Material Safety Data Sheet
Tetraethylene glycol 99.5%
ACC# 07792
Section 1 - Chemical Product and Company Identification |
MSDS Name: Tetraethylene glycol 99.5%
Catalog Numbers:
AC149590000, AC149590010, AC149590025, AC149590250, AC94777942, AC9720696
Synonyms:
Ethanol, 2,2'-(oxybis(ethyleneoxy))di-
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
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CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
112-60-7 |
Tetraethylene glycol |
99.5 | 203-989-9 |
Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: colorless to pale straw colored liquid.
Caution! Causes eye and skin irritation. May cause
respiratory and digestive tract irritation.
Target Organs: None.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
None reported.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Combustible
material when exposed to heat or flames.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
Flash Point: 176 deg C ( 348.80 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 1; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Tetraethylene glycol
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Tetraethylene glycol:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: colorless to pale straw colored
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.01 hPa @ 20 C
Vapor Density: 6.7
Evaporation Rate:Not available.
Viscosity: 44.9 mPa 25.00 deg
Boiling Point: 324.0 - 330.0 deg C @ 760.00m
Freezing/Melting Point:- 4.10 - - 0.00 deg
Decomposition Temperature:Not available.
Solubility: Miscible.
Specific Gravity/Density:1.1250g/cm3
Molecular Formula:C8H18O5
Molecular Weight:194.23
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong bases.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 112-60-7:
XC2100000
LD50/LC50:
CAS# 112-60-7:
Draize test,
rabbit, eye: 500 mg Mild;
Oral,
rat: LD50 = 28900 uL/kg;
Oral,
rat: LD50 = 10000 mg/kg;
Skin,
rabbit: LD50 = >20 gm/kg;
.
Carcinogenicity:
CAS# 112-60-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
Fish: Bluegill/Sunfish: LC50 = >5.0 mg/L; 24 Hr.; 12.8 degrees
CFish: Goldfish: LC50 = >5.0 mg/L; 24 Hr.; 12.8 degrees
CFish: Rainbow trout: LC50 = >5.0 mg/L; 24 Hr.; 12.8 degrees
C
No data available.
Environmental:
Based on a recommended classification scheme, an estimated Koc value
of 10, determined from a structure estimation method, indicates that
tetraethylene glycol is not expected to adsorb to suspended solids
and sediment in water. Alcohols and ethers are generally resistant
to hydrolysis. According to a model of gas/particle partitioning of
semivolatile organic compounds in the atmosphere, tetraethylene
glycol, which has an measured vapor pressure of 4.65X10-5 mm Hg at 26
deg C, will exist in both the vapor and particulate phases.
Physical:
No information available.
Other:
An estimated BCF value of 0.02 was calculated for tetraethylene
glycol, using an estimated log Kow and a recommended
regression-derived equation. According to a classification scheme,
this BCF value suggests that bioconcentration in aquatic organisms is
low(SRC). [REF-19]
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
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US DOT |
Canada TDG |
Shipping Name: |
Not regulated as a hazardous material |
No information available. |
Hazard Class: |
|
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UN Number: |
|
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Packing Group: |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 112-60-7 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 112-60-7 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 112-60-7: 0
Canada - DSL/NDSL
CAS# 112-60-7 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
|
MSDS Creation Date: 6/09/1999
Revision #3 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.