Material Safety Data Sheet
    4-Chlorophenylboronic Acid, 97%
ACC# 01550
  
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Section 1 - Chemical Product and Company Identification | 
  
MSDS Name: 4-Chlorophenylboronic Acid, 97%
Catalog Numbers:
     AC344410000, AC344410010, AC344410050
Synonyms:
     p-Chlorophenylboronic Acid; p-Chlorobenzeneboronic Acid.
Company Identification:
 
 
 
 
 
 
 
Acros Organics N.V.
 
 
 
 
 
 
 
One Reagent Lane
 
 
 
 
 
 
 
Fair Lawn, NJ  07410
For information in North America, call:   800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
  
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Section 2 - Composition, Information on Ingredients
 | 
  | CAS# | 
    Chemical Name | 
    Percent | 
    EINECS/ELINCS | 
|    1679-18-1 | 
4-Chlorophenylboronic Acid | 
   97%    | 216-845-5 | 
  
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Section 3 - Hazards Identification
 | 
EMERGENCY OVERVIEW
Appearance: off-white powder.
 Warning! Causes respiratory tract irritation.
Irritant. Causes eye and skin irritation. May cause digestive tract
irritation.
Target Organs: Respiratory system, eyes, skin.
Potential Health Effects
     
Eye:
          Causes eye irritation.  May cause chemical conjunctivitis.
     
Skin:
          Causes skin irritation.
     
Ingestion:
          May cause gastrointestinal irritation with nausea, vomiting and
          diarrhea.
     
Inhalation:
          Causes respiratory tract irritation. Can produce delayed pulmonary
          edema.
     
Chronic:
          Effects may be delayed.
  
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Section 4 - First Aid Measures
 | 
     
Eyes:
          Immediately flush eyes with plenty of water for at least 15 minutes,
          occasionally lifting the upper and lower eyelids. Get medical aid.
     
Skin:
          Get medical aid. Flush skin with plenty of water for at least 15
          minutes while removing contaminated clothing and shoes. Wash clothing
          before reuse.
     
Ingestion:
          Never give anything by mouth to an unconscious person. Get medical
          aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
          drink 2-4 cupfuls of milk or water. Wash mouth out with water.
     
Inhalation:
          Remove from exposure and move to fresh air immediately. If not
          breathing, give artificial respiration. If breathing is difficult,
          give oxygen. Get medical aid. Do NOT use mouth-to-mouth
          resuscitation.
     
Notes to Physician:
          Treat symptomatically and supportively.
  
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Section 5 - Fire Fighting Measures
 | 
     
General Information:
          As in any fire, wear a self-contained breathing apparatus in
          pressure-demand, MSHA/NIOSH (approved or equivalent), and full
          protective gear. During a fire, irritating and highly toxic gases
          may be generated by thermal decomposition or combustion.
     
Extinguishing Media:
          Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
                  Upper: Not available.
     
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Instability: 0
  
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Section 6 - Accidental Release Measures
 | 
     
General Information: Use proper personal protective equipment as indicated
                          in Section 8.
     
Spills/Leaks:
          Vacuum or sweep up material and place into a suitable disposal
          container. Clean up spills immediately, observing precautions in the
          Protective Equipment section. Avoid generating dusty conditions.
          Provide ventilation.
  
    | 
Section 7 - Handling and Storage
 | 
     
Handling:
          Minimize dust generation and accumulation. Avoid breathing dust,
          vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
          Keep container tightly closed. Avoid ingestion and inhalation. Use
          with adequate ventilation. Wash clothing before reuse.
     
Storage:
          Store in a tightly closed container. Store in a cool, dry,
          well-ventilated area away from incompatible substances.
  
    | 
Section 8 - Exposure Controls, Personal Protection
 | 
     
Engineering Controls:
          Facilities storing or utilizing this material should be equipped
          with an eyewash facility and a safety shower. Use adequate
          ventilation to keep airborne concentrations low.
Exposure Limits
  | Chemical Name | 
    ACGIH | 
    NIOSH | 
    OSHA - Final PELs | 
| 4-Chlorophenylboronic Acid
 | 
none listed
 | 
none listed
 | 
none listed
 | 
     
OSHA Vacated PELs:
          4-Chlorophenylboronic Acid:
             No OSHA Vacated PELs are listed for this chemical.
     
Personal Protective Equipment
                 
Eyes:
                       Wear appropriate protective eyeglasses or chemical
                       safety goggles as described by OSHA's eye and face
                       protection regulations in 29 CFR 1910.133 or European
                       Standard EN166.
                 
Skin:
                       Wear appropriate protective gloves to prevent skin
                       exposure.
             
Clothing:
                       Wear appropriate protective clothing to prevent skin
                       exposure.
          
Respirators:
                       Follow the OSHA respirator regulations found in 29
                       CFR 1910.134 or European Standard EN 149. Use a
                       NIOSH/MSHA or European Standard EN 149 approved
                       respirator if exposure limits are exceeded or if
                       irritation or other symptoms are experienced.
  
    | 
Section 9 - Physical and Chemical Properties
 | 
Physical State:  Powder
Appearance:      white - off-white
Odor:            Not available.
pH:              Not available.
Vapor Pressure:  Not available.
Vapor Density:   Not available.
Evaporation Rate:Not available.
Viscosity:       Not available.
Boiling Point:   Not available.
Freezing/Melting Point:262 - 264 deg C
Decomposition Temperature:Not available.
Solubility:      +/- 2.5%
Specific Gravity/Density:Not available.
Molecular Formula:C6H6BClO2
Molecular Weight:156.38
  
    | 
Section 10 - Stability and Reactivity
 | 
     
Chemical Stability:
          Stable under normal temperatures and pressures.
     
Conditions to Avoid:
          Incompatible materials, dust generation, excess heat.
     
Incompatibilities with Other Materials:
          Oxidizing agents, strong acids.
     
Hazardous Decomposition Products:
          Hydrogen chloride, carbon monoxide, carbon dioxide, boron oxides.
     
Hazardous Polymerization: Will not occur.
  
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Section 11 - Toxicological Information
 | 
     
RTECS#:
     
CAS# 1679-18-1:
CY8950000
     
LD50/LC50:
          Not available.
     
Carcinogenicity:
       CAS#    1679-18-1:
          Not listed by ACGIH, IARC, NTP, or CA Prop 65.
     
Epidemiology:
No information found
     
Teratogenicity:
No information found
     
Reproductive Effects:
No information found
     
Mutagenicity:
No information found
     
Neurotoxicity:
No information found
     
Other Studies:
  
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Section 12 - Ecological Information
 | 
          No information available.
  
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Section 13 - Disposal Considerations
 | 
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
  
    | 
Section 14 - Transport Information
 | 
  |        | 
    US DOT | 
    Canada TDG | 
| Shipping Name: | 
Not regulated as a hazardous material | 
No information available. | 
| Hazard Class: | 
 | 
 | 
| UN Number: | 
 | 
 | 
| Packing Group: | 
 | 
 | 
  
    | 
Section 15 - Regulatory Information
 | 
 US FEDERAL
     
TSCA
     CAS# 1679-18-1 is not listed on the TSCA inventory.
It is for research and development use only.
        
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
        
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
        
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
        
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
        
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
        
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
        
Section 313
     No chemicals are reportable under Section 313.
     
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
     
Clean Water Act:
     None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
     None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
     
OSHA:
     None of the chemicals in this product
are considered highly hazardous by OSHA.
 
STATE
          CAS#    1679-18-1 is not present on
     state lists from CA, PA, MN, MA, FL, or NJ.
 
California Prop 65
     
California No Significant Risk Level:
     None of the chemicals in this product are listed.
 
European/International Regulations
     European Labeling in Accordance with EC Directives
          Hazard Symbols:
      XI
          
Risk Phrases:
     R 36/37/38  Irritating to eyes, respiratory system and skin.          
          
Safety Phrases:
     S 26  In case of contact with eyes, rinse immediately with plenty of  
     water and seek medical advice.                                        
     S 37/39  Wear suitable gloves and eye/face protection.                
   
WGK (Water Danger/Protection)
     CAS# 1679-18-1: No information available.
   Canada - DSL/NDSL
          None of the chemicals in this product are listed on the DSL or NDSL list.
   Canada - WHMIS
     WHMIS: Not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
   Canadian Ingredient Disclosure List
  
    | 
Section 16 - Additional Information
 | 
     MSDS Creation Date:  9/24/1999  
Revision #3 Date: 10/05/2004
     The information above is believed to be accurate and represents the best
     information currently available to us. However, we make no warranty of
     merchantability or any other warranty, express or implied, with respect to
     such information, and we assume no liability resulting from its use. Users
     should make their own investigations to determine the suitability of the
     information for their particular purposes. In no event shall Fisher be liable
     for any claims, losses, or damages of any third party or for lost profits
     or any special, indirect, incidental, consequential or exemplary
     damages, howsoever arising, even if Fisher has been advised of
     the possibility of such damages.