Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
95-82-9	2,5-Dichloroaniline	99	202-455-2

Section 3 - Hazards Identification

Appearance: dark brown flakes.
Harmful if swallowed, inhaled, or absorbed through the skin. Causes respiratory tract irritation. Causes eye and skin irritation. Marine pollutant.
Target Organs: Blood.


Potential Health Effects
Eye: Causes eye irritation. Eye damage may be delayed. Causes redness and pain.
Skin: Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Absorption into the body may cause cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood). Causes redness and pain. Toxic in contact with skin.
Ingestion: May cause irritation of the digestive tract. Poison by ingestion. May cause nausea and vomiting.
Inhalation: Causes respiratory tract irritation. Toxic if inhaled. May cause nausea, dizziness, and headache.
Chronic: May cause liver and kidney damage. Absorption into the body leads to the formation of methemoglobin which in sufficient concentrations causes cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood).

Section 4 - First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately.
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Get medical aid immediately. Wash mouth out with water.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products.
Extinguishing Media: Water or foam may cause frothing. Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: 166 deg C ( 330.80 deg F)
Autoignition Temperature: 540 deg C ( 1,004.00 deg F)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 1; Instability: 0

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid breathing dust.
Storage: Store in a tightly closed container. Store in a dry area. Isolate from oxidizing materials and acids.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
2,5-Dichloroaniline	none listed	none listed	none listed
Dichloroaniline	none listed	none listed	none listed

OSHA Vacated PELs: 2,5-Dichloroaniline: No OSHA Vacated PELs are listed for this chemical. Dichloroaniline: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Flakes
Appearance: beige - dark brown
Odor: characteristic odor
pH: 6.5(0.66g/l aq.sol.)
Vapor Pressure: .02 mm Hg @ 25 deg C
Vapor Density: 5.6 (air=1)
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 251 deg C @ 760 mmHg
Freezing/Melting Point:48 - 51 deg C
Decomposition Temperature:> 350 deg C
Solubility: Insoluble.
Specific Gravity/Density:Not available.
Molecular Formula:C6H5Cl2N
Molecular Weight:162.02

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Light, dust generation, exposure to air.
Incompatibilities with Other Materials: Oxidizing agents, acids, acid chlorides, acid anhydrides.
Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, aniline.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:      
CAS# 95-82-9: BX2610000      
CAS# 27134-27-6 unlisted.
LD50/LC50:
CAS# 95-82-9:
     Oral, mouse: LD50 = 1600 mg/kg;
     Oral, rabbit: LD50 = 3750 mg/kg;
     Oral, rat: LD50 = 1600 mg/kg;
.

CAS# 27134-27-6:
.

Carcinogenicity:
CAS# 95-82-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 27134-27-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information

Ecotoxicity: No data available. No information available.
Environmental: No information available.
Physical: No information available.
Other: Not readily biodegradable. This chemical is not likely to bioconcentrate.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	DICHLOROANILINES, SOLID	DICHLOROANILINES
Hazard Class:	6.1	6.1
UN Number:	UN1590	UN1590
Packing Group:	II	II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 95-82-9 is listed on the TSCA inventory.
     CAS# 27134-27-6 is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 95-82-9 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 27134-27-6 can be found on the following state right to know lists: New Jersey.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     T N
Risk Phrases:
     R 23/24/25 Toxic by inhalation, in contact with skin and if
     swallowed.
     R 33 Danger of cumulative effects.
     R 50/53 Very toxic to aquatic organisms, may cause long-term
     adverse effects in the aquatic environment.

Safety Phrases:
     S 36/37 Wear suitable protective clothing and gloves.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).
     S 60 This material and its container must be disposed of as hazardou
     s waste.
     S 28A After contact with skin, wash immediately with plenty of water
     .
     S 61 Avoid release to the environment. Refer to special instructions
     /safety data sheets.

WGK (Water Danger/Protection)
     CAS# 95-82-9: 3
     CAS# 27134-27-6: No information available.
Canada - DSL/NDSL
     CAS# 95-82-9 is listed on Canada's NDSL List.
Canada - WHMIS
     This product has a WHMIS classification of D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 95-82-9 is not listed on the Canadian Ingredient Disclosure List.
     CAS# 27134-27-6 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 1/28/2000
Revision #3 Date: 10/03/2005

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.