J T BAKER INC -- NITROBENZENE, 9325 -- 6810-00N044265
===================== Product Identification ===================== Product ID:NITROBENZENE, 9325 MSDS Date:05/01/1989 FSC:6810 NIIN:00N044265 === Responsible Party === Company Name:J T BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:201-859-2151 Emergency Phone Num:800-424-8802;800-424-9300(CHEMTREC) CAGE:DO803 === Contractor Identification === Company Name:J T BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:1-800-582-2537 CAGE:DO803 Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:BENZENE, NITRO-; (NITROBENZENE) (SARA III) CAS:98-95-3 RTECS #:DA6475000 Fraction by Wt: 90-100% OSHA PEL:1 PPM, S ACGIH TLV:1 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) 640 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL: CYANOSIS, UNCONSCIOUSNESS,HEADACHE, NAUSEA, VOMITING, DIZZINESS, RAPID INEFFECTIVE BREATHING, LOW BLOOD PRESSURE, IRRITATION OF MUCOUS MEMBRANES, WEAKNESS, CONVULSIONS, AND MAY BE FATAL. SKIN/E YE: IRRITATION. SKIN ABSORP: RAPID ABSORPTION. MAY CAUSE INCREASED HEART RATE, CONVULSIONS, MAY BE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:FATAL. INGEST: CYANOSIS, UNCON, HDCH, NAUSEA, VOMIT, DIZZ, WEAKNESS, RAPID INEFFECTIVE BRTHG, LOW BLOOD PRESS, CONVULSIONS, AND MAY BE FATAL. CHRONIC: CNS DAMAGE, BLURRED VISION, LIVER DAMAGE , ANEMIA. IRRITATION OF UPPER RESPIRATORY TRACT. TARGET ORGANS: BLOOD, LIVER, KIDNEYS, CARDIOVASCULAR SYS, SKIN. Medical Cond Aggravated by Exposure:RESPIRATORY SYSTEM DISEASE, HEART DISORDERS, BLOOD DISORDERS, LIVER DISORDERS. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD. IF CONSCIOUS, IMMED INDUCE VOMIT. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. SKIN:IMMED FLUSH SKIN W/PLENTY OF WATER FOR @ LST 15 MIN WHIL E REMOVING CONTAM CLTHG & SHOES. THORO CLEANSING OF THE ENTIRE CONTAM AREA OF THE BODY INCLUDING SCALP & NAILS IS OF THE UTMOST IMPORTANCE. EYE:IMMED FLUSH W/PLENTY OF WATER FOR @ 15 MIN. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:189F,87C Lower Limits:1.8% Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL OR ORDINARY FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP MOVE CNTNRS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CNTNRS COOL. Unusual Fire/Explosion Hazard:VAPS MAY FLOW ALONG SURFS TO DISTANT IGNITION SOURCES AND FLASH BACK. CLOSED CNTNRS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG. SHUT OFF IGNIT SOURCES. NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPS. TAKE UP W/SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATL (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA OR CABINET. KEEP FROM HEAT, SPARK, FLAME. Other Precautions:DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. DO NOT BREATHE VAPOR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESP PROT REQUIRED IF AIRBORNE CONC EXCEEDS TLV. AT CONCS UP TO 50 PPM, A CHEM CARTRIDGE RESP W/ORGAN VAP CARTRIDGE IS RECOMMENDED. ABOVE THIS LEVEL A NIOSH/MSHA APPROVED SCBA IS RECOMMENDED. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Protective Gloves:VITON GLOVES. Eye Protection:SAFETY GOGGLES AND FACE SHIELD. Other Protective Equipment:UNIFORM, PROTECTIVE SUIT, VITON GLOVES ARE RECOMMENDED. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MATLS TO AVOID: HYDROXIDE, MERCURY, DIMETHYL SULFATE, GLYCEROL, ANILINE, NITROGEN TETROXIDE. SPILL PROC: AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER. ================== Physical/Chemical Properties ================== HCC:T3 Boiling Pt:B.P. Text:411F,211C Melt/Freeze Pt:M.P/F.P Text:42.0F,5.6C Vapor Pres:< 1 @ 20C Vapor Density:4.2 Spec Gravity:1.20 (H2O=1) Solubility in Water:SLIGHT (0.1-1%) Appearance and Odor:YELLOW VISCOUS LIQUID. ALMOND ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG REDUCING AGENTS, MOST COMMON METALS, STRONG OXIDIZING AGENTS, STRONG ACIDS, POTASSIUM, POTASSIUM (SUPP DATA) Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION, FREEZING, LIGHT. Hazardous Decomposition Products:OXIDES OF NITROGEN, CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. HAZARDOUS WASTE NUMBER U169 (TOXIC WASTE). Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.