FISHER SCIENTIFIC,CHEMICAL DIVISION -- SODIUM HYDROXIDE -- 6810-00N009938
===================== Product Identification ===================== Product ID:SODIUM HYDROXIDE MSDS Date:11/18/1985 FSC:6810 NIIN:00N009938 === Responsible Party === Company Name:FISHER SCIENTIFIC,CHEMICAL DIVISION Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Info Phone Num:(201)796-7100 Emergency Phone Num:(201)796-7100 Preparer's Name:GASTON L PILLORI CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 97% Other REC Limits:N/K OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SODIUM CARBONATE. CAS:497-19-8 RTECS #:VZ4050000 Fraction by Wt: 0.50% Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CHLORINE TRIFLUORIDE,CHLOROFORM & METHYL ALCOHOL,CHLORONITROTOLUENE,1,2-DICHLOROETHYLENE,ETHYLENE CYANOHYDRIN,GLYOXAL, RTECS #:9999999ZZ Ingred Name:HALOGENATED HYDROCARBONS,HYDROQUINONE,MALEIC ANHYDRIDE,METALS,NITROETHANE,NITROMETHANE,NITROPARAFFINS,NITROPROPA NE,OLEUM RTECS #:9999999ZZ Ingred Name:PENTOL PHOSPHORUS,PHOSPHORUS PENTOXIDE,B-PROPIOLACTONE,TETRACHLOROBENZENE AND METHYL ALCOHOL,TETRAHYDROFURAN, RTECS #:9999999ZZ Ingred Name:TRICHLOROETHYLENE,WATER,ACETIC ACID,CHLOROSULFONIC ACID,HYDROCHLORIC ACID,HYDROFLUORIC ACID,NITRIC ACID,SULFURIC ACID. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL:CORR.200 MG/CUM IS IMMED DANGER TO LIFE & HEALTH.DERMAT.RAPID,SEV DMG TO EYE.PERM CORNEAL DMG ALMOST INEVITABLE.CORR OF LIPS,MOUTH,TONGUE & PHARYNX.PERFORATION OF ESOPHAGUS & STOMACH CAN OCCUR.C ASES OF SQUAMOUS CELL CARCINOMA HAVE OCCURRED 12-42 YEARS AFTER INGEST (RESULT OF TISSUE DESTRUCT/SCAR FORMATION). Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:SEVERE CORNEAL DAMAGE ALMOST INEVITABLY PERMANENT.ULCERATION & CORNEAL OPACIFICATION.SKIN:SEVERE & RAPID CORROSION.SEVERE BURNS,TEMP HAIR LOSS.INGEST:ABDOMINAL PAIN,CORROSION OF MUCOSA.ASPHYXIA F ROM SWOLLEN THROAT.INHALATION:MILD IRRIT TO SEV PNEUMIT,SORE THROAT,COUGHING,LABORED BRTHG,PULM EDEMA,BRONCH PNEUM. Medical Cond Aggravated by Exposure:N/K ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH W/ LG AMTS OF WATER FOR AT LEAST 15 MIN,HOLDING EYELIDS APART.CALL MD.IF NONE AVAIL,FLUSH 15 MIN AGAIN BEFORE MOVING TO MED FACILITY.SKIN:FLUSH IN SAFETY SHOWER IMMED.IF GOGG ON FLUSH HEAD & FACE,REMOVE GOGG,CLEAN HANDS,REMOVE CONTAM CLTHG/SHOES,CALL MD.WASH FOR 1-2 HRS.GO TO MED FACILITY.INGEST:DO NOT INDUCE VOMIT.GIVE LG AMT WATER OR MILK.GET MED ATTN.INHAL:REMOVE TO (SEE SUPP) ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Lower Limits:N/K Upper Limits:N/K Extinguishing Media:USE FLOODING AMOUNTS OF WATER. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .SEP FROM FIRE IF POSS.COOL FIRE EXPOS CONTR W/ H*2O FROM SIDE UNTIL WELL AFTER FIRE OUT.DO NOT SPLASH MATL. Unusual Fire/Explosion Hazard:NOT COMBUST.SOLID FORM IN CONTACT W/ H*2O MAY PRDCE CORR FUMES & SUFF HEAT TO IGNITE COMBUST MATLS.CONTACT W/ AMPHOTERIC METALS CAN PRODUCE FLAMM HYDROGEN GAS. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID CONT.USE VENT.WEAR PROT EQUIP.STOP LEAK IF W/O RISK.SM:ABSORB & PLACE IN CONTRS FOR DISP,CLOSE TIGHTLY & LBL "CORROSIVE".DRY:SHOVEL INTO CLEAN,DRY CONTR,COVER & MOVE FROM AREA.LARGE:DIKE.EVAC AR EA & DENY ENTRY.KEEP OUT OF SEWER/WATERSOURCES. Neutralizing Agent:N/K ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT OR STORAGE WITH INCOMPATIBLE MATERIALS,INCLUDING THOSE LISTED IN REACTIVITY SECTION. Other Precautions:N/K ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL & GENERAL VENT NECESSARY TO KEEP AIR CONC BELOW TLV .EQUIP MUST BE RESISTANT TO CORROSION BY ALKALIES. Protective Gloves:IMPERVIOUS.SPECIFIC TYPE MAY BE MFR REC. Eye Protection:CHEM WORK GOGG PLUS FACESHIELD (8" MIN). Other Protective Equipment:IMPERVIOUS CLOTHING AS NECESSARY TO AVOID CONTACT WITH SOLUTIONS OR MISTS. Work Hygienic Practices:DO NOT WEAR CONTACT LENSES WHEN WORKING WITH CHEMICALS. Supplemental Safety and Health VP:42 MMHG @ 1000C,1832F.PH:14 FOR A 5% AQ SOLN.SOLVENT SOLUBILITY:ALCOHOL,GLYCEROL.FIRST AID PROC:FRESH AIR.IF BRTHG IS DIFFICULT OR SKIN IS BLUE GIVE O*2 BY QUALIFIED OPERATOR.GET MEDICAL ATTENTION. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:2534F,1390C Melt/Freeze Pt:M.P/F.P Text:605F,318C Decomp Temp:Decomp Text:N/K Vapor Pres:SEE SUPP Vapor Density:N/K Spec Gravity:2.1 (WATER=1) pH:SUPP Evaporation Rate & Reference:N/K Solubility in Water:53% AMBIENT Appearance and Odor:ODORLESS,WHITE OR OFF-WHITE HYGROSCOPIC SOLID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACETALDEHYDE,ACETIC ANHYDRIDE,ACROLEIN,ACRYLONITRILE,ALLYL ALCOHOL,ALLYL CHLORIDE,ALUMINUM,CHLOROHYDRIN (SEE 9999999ZZ) Stability Condition to Avoid:STABLE AT ORDINARY PRESSURES UP TO THE BOILING POINT,1390C.MAY IGNITE COMBUSTIBLES. Hazardous Decomposition Products:DISSOLVING IN H*2O PRDCS HEAT & CORR FUMES.REACTS W/ AMPHOTERIC METALS PRDCG FLAMM H GAS.BOILS AWAY UNCHANGED AT 1390C. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.