Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
937-14-4	3-Chloroperoxybenzoic acid	70-75	213-322-3
535-80-8	3-Chlorobenzoic acid	Balance	208-618-4
7732-18-5	Water	Balance	231-791-2

Section 3 - Hazards Identification

Appearance: white solid.
Danger! Causes eye and skin burns. Strong oxidizer. Contact with other material may cause a fire. Organic peroxide. Heat or contamination may cause hazardous decomposition. Peroxides and decomposition products are flammable and can ignite with explosive force if confined. Causes digestive and respiratory tract burns. May be harmful if swallowed.
Target Organs: Eyes, skin, mucous membranes.


Potential Health Effects
Eye: Causes eye burns.
Skin: Causes skin burns.
Ingestion: May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May be harmful if swallowed.
Inhalation: Causes chemical burns to the respiratory tract.
Chronic: None

Section 4 - First Aid Measures

Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Oxidizer. Greatly increases the burning rate of combustible materials. Containers may explode in the heat of a fire. May be ignited by heat, sparks, and flame.
Extinguishing Media: Do NOT use straight streams of water. For small fires, use dry chemical, carbon dioxide, water spray or regular foam. Cool containers with flooding quantities of water until well after fire is out. For large fires flood fire with water from a distance.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:N/A
Upper: N/A
NFPA Rating: (estimated) Health: ; Flammability: ; Instability: 2; Special Hazard: OX

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Do not use combustible materials such as paper towels to clean up spill.

Section 7 - Handling and Storage

Handling: Keep container tightly closed. Keep away from heat, sparks and flame. Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Do not store near combustible materials. Discard contaminated shoes.
Storage: Keep away from sources of ignition. Do not store near combustible materials. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Keep refrigerated. (Store below 4°C/39°F.)

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
3-Chloroperoxybenzoic acid	none listed	none listed	none listed
3-Chlorobenzoic acid	none listed	none listed	none listed
Water	none listed	none listed	none listed

OSHA Vacated PELs: 3-Chloroperoxybenzoic acid: No OSHA Vacated PELs are listed for this chemical. 3-Chlorobenzoic acid: No OSHA Vacated PELs are listed for this chemical. Water: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties

Physical State: Solid
Appearance: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:92 - 94 deg C
Decomposition Temperature:Not available.
Solubility: insoluble
Specific Gravity/Density:Not available.
Molecular Formula:C7H5ClO3
Molecular Weight:172.57

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, strong oxidants.
Incompatibilities with Other Materials: Iron, manganese oxide, acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), metals and metal compounds (toxic, e.g. beryllium, lead acetate, nickel carbonyl, tetraethyl lead), nitrides (e.g. potassium nitride, sodium nitride), combustible and flammable materials (e.g. alkyl resins, asphalt, gasoline, grease, methyl acetone, polystyrene, polyurethane), oxidizing agents (strong, e.g. bromine, hydrogen peroxide, nitrogen dioxide, potassium nitrate), reducing agents (strong, e.g. aluminum carbide, chlorosilane, hydrogen phosphide, lithium hydride), nickel.
Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:      
CAS# 937-14-4: SD9470000      
CAS# 535-80-8: DG4975990      
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
Not available.

CAS# 7732-18-5:
     Oral, rat: LD50 = >90 mL/kg;
.

Carcinogenicity:
CAS# 937-14-4: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 535-80-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	ORGANIC PEROXIDE TYPE D, SOLID	ORGANIC PEROXIDE TYPE D SOLID (CHLOROPEROXYBENZOIC ACID)
Hazard Class:	5.2	5.2
UN Number:	UN3106	UN3106
Packing Group:	II	II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 937-14-4 is listed on the TSCA inventory.
     CAS# 535-80-8 is listed on the TSCA inventory.
     CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 937-14-4: immediate, fire, reactive.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 937-14-4 can be found on the following state right to know lists: New Jersey.
     CAS# 535-80-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     O C
Risk Phrases:
     R 22 Harmful if swallowed.
     R 34 Causes burns.
     R 7 May cause fire.

Safety Phrases:
     S 17 Keep away from combustible material.
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
     otection.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).

WGK (Water Danger/Protection)
     CAS# 937-14-4: No information available.
     CAS# 535-80-8: 1
     CAS# 7732-18-5: No information available.
Canada - DSL/NDSL
     CAS# 937-14-4 is listed on Canada's DSL List.
     CAS# 535-80-8 is listed on Canada's DSL List.
     CAS# 7732-18-5 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of C, E.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 1/22/1998
Revision #3 Date: 10/21/2004

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.