DECOMPOSITION. Conditions to Avoid Polymerization: ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAIM MAY BE DISPOSED IN RCRA APPRO HAZ WAST FACILITY.DON'T FLUSH TO SEWER REPO & QTY(RQ)(WA)/CERCLA W/ LOCAL,STATE & FED REGS. 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