FISHER SCIENTIFIC CHEMICAL DIVISION -- NAPHTHALENE -- 6810-00-984-9787
===================== Product Identification ===================== Product ID:NAPHTHALENE MSDS Date:03/15/1989 FSC:6810 NIIN:00-984-9787 === Responsible Party === Company Name:FISHER SCIENTIFIC CHEMICAL DIVISION Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7523 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:NAPHTHALENE (SARA III) CAS:91-20-3 RTECS #:QJ0525000 Fraction by Wt: 100% OSHA PEL:10 PPM/15 STEL ACGIH TLV:10 PPM/15 STEL; 9192 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS 1250 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALE- RESPIRATORY TRACT IRRITATION, HEADACHE, NAUSEA. SKIN- IRRITATION AND SEVERE DERMATITIS, SYSTEMIC POISONING.EYE- IRRITATION AND DAMAGE TO THE CORNEA. INGEST- CRAMPS, NAUSEA, VOMITING, DI ARHHEA, HEADACHE. CHRONIC: CONJUNCTIVITIS, ITCHING, REDNESS, SCALING, SENSTITIZATION, CATARACTS AND OCULAR IRRITATION. Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF SKIN AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE SUBJECT TO FRESH AIR. IF BREATHING STOPPED, GIVE ARTIFICIAL RESPIRATION. EYE: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WA TER. REMOVE ALL CONTAMINATED CLOTHING. INGESTION: REMOVE BY GASTRIC LAVAGE OR EMESIS. MAINTAIN AIRWAY AND BLOOD PRESSURE. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:174F,79C Autoignition Temp:Autoignition Temp Text:979F Lower Limits:0.9% Upper Limits:5.9% Extinguishing Media:DRY CHEMICAL, SAND, WATER SPRAY OR FOAM. Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. COOL CONTAINERS EXPOSED TO FLAME WITH WATER FROM SIDE UNTIL WELL AFTER FIRE IS OUT. AVOID BREATHING VAPORS OR DUSTS. Unusual Fire/Explosion Hazard:USE WATER IN FLOODING QUANTITIES AS FOG, SOLID STREAMS MAY NOT BE EFFECTIVE. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE OR SOAK UP SMALL SPILLS WITH PAPER TOWEL OR INERT ABSORBANT. DIKE TO RETAIN LARGE SPILLS. VACUUM UP FREE LIQUID. REMOVE RESIDUE WITH INERT ABSORBANT. PLACE IN DISPOSAL CONTAINER. FLUSH AREA WITH WATER. NO SMOKING, FLAMES OR FLARES IN HAZARD AREA Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE, HEAT AND IGNITION SOURCES. KEEP CONTAINERS CLOSED. Other Precautions:STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH-RESPIRATOR SELECTION. Ventilation:MECHANICAL (GENERAL) VENTILATION IS REQUIRED. LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA IS NOT VENTED. Protective Gloves:RUBBER Eye Protection:CHEMICAL SAFETY GOGGLES/FACESHIELD Other Protective Equipment:SAFETY SHOWER AND EYE BATH. OTHER EQUIPMENT AS REQUIRED TO MINIMIZE EXPOSURE FROM PROLONGED OR REPEATED CONTACT. Work Hygienic Practices:WASH THROUGHLY AFTER HANDLING AND BEFORE EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:424F,218C Melt/Freeze Pt:M.P/F.P Text:176F,80C Vapor Pres:0.05 Vapor Density:4.4 Spec Gravity:1.1 Evaporation Rate & Reference:<1.0 (BUTYL ACETATE=1) Solubility in Water:INSOLUBLE Appearance and Odor:WHITE CRYSTALLINE, VOLATILE FLAKES; ODOR OF MOTH BALLS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CHROMIC ANHYDRIDE, ALUMINUM TRICHLORIDE, STRONG OXIDIZERS, DINITROGEN PENTAOXIDE, PLASTICS, RUBBER, COATINGS. Stability Condition to Avoid:ABNORMAL TEMPERATURES AND PRESSURES. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.