J T BAKER INC -- ETHER ANHYDROUS, 9197 -- 6810-00N054255
===================== Product Identification ===================== Product ID:ETHER ANHYDROUS, 9197 MSDS Date:03/09/1992 FSC:6810 NIIN:00N054255 === Responsible Party === Company Name:J T BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151;800-424-9300(CHEMTREC) CAGE:DO803 === Contractor Identification === Company Name:J T BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:1-800-582-2537 CAGE:DO803 Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANE, 1,1'-OXYBIS-; (ETHYL ETHER) (DIETHYL ETHER) (SARA III). LD50:(ORAL,RAT) 1215 MG/KG. CAS:60-29-7 RTECS #:KI5775000 Fraction by Wt: 97-100% OSHA PEL:400 PPM ACGIH TLV:400 PPM;500 STEL EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ETHYL ALCOHOL; (ETHANOL). LD50:(ORAL,RAT) 7060 MG/KG. CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: <2.5% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:SUPDAT:DISCARD ANY REMAINING ETHER IN OPENED CNTNRS THAT IS NOT CONSUMED AFTER 2-3 DAYS. USE CAUT WHEN OPENING (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:CAP. IMPORTANT - DO NOT USE AFTER EXPIRATION DATE. DANGER! CAUSES IRRIT. EXTREMELY FLAMM. HIGHLY VOLATILE. (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:HARMFUL IF SWALLOWED, INHALED/ABSORBED THRU SKIN. TENDS TO FORM EXPLO PEROXIDES, ESP WHEN ANHYDROUS. KEEP (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:AWAY FROM HEAT, SPARKS, FLAME. AVOID CONTACT W/EYES, SKIN, CLTHG. KEEP AWAY FROM SOURCES OF IGNIT - NO (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:SMOKING. DO NOT EMPTY INTO DRAINS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. WHEN HNDLG LIQ (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:PROD, SECONDARY PROT CNTNRS MUST BE USED FOR CARRYING. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:CNS DEPRESSION, HEADACHE, NAUSEA, VOMITING, DROWSINESS, IRRITATION OF UPPER RESPIRATORY TRACT, JAUNDICE, LIVER DAMAGE, UNCONSCIOUSNESS. SKIN CONTACT:IRRITATION, PROLONGED CONTACT MAY CAUSE SENSIT. SKIN ABSORPTION:RAPID ABSORPTION, CNS DEPRESSION, HEADACHE, NAUSEA, VOMITING, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:DROWSINESS, JAUNDICE, LIVER DMG. INGEST:CNS DEPRESS, HDCH, NAUS, VOMIT, DROW, NERVOUSNESS, JAUNDICE, LIVER DMG, HEART FAILURE, RESP FAILURE, UNCON. CHRONIC:CNS DEPRESS. TARGET ORGANS:CNS, EYE S, SKIN, MUC MEMBS, RESP SYS, LUNGS, HEART, LIVER. Medical Cond Aggravated by Exposure:NONE IDENTIFIED. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD. IF SWALLOWED, DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INHAL:REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GI VE OXYGEN. SKIN:IMMEDIATELY FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS WHILE REMOVING CONTAMINATED CLOTHING & SHOES. WASH CLOTHING BEFORE RE-USE. EYE:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:-47F,-44C Lower Limits:1.9% Upper Limits:36% Extinguishing Media:USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. (WATER MAY BE INEFFECTIVE.) Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . MOVE CNTNRS FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK. USE WATER TO KEEP FIRE-EXPOSED CNTNRS COOL. Unusual Fire/Explosion Hazard:VAPS MAY FLOW ALONG SURFS TO DIST IGNIT SOURCES & FLASH BACK. CLSD CNTNRS EXPOS TO HEAT MAY EXPLODE. CONT W/STRONG OXIDIZERS MAY CAUSE FIRE. MAY FORM (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG. SHUT OFF IGNIT SOURCE; NO FLARES, SMOKING/FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO W/OUT RISK. USE H*2O SPRAY TO REDUCE VAP.TAKE UP W/SAND/NON-COMBUST ABSORB MATL & PUT IN CNTNR FOR LATER DISP.(SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD. STORE IN COOL, DRY, WELL-VENTILATED, FLAMM LIQ STOR AREA. ISOLATE FROM INCOMPAT MATLS. AVOID BRTHG VAP. USE W/ADEQ VENT. Other Precautions:BOND & GROUND CNTNRS WHEN TRANSFERRING LIQ. ETHER IS SUBJECT TO PEROXIDE FORM IN OPENED CNTNRS & SHOULD BE PROT FROM EXPOS TO AIR AS MUCH AS POSS. WHEN LOW PEROXIDE ETHER IS REQD, USE ONLY MATL FROM U NOPENED CAN. DO NOT ALLOW TO (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATORY PROTECTION IS REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 1000 PPM, A NIOSH/MSHA APPRVD CHEM CARTRIDGE RESP W/ORGANIC VAP CARTRIDGE IS REC. ABOVE THIS LEVEL, A NIOSH/MSHA APPRVD SCBA IS REC. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. VENT HOOD. Protective Gloves:NITRILE GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:UNIFORM, APRON ARE RECOMMENDED. LAB COAT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health EXPLO HAZ:EXPLO PEROXIDES, ESP WHEN HEATED & EXPOSED TO AIR . FORMS SHOCK-SENSITIVE MIXTS W/CERTAIN OTHER MATLS. SPILL PROC: FLUSH AREA W/WATER. J.T. BAKER SOLUSORB SOLV ABSORB IS REC FOR SPILLS OF THIS PROD. OTHER PREC:EVAP TO NEAR DRYNESS. ADDN OF WATER/APPROP REDUCING AGENTS WILL LESSEN PEROXIDE FORM. (ING 3) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:95.0F,35.0C Melt/Freeze Pt:M.P/F.P Text:-177F,-116C Vapor Pres:442 @ 20C Vapor Density:2.6 Spec Gravity:0.71 (H*2O=1) Evaporation Rate & Reference:37.5 (BUTYL ACETATE=1) Solubility in Water:MODERATE (1-10%) Appearance and Odor:CLEAR, COLORLESS LIQUID; CHARACTERISTIC ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG BASES, STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION, LIGHT, AIR. Hazardous Decomposition Products:EXPLOSIVE PEROXIDES, CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE & LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: U117 (TOXIC WASTE). Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.